Method for the partial coloring of plastic parts
View Patent ↗The invention relates to an improved method for the partial coloring, in particular for the color laser engraving, of plastic parts, in particular thermoplastic plastic parts, more particularly thermoplastic plastic parts that have a multi-layered structure, to the resulting partially colored, preferably color laser engraved, plastic parts, in particular thermoplastic plastic parts, and to a device for the partial coloring of plastic parts.
1. A process for partial coloring of plastic parts, comprising
i) immersing a plastic part (A) in a coloring bath (B); and
ii) irradiating the plastic part (A) from i) with focused nonionizing electromagnetic radiation (C),
wherein partial coloring of the plastic part (A) is effected substantially only at sites irradiated in step ii),
wherein a wavelength range of the focused nonionizing electromagnetic radiation (C) is chosen such that the coloring bath (B) has a radiation permeability of ≥2% to ≤99% for a chosen radiation determined by the UV-VIS-NIR-MIR method according to DIN EN ISO/IEC 17025, wherein
the coloring bath (B) has a temperature of ≤99° C. to ≥−60° C., wherein the temperature of the coloring bath (B) has a constant temperature over the duration of the process, wherein the focused nonionizing electromagnetic radiation (C) passes through a sheet (D) comprising one or more radiation-decoupling materials before impacting the plastic part (A), and wherein a distance of the sheet (D) from a surface of the plastic part (A) is ≤120 mm.
2. The process according to claim 1 , wherein the focused nonionizing electromagnetic radiation (C) is laser radiation having a wavelength in the range from ≥0.1 μm to ≤1000 μm.
3. The process according to claim 1 , wherein the radiation-decoupling material(s) of the sheet (D) exhibit(s) a scratch-dig value of ≤80-50 to ≤10-10 determined according to ISO10110-8, a surface roughness Rq determined according to ISO 10110-8 of ≥0.5 to ≤500 nm, and a radiation permeability of ≥50% to ≤99.95% for the chosen radiation determined according to the UV-VIS-NIR-MIR method according to DIN EN ISO/IEC 17025.
4. The process according to claim 1 , wherein the radiation-decoupling material(s) of the sheet (D) comprise(s) glass, radiation-permeable plastic, mineral glass, synthetic glass, radiation-permeable ceramic material, or mixtures of at least two thereof.
5. The process according to claim 1 , wherein the plastic part (A) comprises a thermoplastic plastic comprising polymers of ethylenically unsaturated monomers, polycondensates of bifunctional reactive compounds, polyaddition products of bifunctional reactive compounds, or a combination thereof.
6. The process according to claim 1 , wherein the plastic part (A) comprises at least one additive which has an absorption maximum in a wavelength range of the employed focused nonionizing electromagnetic radiation or wherein the plastic part is coated with at least one additive in the form of a coating composition which has an absorption maximum in a wavelength range of the employed focused nonionizing electromagnetic radiation.
7. The process according to claim 6 , wherein the at least one additive comprises at least one or more organic and/or inorganic IR absorbers.
8. The process according to claim 1 , wherein the coloring bath (B) comprises at least one colorant, or mixtures thereof.
9. The process according to claim 1 , wherein the coloring bath (B) comprises at least one dye comprising solvent dyes and/or disperse dyes according to the Colour Index classification or mixtures of these dyes.
10. The process according to claim 1 , wherein the coloring bath (B) comprises:
a) solvent and/or dispersant, and
b) at least one colorant.
11. A security document, comprising a plastic part (A) that is at least partially colored according to the process for partial coloring of plastic parts of claim 1 .