Organic electroluminescent compound, organic electroluminescent material comprising the same, and organic electroluminescent device
The present disclosure relates to an organic electroluminescent compound, an organic electroluminescent material comprising the same, and an organic electroluminescent device. By comprising the organic electroluminescent compound according to the present disclosure, an organic electroluminescent device having improved driving voltage and/or luminous efficiency and/or lifespan characteristics can be provided, compared with the organic electroluminescent device comprising a conventional organic electroluminescent compound.
1. An organic electroluminescent compound represented by the following formula 1-1 or 1-2:
wherein
X represents O or S;
Ar 1 and Ar 2 each independently represent a substituted or unsubstituted phenyl, a substituted or unsubstituted biphenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted terphenyl, a substituted or unsubstituted 9,9-dimethylfluorenyl, a substituted or unsubstituted 9,9-diphenylfluorenyl, a substituted or unsubstituted 9,9′-spirobifluorenyl, a substituted or unsubstituted dibenzofuranyl, a substituted or unsubstituted dibenzothiophenyl, a substituted or unsubstituted 9-phenyl-carbazolyl, a substituted or unsubstituted 2-phenylbenzoxazolyl, or a substituted or unsubstituted 2-phenylbenzothiazolyl;
L 1 and L 2 each independently represent a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted terphenylene, a substituted or unsubstituted dibenzothiophenylene, a substituted or unsubstituted 9-phenyl-carbazolylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, or a substituted or unsubstituted 9,9′-spirobifluorenylene;
R 1 to R 4 , R′, and R″ each independently represent hydrogen or deuterium; and
a and d each independently represent an integer of 1 to 4, b represents an integer of 1 to 3; and
when a, b, and d are an integer of 2 or more, each of R 1 , R 2 , and R 4 may be the same or different.
2. The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted phenyl(ene), the substituted biphenyl(ene), the substituted naphthyl(ene), the substituted terphenyl(ene), the substituted 9,9-dimethylfluorenyl(ene), the substituted 9,9-diphenylfluorenyl(ene), the substituted 9,9′-spirobifluorenyl(ene), the substituted dibenzofuranyl, the substituted dibenzothiophenyl(ene), the substituted 9-phenyl-carbazolyl(ene), the substituted 2-phenylbenzoxazolyl, and the substituted 2-phenylbenzothiazolyl in the Ar 1 , Ar 2 , L 1 , and L 2 each independently represent at least one selected from the group consisting of deuterium, cyano, (C1-05)alkyl, (C6-C12)aryl, and (5- to 15-membered)heteroaryl.
3. The organic electroluminescent compound according to claim 1 , wherein the Ar 1 and Ar 2 each independently are selected from any one of the substituents listed in the following group 1:
4. The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the following compounds:
5. An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
6. A plurality of host materials comprising at least one of the organic electroluminescent material according to claim 5 as a first host material, and at least one of a second host material which is different from the first host material.
7. The plurality of host materials according to claim 6 , wherein the second host material comprises a compound represented by the following formula 11:
wherein
A 1 and A 2 each independently represent a substituted or unsubstituted (C6-C30)aryl;
L 11 represents a single bond or a substituted or unsubstituted (C6-C30)arylene;
X′, X″, X 11 to X 14 , and X 23 to X 26 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or adjacent substituent(s) may be linked to each other to form a ring(s);
m and n each independently represent an integer of 1 to 3; and
when m and n are an integer of 2 or more, each of X′ and X″ may be the same or different.
8. The plurality of host materials according to claim 7 , wherein the compound represented by formula 11 is selected from the following compounds:
9. An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
10. The organic electroluminescent device according to claim 9 , wherein the organic electroluminescent compound is included in a light-emitting layer and/or an electron transport zone.
11. An organic electroluminescent device comprising an anode; a cathode; and at least one light-emitting layer between the anode and the cathode, wherein the at least one light-emitting layer comprise a plurality of host materials according to claim 6 .