ANTI-REFLECTIVE FILM, POLARIZING PLATE, AND DISPLAY APPARATUS
The invention relates to an anti-reflective film that has low reflectance deviation and light transmittance deviation, can simultaneously realize high scratch resistance and anti-fouling property, and can increase screen sharpness of a display apparatus, a polarizing plate and a display apparatus comprising the same.
1 . An anti-reflective film comprising
a light transmitting substrate; a hard coating layer; and a low refractive index layer,
wherein a first peak appears at 2θ value of 25 to 27°, and a second peak appears at 2θ value of 46 to 48°, in X-ray diffraction (XRD) pattern of reflection mode, and
a rate (P2/P1) of the intensity of the second peak (P2) to the intensity of the first peak (P1) is at least 0.01.
2 . The anti-reflective film according to claim 1 , wherein the light transmitting substrate has a moisture permeability under temperature of 30 to 40° C. and relative humidity of 90 to 100%, of 50 g/m 2 ·day or less.
3 . The anti-reflective film according to claim 1 , wherein the low refractive index layer comprises a binder resin and inorganic fine particles dispersed in the binder resin.
4 . The anti-reflective film according to claim 3 , wherein the binder resin comprises a crosslinked polymer between photopolymerizable compounds and fluorine-containing compounds including photoreactive functional groups.
5 . The anti-reflective film according to claim 3 , wherein the inorganic fine particles include one or more selected from the group consisting of solid inorganic nanoparticles having a diameter of 0.5 to 100 m, and hollow inorganic nanoparticles having a diameter of 1 to 200 nm.
6 . The anti-reflective film according to claim 1 , wherein the hard coating layer comprises a binder resin comprising photocurable resin, and organic or inorganic fine particles dispersed in the binder resin.
7 . The anti-reflective film according to claim 6 , wherein the binder resin of the hard coating layer further comprises a high molecular weight (co)polymer having a number average molecular weight of at least 10,000.
8 . The anti-reflective film according to claim 1 , wherein the light transmitting substrate has thickness direction retardation (Rth) measured at a wavelength of 400 nm to 800 nm, of at least 5,000 nm,
a rate of a tensile strength in a direction perpendicular to one direction to a tensile strength in the one direction, of at least 2, and
the tensile strength in one direction is smaller than the tensile strength in a direction perpendicular to the one direction.
9 . The anti-reflective film according to claim 1 , wherein a light transmitting substrate is a polyethylene terephthalate film.
10 . The anti-reflective film according to claim 1 , wherein the anti-reflective film has average reflectance in the wavelength region of 380 nm to 780 nm, of 2.0% or less.
11 . The anti-reflective film according to claim 1 , wherein the anti-reflective film has an average reflectance deviation of 0.2% p or less, and a light transmittance deviation of 0.2% p or less.
12 . A polarizing plate comprising the anti-reflective film according to claim 1 , and a polarizer.
13 . A polarizing plate comprising
a polarizer; a second hard coating layer with a thickness of 10 μM or less; and the anti-reflective film according to claim 1 ,
wherein the second hard coating layer and the anti-reflective film are positioned so as to face based on the polarizer.
14 . The polarizing plate according to claim 13 , wherein a total thickness of the polarizer; the second hard coating layer; and the anti-reflective film is 200 μM or less.
15 . The polarizing plate according to claim 13 , wherein the second hard coating layer with a thickness of 10 μM or less is positioned on one side of the polarizer, and the light transmitting substrate of the antireflective film is positioned on the other side,
wherein the light transmitting substrate has thickness direction retardation (Rth) measured at a wavelength of 400 nm to 800 nm, of at least 5,000 nm,
wherein the light transmitting substrate has a rate of a tensile strength in a direction perpendicular to one direction to a tensile strength in the one direction, of at least 2, and
wherein the tensile strength in one direction is smaller than the tensile strength in a direction perpendicular to the one direction.
16 . A display apparatus comprising the anti-reflective film according to claim 1 .