THERMAL MANAGEMENT MULTILAYER SHEET FOR A BATTERY
An assembly for a battery including a thermal management multilayer sheet disposed on a surface of an electrochemical cell, the thermal management multilayer sheet including a thermally-insulating layer, a first heat-spreading layer disposed on a first side of the thermally-insulating layer, and a second heat-spreading layer disposed on a second side of the thermally-insulating layer.
1 . An assembly for a battery, comprising
a thermal management multilayer sheet disposed on a surface of an electrochemical cell,
the thermal management multilayer sheet comprising
a thermally-insulating layer,
a first heat-spreading layer disposed on a first side of the thermally-insulating layer, and
a second heat-spreading layer disposed on a second side of the thermally-insulating layer.
2 . The assembly for a battery of claim 1 , wherein the thermal management multilayer sheet is disposed on at least two surfaces of the electrochemical cell.
3 . The assembly for a battery of claim 1 , wherein the electrochemical cell comprises a prismatic cell, a pouch cell, or a cylindrical cell.
4 . The assembly for a battery of claim 1 , wherein the first and second heat-spreading layers each independently have a thickness of 5 to 1,000 micrometers.
5 . The assembly for a battery of any claim 1 , wherein the first and second heat-spreading layers each independently comprise copper, aluminum, silver, a copper alloy, an aluminum alloy, a silver alloy, boron nitride, aluminum nitride, silicon carbide, beryllium oxide, carbon fibers, carbon nanotubes, graphene, graphite, or a combination thereof.
6 . The assembly for a battery of claim 1 , wherein the thermally-insulating layer has a thickness of 50 to 15,000 micrometers.
7 . The assembly for a battery of claim 1 , wherein the thermally-insulating layer has a thermal conductivity of 0.01 to 1.0 W/m*K at 23° C., a heat of fusion of 70 to 350 J/g, or both.
8 . The assembly for a battery of claim 1 , wherein the thermally-insulating layer comprises mica, vermiculite, a zeolite, an aerogel, a polymer foam, polymer fibers, a cork, a fiberglass, or a combination thereof.
9 . The assembly for a battery of claim 1 , wherein the thermally-insulating layer is compressible, and has a compression set at 158° F. (70° C.) of less than 10%, measured according to ASTM D 3574-95 Test D.
10 . The assembly for a battery of claim 9 , wherein the thermally-insulating layer comprises a compressible elastomeric polymer.
11 . The assembly for a battery of claim 9 , wherein the thermally-insulating layer comprises a compressible polymer foam.
12 . The assembly for a battery of claim 11 , wherein the compressible polymer foam has a density of 80 to 481 kg/m 3 , a 25% compression force deflection of 351.5 to 70,307 kg/m 2 , measured according to ASTM D 3574-95 Test C, and a compression set at 158° F. (70° C.) of less than 10%.
13 . The assembly for a battery of claim 11 , wherein the compressible polymer foam is in the form of a layer having an uncompressed thickness 250 to 15,000 micrometers.
14 . The assembly for a battery of claim 1 , further comprising an adhesive layer disposed between the first heat-spreading layer and the thermally-insulating layer.
15 . The assembly for a battery of claim 14 , wherein the adhesive layer further comprises a particulate filler.
16 . The assembly for a battery of claim 1 , further comprising an integrity layer comprising a heat resistant reinforcement material disposed between the first heat-spreading layer and the thermally-insulating layer.
17 . The assembly for a battery of claim 16 , wherein the heat resistant reinforcement material comprises a woven or nonwoven mat comprising a high heat resistance polymer or glass.
18 . The assembly for a battery of claim 16 , wherein the integrity layer has a thickness of 20 to 600 micrometers.
19 . The assembly for a battery of claim 1 , wherein the thermal management multilayer sheet comprises, in order,
the first heat-spreading layer;
a first integrity layer;
a first adhesive layer;
the thermally-insulating layer;
a second adhesive layer;
a second integrity layer; and
the second heat-spreading layer.
20 . The assembly for a battery of claim 1 , wherein the assembly comprises at least two electrochemical cells.
21 . A battery, comprising:
the assembly for a battery of claim 1 ; and
a housing at least partially enclosing the assembly for a battery.
22 . A thermal management multilayer sheet, comprising
a first high temperature laminate adhered to a first side of a compressible thermally-insulating layer; and
a second high temperature laminate adhered to a second opposite side of the compressible thermally-insulating layer,
wherein the first high temperature laminate film comprises
a first heat-spreading layer disposed on a first side of a first integrity layer, and
a first adhesive layer disposed on an opposite second side of the first integrity layer, wherein the first adhesive layer adheres the first high temperature laminate film to the first side of the compressible thermally-insulating layer, and
wherein the second high temperature laminate film comprises
a second heat-spreading layer disposed on a first side of a second integrity layer, and
a second adhesive layer disposed on an opposite second side of the second integrity layer, wherein the second adhesive layer adheres the second high temperature laminate film to the second side of the compressible thermally-insulating layer.
23 . An assembly for a battery, comprising
the thermally-insulating multilayer sheet of claim 22 , disposed on an electrochemical cell.
24 . The assembly for a battery of claim 23 , wherein the assembly comprises
at least two electrochemical cells.
25 . A battery, comprising:
the assembly for a battery of any one of claim 23 ; and
a housing at least partially enclosing the assembly for a battery.