Positive electrode lithium replenishment material, preparation method and uses thereof
The present application relates to a positive electrode lithium replenishment material, and a preparation method thereof. The positive electrode lithium replenishment material, includes a first lithium-containing compound selected from one or more of compounds whose chemical formula is denoted by Formula I, Li x A y , 0<x, y≤3. An outer layer of the positive electrode lithium replenishment material includes a second lithium-containing compound. An activity of reacting with water by the second lithium-containing compound is lower than that by the first lithium-containing compound. The positive electrode lithium replenishment material can effectively prevent a gelling phenomenon in a slurry preparation process, and slow down inactivation of the lithium replenishment material caused by a reaction between the electrode plate with moisture and carbon dioxide in the air during storage of the electrode plate, thereby increasing manufacturability of lithium-ion batteries replenished with lithium, and improving the electrochemical performance of the lithium-ion batteries.
1 . A positive electrode lithium replenishment material for replenishing a positive electrode of a lithium-ion battery with lithium, the positive electrode lithium replenishment material are particles comprising a first lithium-containing compound denoted by Formula I:
Li x C y Formula I
wherein,
0<x, y≤3;
a particle diameter . . . 0.05-10 μm;
an outer layer is coated on the particles of the positive electrode lithium replenishment material, the outer layer comprises a second . . . , and an activity of the second lithium-containing compound reacting with water is lower than that of the first lithium-containing compound;
the second lithium-containing compound is selected from . . . , or a lithium ascorbate; and
a mass percent of the second lithium-containing compound in the positive electrode lithium replenishment material is 1-30%.
2 . The positive electrode lithium replenishment material according to claim 1 , wherein the second lithium-containing compound is formed by reaction of the first lithium-containing compound.
3 . The positive electrode lithium replenishment material according to claim 1 , wherein a thickness range of the outer layer is 1-100 nm.
4 . The positive electrode lithium replenishment material according to claim 1 , wherein the particle diameter distribution range is 0.2-4 μm.
5 . A positive electrode plate, comprising a positive electrode current collector and a positive electrode active substance layer located on the positive electrode current collector, wherein
the positive electrode active substance layer comprises a positive electrode active substance, a binder, a conductive agent, and a positive electrode lithium replenishment material; the positive electrode lithium replenishment material further comprises a plurality of particles, an outer layer is coated on the plurality of particles; and the positive electrode lithium replenishment material comprises a first lithium-containing compound denoted by Formula I:
Li x C y Formula I
wherein,
0<x, y≤3;
a particle diameter . . . 0.05-10 μm;
the outer layer comprises a second lithium-containing compound, and an activity of the second lithium-containing compound reacting with water is lower than that of the first lithium-containing compound;
the second lithium-containing compound is selected from . . . , or a lithium ascorbate; and
a mass percent of the second lithium-containing compound in the positive electrode lithium replenishment material is 1-30%.
6 . The positive electrode plate according to claim 5 , wherein the binder comprises a fluorine-containing polyolefin-based binder.
7 . The positive electrode plate according to claim 5 , wherein a mass percent of the positive electrode lithium replenishment material in the positive electrode active substance layer is 0.2%-10%.
8 . A lithium-ion battery, comprising a positive electrode plate,
wherein the positive electrode plate comprises a positive electrode current collector and a positive electrode active substance layer located on the positive electrode current collector, wherein
the positive electrode active substance layer comprises a positive electrode active substance, a binder, a conductive agent, and a positive electrode lithium replenishment material; the positive electrode lithium replenishment material further comprises a plurality of particles, wherein each particle has an inner layer and an outer layer, the inner layer comprises a first lithium-containing compound selected from one or more of compounds whose chemical formula is denoted by Formula I:
Li x A y Formula I
wherein, A is C, 0<x, y≤3, and the compounds denoted by Formula I is not Li 2 O;
a particle diameter distribution range of the positive electrode lithium replenishment material is 0.05-10 μm; and
the outer layer comprises a second lithium-containing compound, and an activity of reacting with water by the second lithium-containing compound is lower than that by the first lithium-containing compound,
wherein the second lithium-containing compound is selected from one or more of Li 2 CO 3 , Li 2 SO 4 , a lithium sulfite, a lithium oxalate, or a lithium ascorbate.
9 . The positive electrode lithium replenishment material according to claim 1 , wherein the compound denoted by Li x C y is Li 2 C 2 .
10 . The positive electrode lithium replenishment material according to claim 1 , wherein a mass percent of the second lithium-containing compound in the positive electrode lithium replenishment material is 2-10%.
11 . The positive electrode lithium replenishment material according to claim 1 , wherein a thickness range of the outer layer is 2-50 nm.