IP Library Granted Patent US 11,312,859
Granted Patent B2
US 11,312,859 · App. 17/221,519 · Granted Apr 26, 2022

Thermoplastic resins for network applications

Inventors: John F. Buzinkai (Chattanooga, TN); Alexander L. Gulledge (Columbia, SC); Benjamin D. Herzog (Wichita, KS); Isaac K. Iverson (Wichita, KS); Chee Sern Lim (Kennesaw, GA); James Michael Shurish (Troy, MI)
Assignee: INV Nylon Chemicals Americas, LLC
C08L77/06C08K7/14H01Q1/42
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Quick Facts
Patent No.
US 11,312,859
App. No.
17/221,519
Granted
Apr 26, 2022
Kind
B2
Abstract

The present disclosure relates to the use of thermoplastic resins in millimeter wave network applications. More specifically, it relates to polyamide materials meeting the requirements of dielectric performance in such applications.

Claims (63)

1. An enclosure for protecting a radio antenna, the enclosure comprising:

a thermoplastic resin comprising:

85:15 to 96:4 wt:wt PA66:DI, wherein DI comprises a combination of 2-methyl-pentamethylenediamine and isophthalic acid,

glass fiber in a range of about 5 to about 20 wt %,

a flame-retardant additive in a range of up to about 20 wt %,

a UV additive in a range of up to about 3 wt %,

a heat stabilizer additive in a range of up to about 2 wt %, and

a colorant additive in a range of up to about 3 wt %

wherein

the radio antenna is configured for operation in a frequency range of 0.5 GHz to 81 GHz, and

the enclosure is free of portions and windows for transmission of an electromagnetic signal having a frequency range of 0.5 GHz to 81 GHz and that are free of the thermoplastic resin.

2. A method comprising:

transmitting electromagnetic radiation having a frequency in a range of 0.5 GHz to 81 GHz through an enclosure for protecting a radio antenna, the enclosure comprising

a thermoplastic resin comprising:

85:15 to 96:4 wt:wt PA66:DI, wherein DI comprises a combination of 2-methyl-pentamethylenediamine and isophthalic acid,

glass fiber in a range of about 5 to about 20 wt %,

a flame-retardant additive in a range of up to about 20 wt %,

a UV additive in a range of up to about 3 wt %,

a heat stabilizer additive in a range of up to about 2 wt %, and

a colorant additive in a range of up to about 3 wt %, and

the enclosure is free of portions and windows for transmission of an electromagnetic signal having a frequency range of 0.5 GHz to 81 GHz and that are free of the thermoplastic resin.

3. The enclosure of claim 1 , wherein the enclosure is configured to fully enclose the radio antenna.

4. The enclosure of claim 3 , wherein the enclosure has a uniform thickness.

5. The enclosure of claim 1 , wherein a relative weight gain of the enclosure due to moisture uptake is less than 4% upon equilibration in an atmosphere at 70° C. and 62% relative humidity, according to ISO 1110.

6. The enclosure of claim 1 , wherein the enclosure has:

a tensile strength in a range of from about 40 MPa to about 300 MPa,

a density in a range of from 0.7 g/cm 3 to 5 g/cm 3 ,

a un-notched Charpy impact resistance, at 23° C., in a range of from 40 kJ/m 2 to 150 kJ/m 2 , and

a signal attenuation of at least one of the following, when a direction of a signal impinging on the enclosure is normal to a surface of the enclosure, and wherein an enclosure thickness is substantially uniform across an area where the signal impinges on the enclosure:

from 1 dB to 0 dB for signal of frequency 500 MHz to 6 GHz when the enclosure thickness is from 0.5 mm to 6 mm,

from 1 dB to 0 dB for signal of frequency 24 GHz to 30 GHz when the enclosure thickness is from 0.5 mm to 4.5 mm,

from 1 dB to 0 dB for signal of frequency 36 GHz to 40 GHz when the enclosure thickness is from 0.5 mm to 4 mm, and

from 1 dB to 0 dB for signal of frequency 76 GHz to 81 GHz when the enclosure thickness is from 0.5 mm to 3.5 mm.

7. The enclosure of claim 1 , wherein a density of the enclosure is in a range of from greater than or equal to 0.7 g/cm 3 to less than or equal to 5 g/cm 3 .

