Solid-state battery
A solid-state battery is provided that allows the exterior can to be sufficiently crimped onto the seal can without leading to improper crimping, thus preventing entry of water from the outside. The solid-state battery 1 includes an exterior can 2 , a seal can 3 , facing the exterior can 2 and a power generation element 4 contained in the space between the exterior can 2 and seal can 3 . The seal can 3 includes a flat portion 31 and a peripheral wall 32 that are contiguous to each other with a curved-surface portion 33 provided therebetween. A first clearance g 1 is defined between the upper edge of the outer peripheral surface of the power generation element 4 and the border 10 between the inner surface of the flat portion 31 and the inner surface of the curved-surface portion 33 , the first clearance having a radial dimension not larger than 2.0 mm at a position where its dimension is at its largest. This will facilitate positioning of the power generation element 4 to properly place it inside the seal can 3 , thereby preventing positional displacement of the power generation element 4.
1. A solid-state battery comprising:
an exterior can having a can bottom and a cylindrical side wall;
a seal can having a flat portion and a peripheral wall and facing the exterior can; and
a power generation element contained between the exterior can and the seal can and including a cathode material layer, an anode material layer, and a solid electrolyte layer located between the cathode material layer and the anode material layer,
wherein the flat portion and the peripheral wall are contiguous to each other with a curved-surface portion provided therebetween,
a first clearance is defined between an upper edge of an outer peripheral surface of the power generation element, on one hand, and a first border between an inner surface of the flat portion and an inner surface of the curved-surface portion, on the other hand, the first clearance being annular in shape in plan view, and
the first clearance has a radial dimension not larger than 2.0 mm at a position where the first clearance is at its largest.
2. The solid-state battery according to claim 1 , wherein a distance between a diameter of the inner surface of the flat portion and a diameter of the power generation element is not larger than 2.0 mm.
3. The solid-state battery according to claim 1 , wherein the first clearance has a radial dimension not smaller than 0.01 mm.
4. The solid-state battery according to claim 1 , wherein the peripheral wall includes a base-end portion located adjacent to the curved-surface portion, an outspread portion having a diameter larger than an outer diameter of the base-end portion and located adjacent to an open edge, and a stepped portion between the base-end portion and the outspread portion.
5. The solid-state battery according to claim 1 , further comprising:
a gasket located between the cylindrical side wall and the peripheral wall,
wherein the gasket includes a gasket bottom portion located between the can bottom and an open edge of the peripheral wall and protruding radially inwardly from the peripheral wall,
a second clearance is defined between the outer peripheral surface of the power generation element and a surface of inner circumference of the gasket bottom portion, and
the second clearance has a radial dimension not larger than 2.0 mm at a position where the second clearance is at its largest.
6. The solid-state battery according to claim 5 , wherein a difference between an inner diameter of the surface of inner circumference of the gasket bottom portion and a diameter of the power generation element is not larger than 2.0 mm.
7. The solid-state battery according to claim 5 , wherein the second clearance has a radial dimension not smaller than 0.01 mm.
8. The solid-state battery according to claim 5 , wherein a plurality of power generation elements connected in series are stacked on top of each other and contained between the can bottom and the flat portion,
the first clearance is defined between an upper edge of an outer peripheral surface of that power generation element which is located closest to the flat portion, on one hand, and the first border between the inner surface of the flat portion and the inner surface of the curved-surface portion, on the other hand, and
the second clearance is defined between an outer peripheral surface of that power generation element which is located closest to the can bottom and the surface of inner circumference of the gasket bottom portion.
9. The solid-state battery according to claim 4 , wherein a plurality of power generation elements connected in series are stacked on top of each other and contained between the can bottom and the flat portion,
an inner surface of the base-end portion has a second border between a side surface contiguous to the inner surface of the curved-surface portion and a curvature surface contiguous to the side surface and an inner surface of the stepped portion,
if that power generation element located closest to the flat portion is a cathode material layer, a height distance between the inner surface of the flat portion and the second border is smaller than a height distance between the inner surface of the flat portion and an upper edge of an outer peripheral surface of that anode material layer which is closest to the flat portion, and,
if that power generation element located closest to the flat portion is an anode material layer, the height distance between the inner surface of the flat portion and the second border is smaller than a height distance between the inner surface of the flat portion and an upper edge of an outer peripheral surface of that cathode material layer which is closest to the flat portion.
10. The solid-state battery according to claim 9 , wherein the side surface expands radially outwardly with increasing distance from the flat portion in an axial direction.