IP Library Granted Patent US 11,407,702
Granted Patent B2
US 11,407,702 · App. 17/261,235 · Granted Aug 9, 2022

Method for producing methanol in a reactor with bypass

Inventors: Emil Andreas Tjärnehov (Limhamn, SE); Per Juul Dahl (Vedbæk, DK)
Assignee: HALDOR TOPSØE A/S
C07C29/152C07C29/1518
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Quick Facts
Patent No.
US 11,407,702
App. No.
17/261,235
Granted
Aug 9, 2022
Kind
B2
Abstract

A method for producing methanol comprises the steps of passing a feed stream of methanol synthesis pas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol, cooling the mixed gas containing methanol, separating methanol from the mixed pas and heating the mixed gas. The stream of heated mixed gas is passed through an additional methanol reactor containing a methanol synthesis catalyst, and the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor.

Claims (22)

1. A method for producing methanol, comprising the steps of

(a) passing a feed stream of methanol synthesis gas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol,

(b) cooling the mixed gas containing methanol,

(c) separating methanol from the mixed gas and

(d) heating the mixed gas, wherein

the stream of heated mixed gas from step (d) is passed through an additional methanol reactor containing a methanol synthesis catalyst,

the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor,

either the main methanol reactor or the additional methanol reactor comprises a tube sheet.

2. The method according to claim 1 , wherein the main methanol reactor is a boiling water reactor (BWR).

3. The method according to claim 2 , wherein an adiabatic catalyst layer is placed on top of the tube sheet.

4. The method according to claim 3 , wherein the main methanol reactor comprises the tube sheet.

5. The method according to claim 3 , wherein the additional methanol reactor comprises the tube sheet.

6. The method according to claim 1 , wherein each of the main methanol reactor and the additional methanol reactor comprises a tube sheet.

7. The method according to claim 3 , wherein each of the main methanol reactor and the additional methanol reactor comprises a tube sheet.

8. The method according to claim 1 , wherein the feed stream of methanol synthesis gas is split into a first stream and a second stream before reaching the main methanol reactor.

9. The method according to claim 8 , wherein the first stream is sent to the main methanol reactor via a throttle valve, and the second stream is sent to the additional methanol reactor after passing a feed/effluent heat exchanger.

10. The method according to claim 1 , wherein effluent from the main methanol reactor is cooled in a loop air cooler and a loop water cooler before being fed to a separator in which liquid methanol product is separated from the gas phase.

11. The method according to claim 10 , wherein, the gas phase leaving the separator is mixed with fresh feed gas and then passed to the additional methanol reactor.

12. The method according to claim 1 , wherein the feed stream of methanol synthesis gas is split into a first stream and a second stream before reaching the main methanol reactor,

wherein the first stream is sent to the main methanol reactor via a throttle valve, and the second stream is sent to the additional methanol reactor after passing a feed/effluent heat exchanger,

wherein effluent from the main methanol reactor is cooled in a loop air cooler and a loop water cooler before being fed to a separator in which liquid methanol product is separated from the gas phase, and

wherein, the gas phase leaving the separator is mixed with fresh feed gas and then passed to the additional methanol reactor.

Assignments (2)
CHANGE OF NAME Recorded Oct 30, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065565/0685 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2021
From: TJÄRNEHOV, EMIL ANDREAS; DAHL, PER JUUL
To: HALDOR TOPSØE A/S
Reel/Frame 055765/0976 →
Priority Claims (1)
DK PA 2018 00475 · Aug 17, 2018 · national
Continuity (1)
Related Publication 20210269380A1 · Sep 2, 2021