Polypropylene composition with excellent stiffness and impact strength
The present invention is directed to a polypropylene composition (C) comprising an α-nucleated heterophasic composition (HECO) comprising a (semi)crystalline polypropylene (PP1), an elastomeric ethylene/propylene copolymer (EPR) and a first α-nucleating agent (NU1), an impact modifier comprising a polyethylene (PE) being a copolymer of ethylene and a C 4 -C 12 α-olefin and a second α-nucleating agent (NU2). The present invention is further directed to a method for preparing said polypropylene composition (C) and an article comprising said polypropylene composition (C). The present invention is also directed to the use of a composition comprising a polyethylene (PE) being a copolymer of ethylene and a C 4 -C 12 α-olefin and an α-nucleating agent (NU2) as an impact modifier.
1. A polypropylene composition (C), comprising:
(a) at least 80.0 wt. % of an α-nucleated heterophasic composition (HECO), comprising
(a1) a (semi)crystalline polypropylene (PP1),
(a2) an elastomeric ethylene/propylene copolymer (EPR) dispersed in said (semi)crystalline polypropylene (PP1),
(a3) a first α-nucleating agent (NU1),
(b) at least 5.0 wt. % of a polyethylene (PE) being a copolymer of ethylene and a C 4 -C 12 α-olefin having a density in the range of 890 to 940 kg/m 3 , and
(c) at least 1.4 wt. % of a second α-nucleating agent (NU2) which is different from the first α-nucleating agent (NU1),
based on the overall weight of the polypropylene composition (C).
2. The polypropylene composition (C) according to claim 1 , wherein the heterophasic composition (HECO) has:
i) a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in the range of 5.0 to 40.0 g/10 min, and/or
ii) a comonomer content in the range of 2.0 to 15.0 mol.
3. The polypropylene composition (C) according to claim 1 , wherein the (semi)crystalline polypropylene (PP1) comprises at least two (semi)crystalline polypropylene fractions which differ in the melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133.
4. The polypropylene composition (C) according to claim 1 , wherein the (semi)crystalline polypropylene (PP1) comprises:
(a) a first (semi)crystalline polypropylene fraction (PP1a) having a melt flow rate MFR 2 (230° C./2.16 kg) in the range of 30.0 to 120.0 g/10 min, and
(b) a second (semi)crystalline polypropylene fraction (PP1b) having a melt flow rate MFR 2 (230° C./2.16 kg) in the range of 5.0 to 25.0 g/10 min.
5. The polypropylene composition (C) according to claim 1 , wherein the heterophasic composition (HECO) has a xylene soluble fraction (XCS) in the range of 5.0 to 30.0 wt.-%.
6. The polypropylene composition (C) according to claim 1 , wherein the xylene soluble fraction (XCS) of the heterophasic composition (HECO) has:
i) an ethylene content in the range of 25.0 to 60.0 mol-%, and/or
ii) an intrinsic viscosity (IV) determined according to DIN ISO 1628/1, October 1999 (in Decalin at 135° C.) in the range of 3.0 to 4.5 dl/g.
7. The polypropylene composition (C) according to claim 1 , wherein:
i) the first α-nucleating agent (NU1) is a polymeric nucleating agent, and
ii) the second α-nucleating agent (NU2) is a non-polymeric nucleating agent.
8. The polypropylene composition (C) according to claim 7 , wherein the first α-nucleating agent (NU1) is a polymeric vinylcycloalkane.
9. The polypropylene composition (C) according to claim 7 , wherein the second α-nucleating agent (NU2) is selected from the group consisting of talc, salts of diesters of phosphoric acid or mixtures thereof.
10. The polypropylene composition (C) according to claim 1 , comprising:
(a) 80.0 to 95.0 wt. % of the heterophasic composition (HECO),
(b) 5.0 to 15.0 wt. % of the polyethylene (PE) being a copolymer of ethylene and a C 4 -C 12 α-olefin, and
(c) 1.4 to 5.0 wt. % of the second α-nucleating agent (NU2).
11. The polypropylene composition (C) according to claim 1 , wherein the polyethylene (PE) is a copolymer of ethylene and 1-butene.
12. The polypropylene composition (C) according to claim 1 , wherein the polyethylene (PE) has:
a melt flow rate MFR 5 (190° C., 5.0 kg) determined according to ISO 1133 equal or below 3.0 g/10 min.
13. The polypropylene composition (C) according to claim 1 , having:
i) a flexural modulus determined according to ISO 178 of at least 1400 MPa, and/or
ii) a Charpy notched impact strength determined according to ISO 179/1eA at 23° C. of at least 8.0 kJ/m 2 .
14. The polypropylene composition (C) according to claim 1 , wherein the (semi)crystalline polypropylene (PP1) is a propylene homopolymer (H-PP) comprising:
(a) a first propylene homopolymer fraction (H-PP1a) having a melt flow rate MFR 2 (230° C./2.16 kg) in the range of 30.0 to 120.0 g/10 min, and
(b) a second propylene homopolymer fraction (H-PP1b) having a melt flow rate MFR 2 (230° C./2.16 kg) in the range of 5.0 to 25.0 g/10 min.
15. An article comprising the polypropylene composition (C) according to claim 1 .
16. The article according to claim 15 , wherein said article is a car seat, a stroller, a baby walker, a toy, a heavy duty pail or a transport packaging.
17. A method for preparing the polypropylene composition (C) according to claim 1 , comprising the steps of:
i) preparing the α-nucleated heterophasic propylene copolymer (HECO) in a sequential polymerization process comprising at least three reactors, wherein the (semi)crystalline polypropylene (PP1) is produced in the first and/or second reactor in the presence of the first α-nucleating agent (NU1) and the elastomeric ethylene/propylene copolymer (EPR) is produced in a subsequent reactor, and
ii) blending the α-nucleated heterophasic propylene copolymer (HECO) obtained in step i) with the polyethylene (PE) being a copolymer of ethylene and a C 4 -C 12 α-olefin and the second α-nucleating agent (NU2).