Positive electrode active material for lithium secondary battery, method for manufacturing same, and lithium secondary battery including same
A cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium metal oxide particle which includes a core part and a shell part and contains nickel (Ni), cobalt (Co) and manganese (Mn). A total Ni content of the lithium metal oxide particle is 70 mol % or more based on a total 100 mol % of Ni, Co and Mn. The shell part includes a depth region in a range of 10 to 100 nm from a surface of the lithium metal oxide particle, and a Co content thereof in the depth region is 1.4 to 6 times a Co content of the core part. Stability of the lithium secondary battery may be improved through surface treatment using high content of Co.
1 . A cathode active material for a lithium secondary battery comprising:
a lithium metal oxide particle which includes a core part and a shell part and contains nickel (Ni), cobalt (Co) and manganese (Mn),
wherein a total Ni content of the lithium metal oxide particle is 75 mol % or more based on a total 100 mol % of Ni, Co and Mn,
wherein the core part does not have a concentration gradient of nickel, cobalt and manganese,
the shell part includes a depth region in a range of 10 to 100 nm from a surface of the lithium metal oxide particle, a Co content thereof in the depth region is 1.4 to 6 times a Co content of the core part, and a concentration gradient.
2 . The cathode active material for a lithium secondary battery according to claim 1 , wherein a total average composition of the lithium metal oxide particle is represented by Formula 1 below:
LiNi tx Co ty Mn 1-tx-ty-tz M1 tz O 2-a , [Formula 1]
wherein in Formula 1, M1 is at least one selected from the group consisting of Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga and B, and,
tx, ty, tz and a have a relationship of 0.75≤tx<1, 0<ty≤0.2, 0≤tz≤0.1, 0≤a≤0.5, and 0<1-tx-ty-tz.
3 . The cathode active material for a lithium secondary battery according to claim 2 , wherein in Formula 1, the tx and ty have a relationship of 0.75≤tx≤0.9 and 0.1<ty≤0.2.
4 . The cathode active material for a lithium secondary battery according to claim 2 , wherein the core part has a composition represented by Formula 2 below, and the shell part has a composition represented by Formula 3 below:
LiNi cx Co cy Mn 1-cx-cy-cz M2 cz O 2-b , [Formula 2]
wherein in Formula 2, M2 is at least one selected from the group consisting of Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga and B, and,
cx, cy, cz and b have a relationship of 0.7≤cx<1, 0<cy≤0.2, 0≤cz≤0.1, 0≤b≤0.5, and 0<1-cx-cy-CZ,
LiNi sx Co sy Mn 1-sx-sy-sz M3 sz O 2-c , [Formula 3]
wherein in Formula 3, M3 is at least one selected from the group consisting of Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga and B, and,
sx, sy, sz and c have a relationship of 0.6≤sx<0.9, 0<sy≤0.4, 0≤sz≤0.1, 0≤c≤0.5, and 0<1-sx-sy-SZ.
5 . The cathode active material for a lithium secondary battery according to claim 4 , wherein in Formula 2, the cx and cy have a relationship of 0.75≤cx≤0.95 and 0.05≤cy≤0.15.
6 . The cathode active material for a lithium secondary battery according to claim 4 , wherein in Formula 3, the sx and sy have a relationship of 0.6≤sx≤0.9 and 0.08≤sy≤0.3.
7 . The cathode active material for a lithium secondary battery according to claim 1 , wherein metals other than lithium contained in the lithium metal oxide particle are composed of Ni, Co and Mn.
8 . The cathode active material for a lithium secondary battery according to claim 1 , wherein the core part has a uniform composition over an entire area of the core part.
9 . The cathode active material for a lithium secondary battery according to claim 1 , wherein a content of Ni is decreased, while a content of Co is increased from an outermost surface of the core part to an outermost surface of the shell part.
10 . The cathode active material for a lithium secondary battery according to claim 1 , wherein a content of Mn is constant over an entire region of the lithium metal oxide particle.
11 . A lithium secondary battery comprising:
an electrode assembly including a cathode including the cathode active material according to claim 1 , an anode, and a separation membrane disposed between the cathode and the anode;
an outer case configured to house the electrode assembly; and
an electrolyte in which the electrode assembly is impregnated in the outer case.