Process for the preparation of an UHMWPE homopolymer
A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR 21 of 0.01 g/10 min or less, said process comprising: (I) prepolymerising at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst; (II) polymerising ethylene at a temperature of 55° C. or less, such as 20 to 55° C., to prepare said UHMW ethylene homopolymer; wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.
1. A process for the preparation of an ultra-high molecular weight (UHMW) ethylene homopolymer having a MFR 21 of 0.01 g/10 min or less, said process comprising:
(I) pre-polymerizing at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst;
(II) polymerizing ethylene at a temperature of 55 ° C. or less to prepare said UHMW ethylene homopolymer;
wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.
2. The process as claimed claim 1 , wherein the prepolymer is an ethylene homopolymer.
3. The process as claimed in claim 1 , wherein the heterogeneous Ziegler Natta catalyst comprises a support.
4. The process as claimed in claim 1 , wherein the pre-polymerization step (I) is carried out in the presence of hydrogen.
5. The process as claimed in claim 1 , wherein the pressure of the pre-polymerization step (I) is 20 to 40 bars and/or wherein the pressure of the polymerization step (II) is 10 to 30 bars.
6. The process as claimed in claim 1 , wherein the pre-polymerization step (I) is carried out at a temperature of 20 to 80° C. and/or wherein the polymerization step (II) is effected at a temperature of 25 to 50° C.
7. The process as claimed in claim 1 , wherein the prepolymer has a Mw of 100,000 to 600,000.
8. The process as claimed in claim 1 , wherein hydrogen is present in the pre-polymerization step (I) and the hydrogen is removed from the product of the pre-polymerization step (I) before the subsequent polymerization step (II).
9. The process as claimed in claim 1 , wherein the partial pressure of ethylene in the polymerization step (II) is 5 to 7 bars.
10. The process as claimed in claim 1 , wherein the polymerization step (II) is carried out at 30° C. and with an ethylene pressure of 6 bar.
11. The process as claimed in claim 1 , wherein the polymerization step (II) is effected in the absence of hydrogen.
12. The process as claimed in claim 1 , wherein the UHMW polyethylene homopolymer comprises 1.0 to 8.0 wt. % of the prepolymer.
13. The process as claimed in claim 1 , wherein the polymerization step (II) is carried out in a slurry loop reactor.
14. The process as claimed in claim 3 , wherein the support is a silica support.
15. The process as claimed in claim 3 , wherein the support has a particle size in the range of 5 to 30 microns.
16. The process as claimed in claim 1 , wherein step (II) is carried out at 20 to 55° C.
17. The process as claimed in claim 1 , wherein the prepolymer has a Mw of 150,000 to 550,000 g/mol.