IP Library Granted Patent US 12,036,107
Granted Patent B2
US 12,036,107 · App. 17/118,388 · Granted Jul 16, 2024

Absorbent articles having antimicrobial properties and methods of manufacturing the same

Inventors: Min Yao (Vernon Hills, IL); Daniel B. Love (Libertyville, IL); Amin Setoodeh (Kildeer, IL); Debashish Chakravarthy (Vernon Hills, IL)
Assignee: Medline Industries, LP
A61F13/8405A61F13/15723A61F13/15804A61F13/51113A61F13/53A61L15/46B32B27/065B32B27/32B32B33/00B32B37/182B32B38/04A61F2013/530481A61F2013/8414A61L2300/206A61L2300/404B32B2307/7145B32B2307/726B32B2307/7265B32B2323/10B32B2555/02
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Quick Facts
Patent No.
US 12,036,107
App. No.
17/118,388
Granted
Jul 16, 2024
Kind
B2
Abstract

According to one embodiment, an absorbent article includes a moisture-impervious outer layer, an inner layer substantially co-extensive with the outer layer, and an absorbent layer interposed between the outer layer and the inner layer. The inner layer is treated with at least one antimicrobial booster. The absorbent layer is treated with at least one antimicrobial agent.

Claims (30)

1. An absorbent article comprising:

a moisture-impervious outer layer;

at least one antimicrobial agent comprising polyhexamethylene biguanide;

at least one antimicrobial booster;

an inner layer formed at least in part from a plastic resin, wherein the at least one antimicrobial booster is mixed with the plastic resin prior to the plastic resin forming the inner layer; and

an absorbent layer interposed between the outer layer and the inner layer, the absorbent layer being treated with the at least one antimicrobial agent,

wherein the at least one antimicrobial booster from the inner layer and the at least one antimicrobial agent from the absorbent layer are configured to be combined when moisture is introduced into the absorbent article during use, the combination providing an effect that increases the effectiveness of the at least one antimicrobial agent.

2. The absorbent article of claim 1 , wherein the effect achieves a microbe kill rate that is greater than the microbe kill rate achieved by the antimicrobial booster or the antimicrobial agent individually.

3. The absorbent article of claim 1 , wherein the effect decreases irritating effects of the antimicrobial agent on a user.

4. The absorbent article of claim 1 , wherein the at least one antimicrobial agent further comprises at least one of cationic antimicrobial polymers, mono-quaternary ammonium salt based antimicrobials, poly-quaternary ammonium salt based antimicrobials, chlorinated phenoxy-based antimicrobials, pyrithione based antimicrobials, cationic polysaccharides, aminopolysaccharides, benzalkonium compounds, nitro compounds, dimethylbenzylammonium chloride, chlorhexidines, crosslinked polyethylene glycols of differing molecular weights, polyethylene glycols of differing molecular weights, hydantoin derivatives with halamine bond, antibiotics, natural extracts with antimicrobial properties, metallic materials, and combinations thereof.

5. The absorbent article of claim 1 , wherein the at least one antimicrobial agent further comprises at least one of trialkoxysilyl quaternary ammonium salt, 3-trimethoxy-silyl-propyldimethyloctadecyl ammonium chloride, polyquat-1, triclosan, zinc pyrithione, chitosan, chitosan derivatives, chitin derivatives, benzalkonium chloride, a mixture of benzalkonium chloride and silver nitrate, 5-nitrofurylacrolein, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, polymycine, neomycin, kanamycin, grisofulvien, grape fruit seed, hops, tea oil, aloe, thyme, rosemary, peppermint, basil, ginger, silver, copper, zinc, zinc oxide, silver oxide, silver chloride, silver nitrate, silver-zinc zeolite, tributylin maleate, and combinations thereof.

6. The absorbent article of claim 1 , wherein the at least one antimicrobial booster comprises one or more of 1,2-hexanediol and 1,2-octanediol.

7. The absorbent article of claim 1 , wherein the at least one antimicrobial booster comprises at least one of aloe, alkyl diols, ethylenediaminetetraacetic acid, 1,2-alkanediol, 1,2-hexanediol, 1,2-octanediol, tropolone, 1,2-decanediol, 1,2-pentanediol, and combinations thereof.

8. The absorbent article of claim 1 , wherein the absorbent layer comprises a fibrous material.

9. The absorbent article of claim 1 , wherein the absorbent article is a diaper, an underpad, or an adult incontinence brief.

