Electrolytic solution, lithium-ion battery, battery module, battery pack and apparatus
View Patent ↗This application relates to the field of batteries, and in particular, to an electrolytic solution and a lithium-ion battery, a battery module, a battery pack and an apparatus that adopt the electrolytic solution. This application provides an electrolytic solution, including an electrolyte and a solvent, and further including an additive A and an additive B. The additive A is selected from at least one of compounds whose chemical structural formula is denoted by Formula I, and the additive B is selected from at least one of compounds whose chemical structural formula is denoted by Formula II. By using the additive A and the additive B together, this application enables films to be formed on surfaces of a positive electrode plate and a negative electrode plate concurrently, thereby significantly improving cycle performance and high-temperature storage performance of the lithium-ion battery, and also ensuring excellent kinetic performance of the lithium-ion battery.
1. An electrolytic solution, comprising an electrolyte and a solvent, an additive A and an additive B, wherein the additive A comprises:
the additive B comprises a compound selected from at least one of compounds whose chemical structural formula is denoted by Formula II-A:
in Formula II-A, A, B, C, and D, are each independently selected from F, Cl, Br or I.
2. The electrolytic solution according to claim 1 , wherein the additive A further comprises a compound selected from one or more of compounds whose chemical structural formula is denoted by Formula I-B, Formula I-C, or Formula I-D:
wherein, R 3 and R 4 are each independently selected from: H; F; Cl; Br; I; saturated or unsaturated, substituted or unsubstituted C 1 -C 10 aliphatic groups; substituted or unsubstituted C 3 -C 9 cycloalkyls; substituted or unsubstituted C 1 -C 10 alkoxies; substituted or unsubstituted C 6 -C 20 aryls; or, substituted or unsubstituted C 3 -C 20 heteroaryls; and
a value of n 2 is 0, 1, 2, 3, 4, 5, 6, 7, 8, or 9.
3. The electrolytic solution according to claim 1 , wherein the additive B further comprises a compound selected from at least one of compounds denoted by Formula II-B:
wherein, J and K are each independently selected from F, Cl, Br or I.
4. The electrolytic solution according to claim 1 , wherein a mass of the additive A is 0.01%-10% of a total mass of the electrolytic solution;
a mass of the additive B is 0.01%-10% of the total mass of the electrolytic solution; and
a mass ratio of the additive A to the additive B is 1:0.1 to 1:10.
5. The electrolytic solution according to claim 1 , wherein a mass of the additive A is 0.1%-6% of a total mass of the electrolytic solution;
a mass of the additive B is 0.1%-5% of the total mass of the electrolytic solution; and
a mass ratio of the additive A to the additive B is 1:0.1 to 1:10.
6. The electrolytic solution according to claim 1 , wherein the electrolyte comprises LiPF 6 .
7. The electrolytic solution according to claim 1 , further comprising an additive C, wherein the additive C comprises a cyclic sulfate compound containing an S═O group.
8. The electrolytic solution according to claim 7 , wherein a chemical structural formula of the cyclic sulfate compound containing an S═O group is denoted by Formula III:
wherein, R 6 and R 7 are each independently selected from: H; F; Cl; Br; I; saturated or unsaturated, substituted or unsubstituted C 1 -C 10 aliphatic groups; substituted or unsubstituted C 3 -C 9 cycloalkyls; substituted or unsubstituted C 1 -C 10 alkoxies; substituted or unsubstituted C 6 -C 20 aryls; or, substituted or unsubstituted C 3 -C 20 heteroaryls.
9. The electrolytic solution according to claim 7 , wherein a chemical structural formula of the cyclic sulfate compound containing an S═O group is denoted by Formula III:
wherein, R 6 and R 7 are each independently selected from H.
10. The electrolytic solution according to claim 7 , wherein a mass of the additive C is 0.1%-8% of a total mass of the electrolytic solution.
11. The electrolytic solution according to claim 7 , wherein a mass of the additive C is 0.1%-5% of a total mass of the electrolytic solution.
12. The electrolytic solution according to claim 1 , wherein the additive A further comprises at least one of compounds denoted by:
13. The electrolytic solution according to claim 6 , wherein the electrolyte further comprises one or more of LiBF 4 , LIN(SO 2 F) 2 , LIN(CF 3 SO 2 ) 2 , LiClO 4 , LiAsF 6 , LiB(C 2 O 4 ) 2 , LiBF 2 (C 2 O 4 ), LIN(SO 2 R F ) 2 , or LIN(SO 2 F)(SO 2 R F ), wherein R F is C n′ F 2n′+1 , and n′ is 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.
14. A lithium-ion battery, comprising a positive electrode plate, a negative electrode plate, a separator located between the positive electrode plate and the negative electrode plate, and an electrolytic solution, wherein the electrolytic solution comprises an electrolyte and a solvent, an additive A and an additive B, wherein the additive A comprises:
the additive B comprises a compound selected from at least one of compounds whose chemical structural formula is denoted by Formula II-A:
in Formula II-A, A, B, C, and D are each independently selected from F, Cl, Br or I.
15. The lithium-ion battery according to claim 14 , wherein the negative electrode plate comprises artificial graphite.
16. The lithium-ion battery according to claim 14 , wherein the negative electrode plate comprises SiOx (x: 0.9-1.8); with respect to 1 gram of the SiOx, a mass of the additive A is 0.0005 g-0.01 g.
17. The lithium-ion battery according to claim 15 , wherein a thickness of an active substance layer on a single side of the negative electrode plate is 30 μm-85 μm.
18. The lithium-ion battery according to claim 14 , wherein the positive electrode plate comprises a positive electrode active substance, and the positive electrode active substance comprises at least one of compounds denoted by Formula IV:
Li 1+y Ni a Co b Me 1-a-b O 2-z A z IV
in Formula IV, −0.1≤y≤0.2, 0.5<a<0.9, 0<b<0.5, 0.5<a+b<1, 0≤z<0.2, Me comprises one or more of Mn, Fe, Cr, Ti, Zn, V, Al, Zr, or Ce, and A comprises one or more of S, N, F, Cl, Br, or I.
19. An apparatus, comprising the lithium-ion battery according to claim 14 .
20. The apparatus according to claim 19 , wherein the apparatus comprises an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, an electric bicycle, an electric scooter, an electric golf cart, an electric truck, an electric ship, and an energy storage system.