Accessories for optical spectrometers
Accessories for improving sensitivity or efficiency of optical spectrometers and methods for utilizing such accessories are disclosed.
1. A system for improving a reflectance spectrum of a diffusive sample, comprising:
an optical spectrometer;
a light source; and
an encasement, comprising:
(i) an outer surface;
(ii) an inner surface defining a cavity and partially or completely enclosing said light source and said optical spectrometer in said cavity, wherein said optical spectrometer is positioned at a center of a floor of said inner surface and wherein said outer surface, a ceiling of said inner surface, and said floor of said inner surface are in optical communication with said diffusive sample, wherein said diffusive sample is positioned outside of said cavity; and
wherein said encasement is disposed relative to each of said optical spectrometer and said light source such that light emitted by said light source achieves at least two optical interactions with said diffusive sample before being received by said optical spectrometer.
2. The system of claim 1 , wherein said outer surface is hemispherical.
3. The system of claim 1 , wherein said outer surface is transparent.
4. The system of claim 1 , wherein said outer surface is translucent.
5. The system of claim 1 , wherein said floor of said inner surface has a reflectivity greater than 98% over a range of wavelengths of light detected by said optical spectrometer.
6. The system of claim 1 , wherein said floor of said inner surface comprises a diffuse reflective material.
7. The system of claim 6 , wherein said diffuse reflective material comprises a diffuse white reflector.
8. The system of claim 6 , wherein said diffuse reflective material is flat.
9. The system of claim 1 , wherein said encasement is in physical contact with said diffusive sample only at said outer surface.
10. The system of claim 1 , wherein said light source is configured to emit light within a light cone having a half-angle of at least 60 degrees.
11. The system of claim 1 , wherein said light source has a bandwidth of at least 10 nanometers (nm).
12. The system of claim 1 , wherein said optical spectrometer is configured to detect light within a light cone having a half-angle of at least 60 degrees.
13. The system of claim 1 , wherein said at least two optical interactions increase a contrast of an optical spectrum obtained by said optical spectrometer by a factor of at least 2 relative to a contrast of an optical spectrum obtained by said optical spectrometer in the absence of said encasement.
14. The system of claim 1 , wherein said cavity is disposed within a measurement volume filled by said diffusive sample.
15. The system of claim 1 , wherein said encasement is disposed relative to said light source such that light emitted by said light source passes through said cavity prior to contacting said inner surface.
16. The system of claim 15 , wherein said light emitted by said light source achieves a uniform power flux density within said cavity.
17. The system of claim 1 , wherein said diffusive sample is a solid.
18. The system of claim 1 , wherein said optical spectrometer is positioned such that light reflected from said inner surface is directed away from said optical spectrometer.
19. The system of claim 1 , wherein said optical spectrometer is positioned such that light reflected from said outer surface is directed away from said optical spectrometer.
20. The system of claim 1 , wherein said ceiling of said inner surface is hemispherical.