10. The absorbent article of claim 1 , wherein the inner layer is formed with the at least one antimicrobial booster at a concentration level of about 0.1% to about 5.0%.

11. The absorbent article of claim 10 , wherein the inner layer is formed with the at least one antimicrobial booster at a concentration level of about 0.5%.

12. An absorbent article comprising:

a moisture-impervious outer layer;

at least one antimicrobial agent comprising polyhexamethylene biguanide;

at least one antimicrobial booster comprising an alkyl diol;

an inner layer formed at least in part from a plastic resin, wherein the at least one antimicrobial booster is mixed with the plastic resin prior to the plastic resin forming the inner layer; and

an absorbent layer interposed between the outer layer and the inner layer, the absorbent layer being treated with the at least one antimicrobial agent,

wherein the at least one antimicrobial booster from the inner layer is configured to combine with the at least one antimicrobial agent from the absorbent layer when moisture is introduced into the article.

13. The absorbent article of claim 12 , wherein the combination achieves a microbe kill rate that is greater than the microbe kill rate achieved by the antimicrobial booster or the antimicrobial agent individually.

14. The absorbent article of claim 12 , wherein the combination decreases irritating effects of the antimicrobial agent on a user when the absorbent article is in use.

15. The absorbent article of claim 12 , wherein the at least one antimicrobial agent further comprises at least one of cationic antimicrobial polymers, mono-quaternary ammonium salt based antimicrobials, poly-quaternary ammonium salt based antimicrobials, chlorinated phenoxy-based antimicrobials, pyrithione based antimicrobials, cationic polysaccharides, aminopolysaccharides, benzalkonium compounds, nitro compounds, dimethylbenzylammonium chloride, chlorhexidines, crosslinked polyethylene glycols of differing molecular weights, polyethylene glycols of differing molecular weights, hydantoin derivatives with halamine bond, antibiotics, natural extracts with antimicrobial properties, metallic materials, and combinations thereof.

16. The absorbent article of claim 12 , wherein the at least one antimicrobial agent further comprises at least one of trialkoxysilyl quaternary ammonium salt, 3-trimethoxy-silyl-propyldimethyloctadecyl ammonium chloride, polyquat-1, triclosan, zinc pyrithione, chitosan, chitosan derivatives, chitin derivatives, benzalkonium chloride, a mixture of benzalkonium chloride and silver nitrate, 5-nitrofurylacrolein, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, polymycine, neomycin, kanamycin, grisofulvien, grape fruit seed, hops, tea oil, aloe, thyme, rosemary, peppermint, basil, ginger, silver, copper, zinc, zinc oxide, silver oxide, silver chloride, silver nitrate, silver-zinc zeolite, tributylin maleate, and combinations thereof.

17. The absorbent article of claim 12 , wherein the inner layer is formed with the at least one antimicrobial booster at a concentration level of about 0.1% to about 5.0%.

18. The absorbent article of claim 17 , wherein the inner layer is formed with the at least one antimicrobial booster at a concentration level of about 0.5%.

Assignments (7)
PATENT SECURITY AGREEMENT Recorded May 28, 2026
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 075643/0462 →
PATENT SECURITY AGREEMENT Recorded Jun 20, 2025
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 071672/0100 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE APPLICATION NUMBER PREVIOUSLY RECORDED AT REEL: 057787 FRAME: 0814. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 1, 2022
From: MEDLINE INDUSTRIES, INC.
To: MEDLINE INDUSTRIES, LP
Reel/Frame 059277/0151 →
SECURITY INTEREST Recorded Oct 21, 2021
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 057927/0091 →
SECURITY INTEREST Recorded Oct 21, 2021
From: MEDLINE INDUSTRIES, LP
To: BANK OF AMERICA, N.A.
Reel/Frame 058040/0001 →
CHANGE OF NAME Recorded Oct 12, 2021
From: MEDLINE INDUSTRIES, INC.
To: MEDLINE INDUSTRIES, LP
Reel/Frame 057787/0814 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 10, 2020
From: YAO, MIN; LOVE, DANIEL B.; CHAKRAVARTHY, DEBASHISH; SETOODEH, AMIN
To: MEDLINE INDUSTRIES, INC.
Reel/Frame 054611/0391 →
Continuity (3)
Division 15397250 · Jan 3, 2017
Continuation 12233215 · Sep 18, 2008
Related Publication 20210085538A1 · Mar 25, 2021