Negative electrode plate and secondary battery
The present application relates to the electrochemical field, and in particular, to a negative electrode plate and a secondary battery including the electrode plate. The present application provides a negative electrode plate. The negative electrode plate includes a negative electrode current collector, a first negative electrode active substance layer disposed on at least one surface of the negative electrode current collector, and a second negative electrode active substance layer disposed on the first negative electrode active substance layer. The first negative electrode active substance layer includes a first negative electrode active substance, and the second negative electrode active substance layer includes a second negative electrode active substance. The first negative electrode active substance satisfies 1 GPa≤Young's modulus≤10 GPa, and the second negative electrode active substance satisfies 11 GPa≤Young's modulus≤30 GPa.
1. A secondary battery, comprising a negative electrode plate, wherein:
the negative electrode plate comprises a negative electrode current collector, a first negative electrode active substance layer disposed on at least one surface of the negative electrode current collector, and a second negative electrode active substance layer disposed on the first negative electrode active substance layer;
the first negative electrode active substance layer comprises a first negative electrode active substance, and the second negative electrode active substance layer comprises a second negative electrode active substance; and
the first negative electrode active substance satisfies 1 GPa≤Young's modulus≤10 GPa, and the second negative electrode active substance satisfies 11 GPa≤Young's modulus≤30 GPa.
2. The secondary battery according to claim 1 , wherein the first negative electrode active substance satisfies 4 GPa≤Young's modulus≤10 GPa.
3. The secondary battery according to claim 2 , wherein the first negative electrode active substance satisfies 6 GPa≤Young's modulus≤10 GPa.
4. The secondary battery according to claim 1 , wherein the second negative electrode active substance satisfies 11 GPa≤Young's modulus≤20 GPa.
5. The secondary battery according to claim 4 , wherein the second negative electrode active substance satisfies 12 GPa≤Young's modulus≤16 GPa.
6. The secondary battery according to claim 1 , wherein a difference between the Young's modulus of the second negative electrode active substance and the Young's modulus of the first negative electrode active substance ranges from 3 GPa to 12 GPa.
7. The secondary battery according to claim 6 , wherein the difference between the Young's modulus of the second negative electrode active substance and the Young's modulus of the first negative electrode active substance ranges from 6 GPa to 10 GPa.
8. The secondary battery according to claim 1 , wherein an average grain size of the first negative electrode active substance ranges from 11 μm to 20 μm; or
a specific surface area of the first negative electrode active substance ranges from 1 m 2 /g to 3 m 2 /g; or
a porosity of the first negative electrode active substance ranges from 25% to 40%.
9. The secondary battery according to claim 1 , wherein an average grain size of the second negative electrode active substance ranges from 1 μm to 10 μm; or
a specific surface area of the second negative electrode active substance ranges from 4 m 2 /g to 8 m 2 /g; or
a porosity of the second negative electrode active substance ranges from 10% to 20%.
10. The secondary battery according to claim 1 , wherein the first negative electrode active substance and/or the second negative electrode active substance are separately selected from one or more of soft carbon, hard carbon, graphite, carbon fiber, carbonaceous mesophase spherule, silicon-based material, tin-based material, and lithium titanate.
11. The secondary battery according to claim 1 , wherein a coating weight per unit area of the first negative electrode active substance layer or the second negative electrode active substance layer ranges from 30 g/m 2 to 150 g/m 2 .
12. The secondary battery according to claim 1 , wherein a thickness of the first negative electrode active substance layer or the second negative electrode active substance layer ranges from 20 μm to 150 μm.
13. The secondary battery according to claim 1 , wherein a porosity of the first negative electrode active substance layer or the second negative electrode active substance layer ranges from 20% to 45%.
14. The secondary battery according to claim 13 , wherein the porosity of the first negative electrode active substance layer or the second negative electrode active substance layer ranges from 25% to 40%.
15. The secondary battery according to claim 1 , wherein a porosity of the second negative electrode active substance layer is greater than or equal to a porosity of the first negative electrode active substance layer.