8. The enclosure of claim 1 , wherein the thermoplastic resin comprises from 10 to 20 wt % glass fibers.

9. The enclosure of claim 6 , wherein the enclosure has a tensile strength in a range of from 40 to 300 MPa.

10. The enclosure of claim 1 , having a substantially uniform signal attenuation of:

from 1 dB to 0 dB for signal of frequency 500 MHz to 6 GHz when an enclosure thickness is from 1.5 mm to 4 mm,

from 1 dB to 0 dB for signal of frequency 24 GHz to 30 GHz when the enclosure thickness is from 2.5 mm to 4 mm,

from 1 dB to 0 dB for signal of frequency 36 GHz to 40 GHz when the enclosure thickness is from 1.75 mm to 2.75 mm, or

from 1 dB to 0 dB for signal of frequency 76 GHz to 81 GHz when the enclosure thickness is from 1.75 mm to 2.75 mm.

11. The method of claim 2 , wherein the enclosure is configured to fully enclose the radio antenna.

12. The method of claim 11 , wherein the enclosure has a uniform thickness.

13. The method of claim 11 , wherein a relative weight gain of the enclosure due to moisture uptake is less than 4% upon equilibration in an atmosphere at 70° C. and 62% relative humidity, according to ISSO 1110.

14. The method of claim 2 , wherein the enclosure has:

a tensile strength in a range of from about 40 MPa to about 300 MPa,

a density in a range of from 0.7 g/cm 3 to 5 g/cm 3 ,

a un-notched Charpy impact resistance, at 23° C. in a range of from 40 kJ/m 2 to 150 kJ/m 2 , and

a signal attenuation of at least one of the following, when a direction of a signal impinging on the enclosure is normal to a surface of the enclosure, and wherein an enclosure thickness is substantially uniform across an area where the signal impinges on the enclosure:

from 1 dB to 0 dB for signal of frequency 500 MHz to 6 GHz when the enclosure thickness is from 0.5 mm to 6 mm,

from 1 dB to 0 dB for signal of frequency 24 GHz to 30 GHz when the enclosure thickness is from 0.5 mm to 4.5 mm,

from 1 dB to 0 dB for signal of frequency 36 GHz to 40 GHz when the enclosure thickness is from 0.5 mm to 4 mm, and

from 1 dB to 0 dB for signal of frequency 76 GHz to 81 GHz when the enclosure thickness is from 0.5 mm to 3.5 mm.

15. The method of claim 2 , wherein a density of the enclosure is in a range of from greater than or equal to 0.7 g/cm 3 to less than or equal to 5 g/cm 3 .

16. The method of claim 2 , wherein the thermoplastic resin comprises from 10 to 20 wt % glass fibers.

17. The method of claim 16 , wherein the enclosure has a tensile strength in a range of from 40 to 300 MPa.

18. The method of claim 2 , having a substantially uniform signal attenuation of:

from 1 dB to 0 dB for signal of frequency 500 MHz to 6 GHz when an enclosure thickness is from 1.5 mm to 4 mm,

from 1 dB to 0 dB for signal of frequency 24 GHz to 30 GHz when the enclosure thickness is from 2.5 mm to 4 mm,

from 1 dB to 0 dB for signal of frequency 36 GHz to 40 GHz when the enclosure thickness is from 1.75 mm to 2.75 mm, or

from 1 dB to 0 dB for signal of frequency 76 GHz to 81 GHz when the enclosure thickness is from 1.75 mm to 2.75 mm.

19. The enclosure of claim 7 , wherein a density of the enclosure is in a range of from greater than or equal to 0.8 g/cm 3 to less than or equal to 4 g/cm 3 .

20. The enclosure of claim 19 , wherein a density of the enclosure is in a range of from greater than or equal to 0.85 g/cm 3 to less than or equal to 3 g/cm 3 .

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2022
From: INV NYLON CHEMICALS AMERICAS, LLC
To: INV NYLON POLYMERS AMERICAS, LLC
Reel/Frame 061803/0585 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE FIFTH ASSIGNOR'S NAME PREVIOUSLY RECORDED AT REEL: 056727 FRAME: 0177. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Oct 5, 2021
From: BUZINKAI, JOHN F.; GULLEDGE, ALEXANDER L.; HERZOG, BENJAMIN D.; IVERSON, ISAAC K.; LIM, CHEE SERN; SHURISH, JAMES MICHAEL
To: INV NYLON CHEMICALS AMERICAS, LLC
Reel/Frame 057772/0139 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 1, 2021
From: BUZINKAI, JOHN F.; GULLEDGE, ALEXANDER L.; HERZOG, BENJAMIN D.; IVERSON, ISAAC K.; LEE, CHEE SERN; SHURISH, JAMES MICHAEL
To: INV NYLON CHEMICALS AMERICAS, LLC
Reel/Frame 056727/0177 →
Continuity (5)
Continuation PCTIB2021052093 · Mar 12, 2021
Provisional Application 63154035 · Feb 26, 2021
Provisional Application 63142081 · Jan 27, 2021
Provisional Application 62989105 · Mar 13, 2020
Related Publication 20210292553A1 · Sep 23, 2021