Cast lens
An ophthalmic lens incorporating an optically functional wafer having improved adhesion to a polymerized polyurea-urethane bulk lens resin.
1. A method of forming an ophthalmic lens comprising:
obtaining an optically functional wafer;
coating the optically functional wafer with an adhesion improving coating to form a coated optically functional wafer;
positioning the coated optically functional wafer within a cavity of a lens mold assembly;
introducing a mixture of an aliphatic diisocyanate component, a dual amine/hydroxyl component comprising an amino and a hydroxyl functional group in the same molecule and a hydroxyl-containing component or a mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component to form a polyurea-urethane lens resin into the cavity of the lens mold adjacent to the adhesion improving coating of the coated optically functional wafer; and
polymerizing the polyurea-urethane lens resin within the cavity of the lens mold.
2. The method of claim 1 , wherein obtaining said optically functional wafer comprises obtaining said optically functional wafer formed into a desired base curvature.
3. The method of claim 1 , wherein positioning the coated optically functional wafer within said cavity of said lens mold assembly comprises positioning the coated optically functional wafer within a casting mold gasket.
4. The method of claim 1 , wherein coating the optically functional wafer comprises coating the optically functional wafer with an aqueous polycarbonate polyurethane dispersion.
5. The method of claim 1 , wherein introducing the polyurea-urethane lens resin into the cavity of the lens mold comprises introducing a layer of the polyurea-urethane lens resin adjacent to the adhesion improving coating on a first side and on a second side of the coated optically functional wafer.
6. The method of claim 1 , wherein introducing said mixture of said aliphatic diisocyanate component, said dual amine/hydroxyl component and a hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component into said cavity of said lens mold further comprises:
mixing said aliphatic diisocyanate component with said dual amine/hydroxyl component and said hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component such that a ratio of isocyanate to a sum of amino and hydroxyl functionalities is in a range of 0.9 to 1.1.
7. A method of forming an ophthalmic lens comprising:
obtaining an optically functional wafer having a first side and a second side;
coating said first side with an adhesion improving coating to form a coated first side and said second side with said adhesion improving coating to form a coated second side;
positioning said optically functional wafer having said coated first side and said coated second side within a cavity of a lens mold assembly;
adding a mixture of an aliphatic diisocyanate component, a dual amine/hydroxyl component comprising an amino and a hydroxyl functional group in the same molecule and a hydroxyl-containing component or a mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component to form a first and second layers of a polyurea-urethane lens resin onto said coated first side and said coated second side of said optically functional wafer;
polymerizing said first layer of polyurea-urethane lens resin onto said coated first side and said second layer of the polyurea-urethane lens resin onto said coated second side of said optically functional wafer to form said ophthalmic lens; and
removing said lens mold assembly from said ophthalmic lens.
8. The method of claim 7 , wherein coating said first side with said adhesion improving coating to form said coated first side and said second side with said adhesion improving coating to form said coated second side further comprises coating said first side and said second side with an aliphatic polycarbonate polyurethane dispersion.
9. The method of claim 7 , wherein coating said first side with said adhesion improving coating to form said coated first side and said second side with said adhesion improving coating to form said coated second side further comprises coating said first side and said second side with a polysiloxane.
10. The method of claim 7 , wherein adding said mixture of said aliphatic diisocyanate component, said dual amine/hydroxyl component and a hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component onto said coated first side and said coated second side of said optically functional wafer further comprises:
mixing said aliphatic diisocyanate component with said dual amine/hydroxyl component and said hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component such that a ratio of isocyanate to a sum of amino and hydroxyl functionalities is in a range of 0.9 to 1.1.
11. A method for forming an ophthalmic lens comprising:
obtaining an optically functional wafer having at least one protective layer;
treating said optically functional wafer having said at least one protective layer with a wafer treatment comprising an aliphatic polycarbonate polyurethane dispersion or a polysiloxane to form a coated optically functional wafer having said at least one protective layer;
positioning said coated optically functional wafer having said at least one protective layer within a casting mold gasket comprising a front glass mold, a gasket and a back glass mold;
adding a mixture of an aliphatic diisocyanate component, a dual amine/hydroxyl component comprising an amino and a hydroxyl functional group in the same molecule and a hydroxyl-containing component or a mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component to form a polyurea-urethane lens resin into said casting mold gasket to further coat said coated optically functional wafer having said at least one protective layer;
polymerizing said polyurea-urethane lens resin within said casting mold gasket; and
removing said casting mold gasket from said ophthalmic lens.
12. The method of claim 11 , wherein obtaining said optically functional wafer having said at least one protective layer further comprises embedding said optically functional wafer in between two protective layers.
13. The method of claim 11 , wherein obtaining said optically functional wafer having said at least one protective layer further comprises obtaining said optically functional wafer having at least one polycarbonate protective layer.
14. The method of claim 11 , wherein treating said optically functional wafer having said at least one protective layer with wafer treatment further comprises dip coating said optically functional wafer having said at least one protective layer with said aliphatic polycarbonate polyurethane dispersion or said polysiloxane.
15. The method of claim 11 , wherein adding said mixture of said aliphatic diisocyanate component, said dual amine/hydroxyl component and said hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component to further coat said coated optically functional wafer having said at least one protective layer further comprises:
mixing said aliphatic diisocyanate component with said dual amine/hydroxyl component and said hydroxyl-containing component or said mixture of said aliphatic diisocyanate component and said dual amine/hydroxyl component such that a ratio of isocyanate to a sum of amino and hydroxyl functionalities is in a range of 0.9 to 1.1.
16. The method of claim 11 , wherein adding said polyurea-urethane lens resin into said casting mold gasket further comprises introducing a layer of the polyurea-urethane lens resin to further coat a coated first side and a coated second side of said optically functional wafer having said at least one protective layer.
17. The method of claim 11 , wherein obtaining an optically functional wafer having said at least one protective layer comprises obtaining said optically functional wafer having said at least one protective layer formed into a desired base curvature.