Negative electrode plate, secondary battery, battery module, battery pack, and apparatus
View Patent ↗This application provides a negative electrode plate, a secondary battery, a battery module, a battery pack, and an apparatus. The negative electrode plate includes a negative current collector and a plurality of active substance layers formed on the negative current collector, where the plurality of active substance layers include at least a first active substance layer and a second active substance layer; the first active substance layer includes a first negative active substance, and the second active substance layer includes a second negative active substance; a ratio of thickness of the negative active substance of the first active substance layer to average particle size of the first negative active substance is 2.0 to 4.0; and a ratio of thickness of the second active substance layer to average particle size of the second negative active substance is 2.2 to 5.0.
1. A secondary battery, comprising a negative electrode plate, wherein the negative electrode plate comprises:
a negative current collector, a first active substance layer disposed on at least one surface of the negative current collector, and a second active substance layer disposed on the first active substance layer;
wherein the first active substance layer comprises a first negative active substance, and the second active substance layer comprises a second negative active substance; and
the following relationships are satisfied: 2.0≤B/A≤4.0, 2.2≤D/C≤5.0 and D/C ≥B/A, wherein
A is an average particle size of the first negative active substance;
B is a thickness of the first active substance layer;
C is an average particle size of the second negative active substance; and
D is a thickness of the second active substance layer.
2. The secondary battery according to claim 1 , wherein 2.5≤B/A≤3.5.
3. The secondary battery according to claim 1 , wherein 2.8≤D/C≤4.5.
4. The secondary battery according to claim 1 , wherein A ≥C.
5. The secondary battery according to claim 4 , wherein 0.4≤C/A≤1.0.
6. The secondary battery according to claim 1 , wherein B ≥D.
7. The secondary battery according to claim 6 , wherein 0.2≤D/B≤1.0.
8. The secondary battery according to claim 1 , wherein 12 μm≤A≤25 μm; or 35 μm≤B≤105 μm; or 4 μm≤C≤18 μm; or 10 μm≤D≤45 μm.
9. The secondary battery according to claim 8 , wherein 15 μm≤A≤19 μm.
10. The secondary battery according to claim 8 , wherein 40 μm≤B≤60 μm.
11. The secondary battery according to claim 8 , wherein 7 μm≤C≤15 μm.
12. The secondary battery according to claim 8 , wherein 20 μm≤D≤40 μm.
13. The secondary battery according to claim 1 , wherein the first negative active substance and the second negative active substance are respectively selected from one or more of artificial graphite, natural graphite, mesocarbon microbeads, soft carbon, and hard carbon.
14. The secondary battery according to claim 13 , wherein a degree of graphitization of the first negative active substance is greater than a degree of graphitization of the second negative active substance.
15. A battery module, comprising a secondary battery, the secondary battery comprising a positive electrode plate, a negative electrode plate, a separator and electrolyte, wherein the negative electrode plate comprises:
a negative current collector, a first active substance layer disposed on at least one surface of the negative current collector, and a second active substance layer disposed on the first active substance layer;
wherein the first active substance layer comprises a first negative active substance, and the second active substance layer comprises a second negative active substance; and
the following relationships are satisfied: 2.0≤B/A≤4.0, 2.2≤D/C≤5.0, and D/C ≥B/A, wherein
A is an average particle size of the first negative active substance;
B is a thickness of the first active substance layer;
C is an average particle size of the second negative active substance; and
D is a thickness of the second active substance layer.
16. The battery module according to claim 15 , wherein the first negative active substance and the second negative active substance are respectively selected from one or more of artificial graphite, natural graphite, mesocarbon microbeads, soft carbon, and hard carbon.
17. An apparatus, comprising a secondary battery, the secondary battery comprising a positive electrode plate, a negative electrode plate, a separator and electrolyte, wherein the negative electrode plate comprises:
a negative current collector, a first active substance layer disposed on at least one surface of the negative current collector, and a second active substance layer disposed on the first active substance layer;
wherein the first active substance layer comprises a first negative active substance, and the second active substance layer comprises a second negative active substance; and
the following relationships are satisfied: 2.0≤B/A≤4.0, 2.2≤D/C≤5.0, and D/C ≥B/A, wherein
A is an average particle size of the first negative active substance;
B is a thickness of the first active substance layer;
C is an average particle size of the second negative active substance; and
D is a thickness of the second active substance layer.
18. The apparatus according to claim 17 , wherein the first negative active substance and the second negative active substance are respectively selected from one or more of artificial graphite, natural graphite, mesocarbon microbeads, soft carbon, and hard carbon.
19. The apparatus according to claim 17 , wherein the apparatus is one selected from the group consisting of a mobile device, an electric vehicle, an electric train, a satellite, a ship, and an energy storage system.