Color electrophoretic layer including microcapsules with nonionic polymeric walls
A capsule comprising a capsule wall and an electrophoretic fluid encapsulated by the capsule wall. The capsule wall comprises a cross-linked nonionic, water-soluble or water-dispersible polymer. The electrophoretic fluid comprises a suspending fluid, first pigment particles, second pigment particles, and third pigment particles. In some embodiments, the electrophoretic fluid includes a fourth electrophoretic particle. The first, second, and third particles are electrically charged, suspended in the suspending fluid, and capable of moving through the suspending fluid upon application of an electric field to the capsule.
1. A capsule comprising a capsule wall and an electrophoretic fluid encapsulated by the capsule wall, in which:
the capsule wall comprises a cured coacervation layer formed from a nonionic polymer and a polyvinyl lactam, the nonionic polymer being a polyol that is water-soluble or water-dispersible and cross-linked; and
the electrophoretic fluid comprises a suspending solvent, first pigment particles, second pigment particles, and third pigment particles, wherein the first, second, and third particles are differently colored, electrically charged, suspended in the suspending fluid, and capable of moving through the suspending fluid upon application of an electric field to the capsule.
2. The capsule according to claim 1 , wherein the polyol is polyvinyl alcohol.
3. The capsule according to claim 1 , wherein the polyvinyl lactam is polyvinylpyrrolidone.
4. The capsule according to claim 1 ; wherein the capsule wall is cross-linked by reaction with a dialdehyde.
5. The capsule according to claim 4 , wherein the dialdehyde is glutaraldehyde.
6. The capsule according to claim 1 , wherein the suspending solvent comprises a hydrocarbon.
7. The capsule according to claim 1 , wherein the electrophoretic fluid further comprises a fourth pigment particle.
8. An electrophoretic medium comprising a plurality of capsules according to claim 1 and a binder surrounding the capsules.
9. An electrophoretic display comprising a layer of an electrophoretic medium according to claim 8 , at least one electrode disposed adjacent the electrophoretic medium and arranged to apply an electric field to the electrophoretic medium.
10. The electrophoretic medium of claim 8 , comprising capsules that have an average diameter between 15 μm and 50 μm, and where less than one third of the capsules (by number) are smaller than 15 μm or larger than 50 μm.
11. An electrophoretic display comprising a layer of an electrophoretic medium according to claim 10 , at least one electrode disposed adjacent the electrophoretic medium and arranged to apply an electric field to the electrophoretic medium.