ORGANIC ELECTROLUMINESCENT DEVICE

1 . An organic electroluminescent device comprising a first electrode; a second electrode facing the first electrode; a light-emitting layer between the first electrode and the second electrode; and an electron transport zone between the light-emitting layer and the second electrode,

wherein the electron transport zone includes a hole blocking layer, an electron buffer layer, or both of them, and an electron transport layer and an electron injection layer,

wherein the electron transport layer is formed between the hole blocking layer or the electron buffer layer and the second electrode,

wherein the electron injection layer is formed between the electron transport layer and the second electrode,

wherein the light-emitting layer comprises a compound represented by the following formula 1 and a compound represented by the following formula 2, and

wherein the hole blocking layer, the electron buffer layer, or both of them comprises a compound represented by the following formula 11;

wherein

L 1 and L 2 each independently represent a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (5- to 30-membered)heteroarylene;

Ar 1 and Ar 2 each independently represent a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (5- to 30-membered)heteroaryl; and

R 1 to R 8 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, or -L 4 -N-(Ar 4 )(Ar 5 );

wherein

Ring A, Ring B and Ring C each independently represent a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 50-membered)heteroaryl;

Y 1 represents B;

X 1 and X 2 each independently represent NR; and

R represents hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, or -L 4 -N-(Ar 4 )(Ar 5 ); or may be linked to at least one of Ring A, Ring B and Ring C to form a ring(s);

wherein

Z 1 to Z 3 each independently represent CR 1 a;

R 18 each independently represents hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C50)aryl, a substituted or unsubstituted (3- to 50-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, or -L 4 -N-(Ar)(Ar 5 ), provided that R 18 does not include 2-dimethylfluorenyl, quinolinyl, and pyridyl;

L 4 each independently represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;

Ar 4 and Ar 5 each independently represent hydrogen, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted fused ring of an (C3-C30) aliphatic ring and an (C6-C30) aromatic ring, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; and

when a plurality of substituents represented by the same symbol are present, each of the substituents represented by the same symbol may be the same or different.

2 . The organic electroluminescent device according to claim 1 , wherein the substituent of the substituted alkyl, the substituted alkenyl, the substituted aryl, substituted arylene, the substituted heteroaryl, the substituted heteroarylene, the substituted cycloalkyl, the substituted alkoxy, the substituted heterocycloalkyl, the substituted trialkylsilyl, the substituted dialkylarylsilyl, the substituted alkyldiarylsilyl, the substituted triarylsilyl and the substituted fused ring of aliphatic ring and aromatic ring each independently represents at least one selected from the group consisting of deuterium; halogen; cyano; carboxyl; nitro; hydroxy; (C1-C30)alkyl; halo(C1-C30)alkyl; (C2-C30)alkenyl; (C2-C30)alkynyl; (C1-C30)alkoxy; (C1-C30)alkylthio; (C3-C30)cycloalkyl; (C3-C30)cycloalkenyl; (3- to 7-membered)heterocycloalkyl; (C6-C30)aryloxy; (C6-C30)arylthio; (5- to 50-membered)heteroaryl unsubstituted or substituted with at least one of (C1-C30)alkyl, (C6-C30)aryl, and di(C6-C30)arylamino; (C6-C30)aryl unsubstituted or substituted with at least one of (C1-C30)alkyl, (3- to 50-membered)heteroaryl, and mono- or di-(C6-C30)arylamino; tri(C1-C30)alkylsilyl; tri(C6-C30)arylsilyl; di(C1-C30)alkyl(C6-C30)arylsilyl; (C1-C30)alkyldi(C6-C30)arylsilyl; amino; mono- or di-(C1-C30)alkylamino; mono- or di-(C2-C30)alkenylamino; mono- or di-(C6-C30)arylamino unsubstituted or substituted with at least one of (C1-C30)alkyl, (5- to 30-membered)heteroaryl, and di(C6-C30)arylamino; mono- or di-(3- to 30-membered)heteroarylamino; (C1-C30)alkyl(C2-C30)alkenylamino; (C1-C30)alkyl(C6-C30)arylamino; (C1-C30)alkyl(3- to 30-membered)heteroarylamino; (C2-C30)alkenyl(C6-C30)arylamino; (C2-C30)alkenyl(3- to 30-membered)heteroarylamino; (C6-C30)aryl(3- to 30-membered)heteroarylamino; (C1-C30)alkylcarbonyl; (C1-C30)alkoxycarbonyl; (C6-C30)arylcarbonyl; di(C6-C30)arylboronyl; di(C1-C30)alkylboronyl; (C1-C30)alkyl(C6-C30)arylboronyl; (C6-C30)ar(C1-C30)alkyl; and (C1-C30)alkyl(C6-C30)aryl.

3 . The organic electroluminescent device according to claim 1 , wherein L 1 and L 2 in the formula 1 each independently represent a single bond, or are selected from any one of the substituents listed in the following Group 1:

wherein

Z represents O, S, NR 101 , CR 102 R 103 or SiR 104 R 105 ;

R 101 to R 105 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to the adjacent substituent to form a ring(s); and

each of the two * in any one of the Group 1 represents a bonding site to the anthracene skeleton, and a bonding site to Ar 1 or Ar 2 .

4 . The organic electroluminescent device according to claim 1 , wherein Ar 1 and Ar 2 in the formula 1 are each independently selected from any one of the substituents listed in the following Group 2:

wherein

A, G, E and M each independently represent O, S, NR 106 , CR 107 R 108 or SiR 109 R 110 ;

R 106 to R 110 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to the adjacent substituent to form a ring(s); and

* represents a bonding site to the anthracene skeleton, L 1 , or L 2 .

5 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 1 is represented by the following formula 1-1:

wherein

X represents O or S;

R 9 to R 12 each independently represent hydrogen or deuterium, or a bonding site to L 2 ;

R 13 each independently represents hydrogen, deuterium, a substituted or unsubstituted (C6-C50)aryl, or a substituted or unsubstituted (3- to 50-membered)heteroaryl;

a represents an integer of 1 to 4, and when a is an integer of 2 or more, each of R 13 may be the same or different; and

L 1 , L 2 , Ar 1 and R 1 to R 8 are as defined in claim 1 .

6 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 2 is represented by the following formula 2-1:

wherein

R 21 to R 31 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, or -L 4 -N-(Ar 4 )(Ar 5 ); or may be linked to the adjacent substituent to form a ring(s); and

Y 1 , X 1 , X 2 , L 4 , Ar 4 , and Ar 5 are as defined in claim 1 .

7 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 11 is represented by the following formula 11-1:

wherein

A 1 and A 2 each independently are as defined as R 1 in formula 11;

L 3 represents a single bond, a substituted or unsubstituted (C6-C50)arylene, or a substituted or unsubstituted (5- to 50-membered)heteroarylene;

Ar 3 represents a substituted or unsubstituted (C6-C50)aryl, or a substituted or unsubstituted (5- to 50-membered)heteroaryl, provided that Ar 3 is not 2-dimethylfluorenyl, quinolinyl, and pyridyl; and

m represents an integer of 1 or 2, and when m is 2, each of Ar 3 may be the same or different.

8 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 1 is selected from the following compounds:

wherein

Dn means that n of the hydrogens are replaced with deuterium, wherein n represents an integer from 1 to 50.

9 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 2 is selected from the following compounds:

wherein

D2 to D5 represent that two to five hydrogens each have been replaced with deuterium.

10 . The organic electroluminescent device according to claim 1 , wherein the compound represented by formula 11 is selected from the following compounds: