IP Library Granted Patent US 11,766,822
Granted Patent B2
US 11,766,822 · App. 17/182,507 · Granted Sep 26, 2023

Microstructured surface with increased microorganism removal when cleaned, articles and methods

Inventors: Jodi L. Connell (St. Paul, MN); Raymond P. Johnston (Lake Elmo, MN); John J. Sullivan (Hudson, WI); Karl J. L. Geisler (St. Paul, MN); Vivian W. Jones (Woodbury, MN); Gordon A. Kuhnley (St. Paul, MN); Patrick G. Zimmerman (Mendota Heights, MN); Bradley W. Eaton (Woodbury, MN); Kurt J. Halverson (Lake Elmo, MN); Brian W. Lueck (Houlton, WI); Alexander C. Eldredge (Mahtomedi, MN); Hyacinth L. Lechuga (St. Paul, MN)
Assignee: 3M Innovative Properties Company
B29C59/022B08B17/065B29C51/02B29C51/14B29C2059/023B29L2031/756B32B37/12B32B2307/754
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Quick Facts
Patent No.
US 11,766,822
App. No.
17/182,507
Granted
Sep 26, 2023
Kind
B2
Abstract

Films and articles are described comprising a microstructured surface having an array of peak structures and adjacent valleys. For improved cleanability, the valleys preferably have a maximum width ranging from 10 microns to 250 microns and the peak structures have a side wall angle greater than 10 degrees. The peak structures may comprise two or more facets such as in the case of a linear array of prisms or an array of cube-corners elements. The facets form continuous or semi-continuous surfaces in the same direction. The valleys typically lack intersecting walls. Also described are methods of making and methods of use. The microstructured surface of the article can be prepared by various microreplication techniques such as coating, injection molding, embossing, laser etching, extrusion, casting and curing a polymerizable resin; and bonding microstructured film to a surface or article with an adhesive.

Claims (41)

1. A method of providing an article having a surface with increased microorganism removal when cleaned comprising:

providing a microstructured surface on an article wherein the microstructured surface comprises an array of peak structures and adjacent valleys wherein the valleys have a maximum width ranging from 5 microns to 250 microns and the peak structures have a side wall angle of greater than 10 degrees and the microstructured surface comprises less than 30% of flat surface area that is parallel to a planar base layer, wherein the microstructured surface can provide a mean log 10 reduction of bacteria of at least 2 after cleaning.

2. The method of claim 1 wherein the peak structures comprise two or more facets and the facets form continuous or semi-continuous surfaces in the same direction.

3. The method of claim 1 wherein the microstructured surface comprises a linear array of prisms or an array of cube-corners elements including preferred geometry cube corner elements.

4. The method of claim 1 wherein peak structures have an apex that is sharp, rounded or truncated.

5. The method of claim 1 wherein the peak structures have an apex angle ranging from 20 to 120 degrees.

6. The method of claim 1 wherein the peak structures and valleys are free of flat surface area that is parallel to the planar base layer.

7. The method of claim 1 wherein the valleys lack intersecting walls.

8. The method of claim 1 wherein the article is not a sterile implantable medical article, an orthodontic appliance or orthodontic brackets.

9. The method of claim 1 wherein the article is an interior component of a vehicle housing or case of an electronic device; a handle; food preparation article; food preparation container; utensil; furniture; desktop, flooring, countertop, window sill; component of a lavatory; toothbrush; protective athletic equipment; or playground equipment.

10. The method of claim 1 wherein the microstructured surface is provided on the article by

providing a film comprising the microstructured surface disposed on a planar base layer; and a pressure sensitive adhesive on the opposing surface of the film; and

bonding the film to the article with the pressure sensitive adhesive.

11. The method of claim 1 wherein the microstructured surface is provided on the article by

providing a base member comprising the microstructured surface wherein the peak structures have a melt temperature greater than the base member;

thermoforming the base member into an article at a temperature below the melt temperature of the peak structures.

12. The method of claim 1 wherein the microstructured surface can provide a mean log 10 reduction of bacteria of at least 3 after cleaning.

13. The method of claim 1 wherein the microstructured surface can provides a reduction in bacteria touch transfer in a range of 50% to 99%.

14. A method of cleaning an article comprising:

providing an article of claim 1 ;

cleaning the microstructured surface.

15. The method of claim 14 wherein cleaning comprises

a) wiping the microstructured surface with a woven or non-woven material;

b) scrubbing the microstructured surface with a brush;

c) applying an antimicrobial solution to the microstructured surface; or

a combination thereof.

16. The method of claim 1 wherein the microstructured surface is exposed to the environment and is subject to be touched or otherwise coming in contact with people and/or animals.

17. The method of claim 1 wherein at least 90% of the microstructured surface comprises cleaning solution 1-3 minutes after applying the cleaning solution to the microstructured surface.

18. The method of claim 1 wherein the microstructured surface has a Sbi/Svi of greater than 3 and less than 90.

19. The method of claim 1 wherein the microstructured surface can provide a mean log 10 reduction of a bacteriophage or virus of at least 2 after cleaning.

20. The method of claim 1 wherein the microstructured surface does not comprise a material selected from the group consisting of a low surface energy material, a fluorinated material, and a polydimethylsiloxane material.

21. The method of claim 1 wherein the peaks have a height of at least 2 microns.

22. The method of claim 1 wherein the microstructured surface is present on a macrostructured surface.

23. The method of claim 1 wherein the microstructured surface lacks a significant number of structures with smaller valleys and/or valleys with insufficient side wall angles that can impede bacteria cleanability.

24. The method of claim 1 wherein the microstructured surface lacks a significant number of structures with smaller valleys and/or valleys with insufficient side wall angles that can impede dirt removal.

25. The method of claim 1 wherein the microstructured surface can provide a mean log 10 reduction of bacteria of at least 4 after cleaning.

26. The method of claim 1 wherein the microstructured surface can provide a mean log 10 reduction of bacteria of at least 6 after cleaning.

27. The method of claim 1 wherein the microstructured surface can provide a mean log 10 reduction of bacteria of at least 8 after cleaning.

28. The method of claim 1 wherein the peaks have a height of at least 3 microns.

29. The method of claim 1 wherein the peaks have a height of at least 4 microns.

30. The method of claim 1 wherein the peaks have a height of at least 5 microns.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 1, 2024
From: 3M INNOVATIVE PROPERTIES COMPANY
To: SOLVENTUM INTELLECTUAL PROPERTIES COMPANY
Reel/Frame 066433/0049 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 27, 2021
From: CONNELL, JODI L.; JOHNSTON, RAYMOND P.; SULLIVAN, JOHN J.; GEISLER, KARL J.L.; JONES, VIVIAN W.; KUHNLEY, GORDON A.; ZIMMERMAN, PATRICK G.; EATON, BRADLEY W.; HALVERSON, KURT J.; LUECK, BRIAN W.; ELDREDGE, ALEXANDER C.; LECHUGA, HYACINTH L.
To: 3M INNOVATIVE PROPERTIES COMPANY
Reel/Frame 056368/0264 →
Continuity (6)
Continuation In Part PCTIB2020057840 · Aug 20, 2020
Provisional Application 63142688 · Jan 28, 2021
Provisional Application 63067701 · Aug 19, 2020
Provisional Application 63027412 · May 20, 2020
Provisional Application 62889088 · Aug 20, 2019
Related Publication 20210187819A1 · Jun 24, 2021