Method of producing ethylene-carboxylic acid compolymer
In a method of producing an ethylene-carboxylic acid copolymer, a monomer solution containing a carboxylic acid monomer is supplied from a discharging unit. The carboxylic acid monomer is copolymerized with an ethylene-based monomer. A coefficient of friction between the discharging unit and the monomer solution is maintained as 0.3 or less.
1. A method of producing an ethylene-carboxylic acid copolymer, comprising:
supplying a monomer solution containing a carboxylic acid monomer from a discharging unit; and
copolymerizing the carboxylic acid monomer with an ethylene-based monomer,
wherein a coefficient of friction between the discharging unit and the monomer solution is maintained as 0.3 or less,
wherein the coefficient of friction between the discharging unit and the monomer solution is defined as a value measured by using a Mini-Traction Machine 2 while rotating a disk and a ball therein,
wherein a slide roll ratio between the disk and the ball is in a range of 0% to 70%,
wherein the disk has the same surface roughness as that of the discharging unit,
wherein a temperature in the Mini-Traction Machine 2 is the same as that in the discharging unit, and
wherein a pressure in the Mini-Traction Machine 2 is the same as a contact pressure in the discharging unit.
2. The method of claim 1 , wherein the coefficient of friction between the discharging unit and the monomer solution is maintained as 0.1 or less.
3. The method of claim 1 , wherein the discharging unit comprises a piston and a packing unit surrounding the piston.
4. The method of claim 3 , wherein the coefficient of friction between a surface of the piston and the monomer solution, and the coefficient of friction between the packing unit and the monomer solution are all maintained as 0.3 or less.
5. The method of claim 3 , wherein the piston and the packing unit each has a surface roughness (Ra) of less than 75 nm.
6. The method of claim 3 , wherein the piston and the packing unit each has a surface roughness (Ra) of 2 nm or less.
7. The method of claim 1 , wherein the temperature in the discharging unit is 85° C. or less.
8. The method of claim 1 , wherein the temperature in the discharging unit is from 20° C. to 60° C.
9. The method of claim 1 , further comprising supplying a lubricating composition into the discharging unit.
10. The method of claim 9 , wherein an amount of dissolved oxygen in the lubricating composition is 10 ppm or less.
11. The method of claim 9 , wherein the lubricating composition includes a base oil and a phenothiazine-based polymerization inhibitor, and an amount of the polymerization inhibitor in the lubricating composition is from 0.1 ppm to 10 ppm.
12. The method of claim 1 , wherein the copolymerizing the carboxylic acid monomer with the ethylene-based monomer comprises injecting the ethylene-based monomer after the monomer solution is supplied from the discharging unit.
13. The method of claim 1 , wherein the monomer solution further includes the ethylene-based monomer, and
wherein the copolymerizing the carboxylic acid monomer with the ethylene-based monomer comprises injecting the monomer solution containing the carboxylic acid monomer and the ethylene-based monomer into a reactor from the discharging unit.