Porous medium with adjustable fluid permeability and associated systems and methods
The present disclosure is related to porous media with adjustable fluid permeabilities and related systems and methods. In certain cases, the fluid permeability of a porous medium can be adjusted by applying an electrical potential to the porous medium. In some such cases, the application of the electrical potential to the porous medium results in the deposition of material over or the removal of material from the porous medium. Also disclosed herein are systems and methods for capturing species (e.g., acid gases) in which porous media with adjustable fluid permeabilities are used, for example, to control the flow of fluid into and out of a medium used to capture the species.
1. A method, comprising:
transporting a fluid through a first electronically conductive porous solid such that a species from the fluid is captured by a medium adjacent to the first electronically conductive porous solid;
altering an electrical potential applied between the first electronically conductive porous solid and a second electronically conductive porous solid such that the fluid permeability of the first electronically conductive porous solid is reduced and the fluid permeability of the second electronically conductive porous solid is increased; and
releasing the species from the medium such that the species is transported through the second electronically conductive porous solid.
2. The method of claim 1 , wherein the fluid comprises a gas.
3. The method of claim 1 , wherein the species comprises an acid gas and/or a hydrocarbon gas.
4. The method of claim 1 , wherein at least one of the first electronically conductive porous solid and the second electronically conductive porous solid comprises a metal.
5. The method of claim 4 , wherein the metal is coated on an electronically insulating porous solid.
6. The method of claim 1 , wherein altering the electrical potential applied between the first electronically conductive porous solid and the second electronically conductive porous solid such that the fluid permeability of the first electronically conductive porous solid is reduced comprises altering the electrical potential such that a material is deposited over pores of the first electronically conductive porous solid.
7. The method of claim 6 , wherein the material deposited over pores of the first electronically conductive porous solid comprises a metal and/or a metal oxide.
8. The method of claim 6 , wherein the deposition of material over pores of the first electronically conductive porous solid comprises deposition of colloidal particles over pores of the first electronically conductive porous solid.
9. The method of claim 6 , wherein the deposition of material over pores of the first electronically conductive porous solid comprises precipitation of the material over pores of the first electronically conductive porous solid.
10. The method of claim 1 , wherein altering the electrical potential applied between the first electronically conductive porous solid and a second electronically conductive porous solid such that the fluid permeability of the second electronically conductive porous solid is increased comprises altering the electrical potential such that material is removed from pores of the second electronically conductive porous solid.
11. The method of claim 1 , wherein the medium comprises a sequestration material.
12. The method of claim 11 , wherein the sequestration material captures the species via a non-electrochemical mechanism.
13. The method of claim 12 , wherein the non-electrochemical mechanism comprises adsorption, absorption, and/or a non-electrochemical chemical reaction.
14. The method of claim 11 , wherein releasing the species from the medium comprises exposing the medium to a stimulus.
15. The method of claim 14 , wherein the stimulus comprises a change in temperature and/or a change in pressure.
16. The method of claim 11 , wherein the sequestration material comprises a zeolite, a metal-organic framework, a resin, and/or an electrolyte.
17. The method of claim 1 , wherein the medium comprises a first electrode and a second electrode.
18. The method of claim 17 , further comprising applying a first medium electrical potential between the first electrode and the second electrode of the medium such that the species from the fluid is electrochemically captured by the medium.
19. The method of claim 18 , further comprising applying a second medium electrical potential between the first electrode and the second electrode of the medium, the second medium electrical potential having a polarity that is the opposite of the polarity of the first medium electrical potential, such that the species captured by the medium is released by the medium.
20. A device, comprising:
a first electronically conductive porous solid;
a second electronically conductive porous solid electronically coupled to the first electronically conductive porous solid; and
a medium between the first electronically conductive porous solid and the second electronically conductive porous solid;
wherein the device is configured such that:
when an electrical potential is applied to the first and second electronically conductive porous solids with a first polarity, a fluid permeability of the first electronically conductive porous solid is reduced, and
when an electrical potential is applied to the first and second electronically conductive porous solids with a second polarity opposite the first polarity, the fluid permeability of the second electronically conductive porous solid is reduced.
21. The device of claim 20 , wherein the device is configured such that:
when the electrical potential is applied to the first and second electronically conductive porous solids with the first polarity, a fluid permeability of the second electronically conductive porous solid is increased, and
when the electrical potential is applied to the first and second electronically conductive porous solids with the second polarity opposite the first polarity, the fluid permeability of the first electronically conductive porous solid is increased.
22. The device of claim 20 , wherein at least one of the first electronically conductive porous solid and the second electronically conductive porous solid comprises a metal.
23. The device of claim 22 , wherein the metal is coated on an electronically insulating porous solid.
24. The device of claim 20 , wherein the device is configured such that when the electrical potential is applied to the first and second electronically conductive porous solids with the first polarity, a material is deposited at an interface between the medium and the first electronically conductive porous solid.
25. The device of claim 24 , wherein the material deposited at the interface between the medium and the first electronically conductive porous solid comprises a metal and/or a metal oxide.
26. The device of claim 24 , wherein the material deposited at the interface between the medium and the first electronically conductive porous solid comprises a colloidal particle.
27. The device of claim 20 , wherein the device is configured such that when an electrical potential is applied to the first and second electronically conductive porous solids in a second polarity opposite the first polarity, material is deposited at an interface between the medium and the second electronically conductive porous solid.
28. The device of claim 27 , wherein the device is configured such that when the electrical potential is applied to the first and second electronically conductive porous solids in the second polarity opposite the first polarity, material is removed from an interface between the medium and the first electronically conductive porous solid.
29. The device of claim 20 , wherein the medium comprises a sequestration material.
30. The device of claim 29 , wherein the sequestration material comprises a zeolite, a metal-organic framework, a resin, and/or an electrolyte.
31. The device of claim 30 , wherein the medium comprises a metal salt dissolved in a solvent.
32. The device of claim 20 , wherein the medium comprises a first electrode and a second electrode.
33. The device of claim 32 , wherein the medium is configured such that when a medium electrical potential is applied between the first electrode and the second electrode of the medium, a species is captured by the medium.
34. The device of claim 33 , wherein the medium is configured such that, when a second medium electrical potential is applied between the first electrode and the second electrode of the medium, the second medium electrical potential having a polarity that is opposite the polarity of the first medium electrical potential applied between the first electrode and the second electrode of the medium, the species is released by the medium.