Dual temperature curable silicone compositions, methods of manufacture, and articles prepared therefrom
Dual temperature curable silicone compositions, articles made from such compositions, and methods for the manufacture and use thereof. In particular, a dual temperature curable silicone composition is manufactured from a composition comprising a vinyl silicone; a silicone hydride-containing crosslinker; a platinum-containing catalyst; and a peroxide catalyst.
1. A method of fully curing a dual temperature curable silicone composition to form an article, the method comprising:
providing a silicone composition, wherein the silicone composition comprises:
100 parts by weight of a vinyl silicone of Formula I
R B [Si(R 1 R 2 )—O]—[(Si(R 3 R 4 )—O)] n —[Si(R 5 R 6 )—O)] m —Si(R 1 R 2 )—R A (Formula I)
wherein
n has an average value of 1 to 200,
m has an average value of 5,000 to 20,000,
R A , R B , R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each independently a C 1 -C 6 alkyl group; and
at least one of R A , R B , R 3 and R 4 has the formula —CH═CR F R G , where R F and R G are each independently hydrogen or a C 1 -C 6 alkyl group;
0.05-10 parts by weight of a silicone hydride-containing crosslinker;
a platinum-containing catalyst; and
0.2-5 parts by weight of a peroxide catalyst, wherein the platinum-containing catalyst and peroxide catalyst are present in a weight percent ratio of 0.001:1 to 0.01:1;
shaping the silicone composition to provide a shaped silicone composition;
exposing the shaped silicone composition to a first temperature to activate the platinum catalyst but not the peroxide catalyst, to form a shaped, semi-cured, article; and
heating the shaped, semi-cured article to a second temperature sufficient to activate the peroxide catalyst, to form a fully cured article.
2. The method of claim 1 , further comprising storing the shaped, semi-cured article for a period of time before heating to the second temperature.
3. The method of claim 1 , further comprising repositioning the shaped, semi-cured article before heating to the second temperature.
4. The method of claim 1 , wherein the shaping comprises casting or calendering the silicone composition to form a layer.
5. The method of claim 4 , comprising forming the layer on a substrate to provide an article comprising the shaped, semi-cured, article disposed on the substrate.
6. The method of claim 5 , wherein heating the shaped, semi-cured, article disposed on the substrate to the second temperature forms a fully cured article wherein the fully cured article is laminated to the substrate.
7. The method of claim 1 , wherein the first temperature is below 100° C., and the second temperature is 70° C. to 200° C., provided that the second temperature is higher than the first temperature.
8. The method of claim 7 , wherein the first temperature is below 50° C.
9. The method of claim 7 , wherein the first temperature is 21° C. to 25° C.
10. The method of claim 7 , wherein the first temperature is below 50° C. and the second temperature is 100° C. to 250° C.
11. The method of claim 1 , wherein at least one of R A , R B , R 3 and R 4 is —CH═CH 2 .
12. The method of claim 1 , wherein at least one of R A or R B is —CH═CH 2 and R 1 and R 2 are both methyl groups.
13. The method of claim 1 , wherein
the vinyl silicone comprises a polydiorganosiloxane functionalized with a terminal —Si(Me) 2 -CH═CH 2 group; and
the silicone hydride-containing crosslinker is of Formula (II):
R D —Si(R 7 R 8 )O—[Si(R 9 R 10 )—O)] x —[Si(R 11 R 12 )—O)] y —Si(R 13 R 14 )—R E (Formula II)
wherein
at least one of R D , R E , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 and R 14 is hydrogen, and the others of R D , R E , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 and R 14 are each independently hydrogen, or C 1 -C 6 alkyl;
x has an average value of 1 to 300; and
y is 0 or has an average value of 1 to 300.
14. The method of claim 13 , wherein both of R D and R E are hydrogen and R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , and R 14 are methyl.
15. The method of claim 14 , wherein y is 0; both of R D and R E are methyl; R 9 is hydrogen and R 7 , R 8 , R 10 , R 13 , and R 14 are methyl.
16. The method of claim 14 , wherein both of R D and R E are methyl; R 9 is hydrogen and R 7 , R 8 , R 10 , R 11 , R 12 , R 13 and R 14 are methyl.
17. The method of claim 1 , wherein
the platinum-containing catalyst comprises a Pt(0) complex, a Pt(II) complex, a Pt(IV) complex, or a combination comprising at least one of the foregoing; and
the peroxide catalyst comprises an organic peroxide; an aliphatic peroxide; an aromatic peroxide; an organic hydroperoxide; or a combination comprising at least one of the foregoing.
18. A shaped, fully cured article made by the method of claim 1 .