Organic electroluminescent compound, a plurality of host materials, and organic electroluminescent device comprising the same
The present disclosure relates to an organic electroluminescent compound represented by formula 2-1, a plurality of host materials comprising a first host material comprising a compound represented by formula 1, and a second host material comprising a compound represented by formula 2, and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound according to the present disclosure as a single host material, or the specific combination of compounds according to the present disclosure as a plurality of host materials, it is possible to provide an organic electroluminescent device having lower driving voltage, higher luminous efficiency, and/or improved lifetime properties, compared to conventional organic electroluminescent devices.
1 . A plurality of host materials comprising a first host material comprising a compound represented by the following formula 1-2, and a second host material comprising a compound represented by the following formula 2:
in formula 1,
X 1 represents —N═;
Y 1 represents —O— or —S—;
L 1 represents a single bond, or a substituted or unsubstituted (C6-C30)arylene;
R 31 and R 32 , each independently, represent a substituted or unsubstituted dibenzofuranyl, a substituted or unsubstituted dibenzothiophenyl, a substituted or unsubstituted benzofuropyridyl, a substituted or unsubstituted benzonaphthofuranyl, or a substituted or unsubstituted benzonaphthothiophenyl;
R 1 represents a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
R 2 to R 4 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted fused ring group of a (C3-C30) aliphatic ring(s) and a (C6-C30) aromatic ring(s), or -L 3 -N(Ar 1 )(Ar 2 ); or may be linked to an adjacent substituent to form a ring(s);
L 3 , each independently, represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
Ar 1 and Ar 2 , each independently, represent hydrogen, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted fused ring group of a (C3-C30) aliphatic ring(s) and a (C6-C30) aromatic ring(s), a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; and
a and b, each independently, represent an integer of 1 or 2, and c represents an integer of 1 to 3, where if a to c are an integer of 2 or more, each of R 2 , each of R 3 , and each of R 4 may be the same or different;
in formula 2,
HAr represents a substituted with deuterium or unsubstituted (3- to 20-membered)heteroaryl containing a nitrogen atom(s);
L 2 , each independently, represents a substituted with deuterium or unsubstituted phenylene;
Ar 2 , each independently, represents a phenyl unsubstituted or substituted with deuterium, a naphthyl unsubstituted or substituted with deuterium, a phenylnaphthyl unsubstituted or substituted with deuterium or a naphthylphenyl unsubstituted or substituted with deuterium;
wherein one of Ar 2 represents a phenylnaphthyl unsubstituted or substituted with deuterium or a naphthylphenyl unsubstituted or substituted with deuterium;
d represents an integer of 2 to 3, where each of ((L 2 ) e -Ar 2 ) may be the same or different;
e represents an integer of 0 to 1; and
* represents a site linked to L 2 .
2 . The plurality of host materials according to claim 1 , wherein the substituents of the substituted alkyl, the substituted alkenyl, the substituted aryl, the substituted arylene, the substituted heteroaryl, the substituted heteroarylene, the substituted heteroaryl containing a nitrogen atom(s), the substituted cycloalkyl, the substituted alkoxy, the substituted trialkylsilyl, the substituted dialkylarylsilyl, the substituted alkyldiarylsilyl, the substituted triarylsilyl, and the substituted fused ring group of an aliphatic ring(s) and an aromatic ring(s), each independently, are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a phosphineoxide; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s); a (C6-C30)aryl unsubstituted or substituted with at least one of a (C1-C30)alkyl(s) and a (3- to 30-membered)heteroaryl(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; a fused ring group of a (C3-C30) aliphatic ring(s) and a (C6-C30) aromatic ring(s); an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C2-C30)alkenylamino; a (C1-C30)alkyl(C2-C30)alkenylamino; a mono- or di-(C6-C30)arylamino; a (C1-C30)alkyl(C6-C30)arylamino; a mono- or di-(3- to 30-membered)heteroarylamino; a (C1-C30)alkyl(3- to 30-membered)heteroarylamino; a (C2-C30)alkenyl(C6-C30)arylamino; a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino; a (C6-C30)aryl(3- to 30-membered)heteroarylamino; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a (C6-C30)arylphosphine; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.
3 . The plurality of host materials according to claim 1 , wherein the formula 2 is represented by at least one of the following formulas 2-1 to 2-3:
wherein
A 1 to A 24 , each independently, represent CR 10 or N, in which at least one of A 1 to A 6 represents N, at least one of A 7 to A 14 represents N, and at least one of A 15 to A 24 represents N;
R 10 , each independently, represents hydrogen or -L 2 -Ar 2 , where if a plurality of R 10 's are present, each of R 10 may be the same or different; and
L 2 , Ar 2 , d, and e are as defined in claim 1 .
4 . The plurality of host materials according to claim 1 , wherein the compound represented by formula 1-2 is at least one selected from the following compounds:
5 . The plurality of host materials according to claim 1 , wherein the compound represented by formula 2 is at least one selected from the following compounds:
6 . An organic electroluminescent device comprising an anode, a cathode, and at least one light-emitting layer between the anode and the cathode, wherein at least one of the light-emitting layers comprises the plurality of host materials according to claim 1 .