Electrolytic copper foil for secondary battery and method for producing the same
The present invention relates to an electrolytic copper foil for a secondary battery, and a method of producing the same. The electrolytic copper foil for a secondary battery exhibits a little change in a physical property caused by a difference in a crosshead speed when tensile strength and an elongation percentage of the electrolytic copper foil are measured, thereby achieving excellent charging and discharging characteristics of a battery and preventing exfoliation of an active material. The electrolytic copper foil for a secondary battery is produced from a plating solution containing Total Organic Carbon (TOC), cobalt, and iron by using a drum, in which a ratio of the TOC to the cobalt and the iron contained in the electrolytic copper foil follows Formula 1 below. TOC/(cobalt+iron)=1.3 to 1.5 [Formula 1]
1. A method of producing an electrolytic copper foil for a secondary battery, the method comprising:
preparing a plating solution containing copper, Total Organic Carbon (TOC), cobalt, and iron; and
applying a current density of 30 Ampere per Square Deci-metre (ASD) to 150 ASD under a temperature condition of 30° C. to 70° C. and performing electroplating by using a drum,
wherein a ratio of the TOC to the cobalt and the iron contained in the electrolytic copper foil follows Formula 1 below:
TOC/(cobalt+iron)=1.3 to 1.5 [Formula 1].
2. The method of claim 1 , wherein a difference in a crosshead speed for measuring tensile strength at room temperature and 110° C. (six hours) follows Formula 2, and
a difference in a crosshead speed for measuring an elongation percentage at room temperature and 110° C. (six hours) follows Formula 3:
(Tensile strength at 1 mm/min crosshead speed)/(Tensile strength at 50 mm/min crosshead speed)≥0.9 [Formula 2]
(Elongation percentage at 1 mm/min crosshead speed)/(Elongation percentage at 50 mm/min crosshead speed)≥0.8 [Formula 3].
3. The method of claim 1 , wherein a concentration of the TOC contained in the plating solution is equal to or larger than 100 ppm.
4. The method of claim 1 , wherein tensile strength of the electrolytic copper foil at room temperature is 40 kgf/mm 2 to 51 kgf/mm 2 .
5. The method of claim 1 , wherein a thickness of the electrolytic copper foil is 4 μm to 12 μm.
6. The method of claim 1 , wherein an elongation percentage of the electrolytic copper foil is 2% to 18%.