CATHODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY
A lithium secondary battery includes a cathode including a cathode active material including a lithium-transition metal composite oxide particle having a crystal grain size of greater than 500 nm measured through X-ray diffraction (XRD) analysis, and an anode disposed to face the cathode. The present invention provides a lithium secondary battery having improved life-span characteristics while suppressing gas generation due to crack of the particles by controlling the crystal grain size of the lithium-transition metal composite oxide particles.
1 . A cathode active material for a lithium secondary battery comprising:
a lithium-transition metal composite oxide particle having a crystal grain size of greater than 500 nm measured through X-ray diffraction (XRD) analysis.
2 . The cathode active material for a lithium secondary battery according to claim 1 , wherein the crystal grain size is measured through Equation 1 below:
L
=
0.9
λ
βcosθ
[
Equation
1
]
(In Equation 1, L represents the crystal grain size, A represents an X-ray wavelength, β represents a full width at half maximum (FWHM) of a peak of (003) plane, and θ represents an angle of diffraction).
3 . The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle has a crystal grain size of 600 to 1100 nm.
4 . The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle comprises a first lithium-transition metal composite oxide particle having a crystal grain size of greater than 500 nm measured through the XRD analysis and a second lithium-transition metal composite oxide particle in a form of a secondary particle.
5 . The cathode active material for a lithium secondary battery according to claim 4 , wherein the first lithium-transition metal composite oxide particle includes a form of a single particle having single crystal or polycrystalline structure in crystallography.
6 . The cathode active material for a lithium secondary battery according to claim 4 , wherein the crystal grain size of the second lithium-transition metal composite oxide particle measured through the XRD analysis is 500 nm or less.
7 . The cathode active material for a lithium secondary battery according to claim 4 , wherein a weight ratio of the first lithium-transition metal composite oxide particle and the second lithium-transition metal composite oxide particle is 3:7 to 7:3 in the cathode active material.
8 . The cathode active material for a lithium secondary battery according to claim 4 , wherein a particle diameter (D 50 ) of the second lithium-transition metal composite oxide particle is larger than a particle diameter of the first lithium-transition metal composite oxide particle.
9 . The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle has a composition represented by the following formula (1):
Li x Ni 1-y M y O 2+z [Formula 1]
(In Formula 1, x and y are in a range of 0.9 ≤x≤1.1, and 0≤y≤0.7, z is in a range of −0.1≤z≤0.1, and M is at least one element selected from Na, Mg, Ca, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Co, Fe, Cu, Ag, Zn, B, Al, Ga, C, Si, Sn and Zr).
10 . The cathode active material for a lithium secondary battery according to claim 9 , wherein a molar ratio of Ni in the Formula 1 is 0.8 or more.
11 . A lithium secondary battery comprising:
a cathode including the cathode active material for a lithium secondary battery according to claim 1 ; and
an anode disposed to face the cathode.