Granted Patent B2

US 12,312,693 · App. 17/273,522 · Granted May 27, 2025

Inventors: Lars Sebralla (Frankfurt am Main, DE); Nawel Souad Khelfallah (Frankfurt am Main, DE); Axel Schoene (Frankfurt am Main, DE); Marie-Pierre Labeau (Sèvres, FR); Guillaume Gody (Rueil-Malmaison, FR)

Assignees: RHODIA OPERATIONS; CHEMETALL GMBH

C23C22/361C08K3/10C23C22/82C23F11/1676C08K2003/2237C08K2003/2244

Abstract

Claims (37)

1. A method for treatment of at least one surface of a substrate, wherein said surface is at least partially made of aluminum and/or an aluminum alloy, comprising at least a step (1) of contacting said at least one surface with an acidic aqueous composition (A), the acidic aqueous composition (A) comprising

(a) one or more metal compounds (M) selected from the group consisting of complex fluorides of titanium, zirconium, hafnium, and mixtures thereof, and

(b) one or more linear polymers (P) prepared by controlled radical polymerization containing

(m1) hydroxyethyl- and/or hydroxypropyl-(meth)acrylate,

(m2) vinylphosphonic acid, and

(m3) (meth)acrylic acid

in a form of their polymerized monomeric units,

said one or more linear polymers (P) being comprised in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm, based on a total weight of the acidic aqueous composition (A).

2. The method according to claim 1 , characterized in that the surface of the substrate consists of aluminum or an aluminum alloy.

3. The method according to claim 1 , characterized in that the acidic aqueous composition (A) has a pH in a range of 0.5 to 6.5.

4. The method according to claim 1 , characterized in that the one or more metal compounds (M) are comprised in the acidic aqueous composition (A) in a concentration in a range of 50 to 5000 ppm, based in each case on titanium, zirconium, and/or hafnium as metal.

5. The method according claim 1 , characterized in that the one or more linear polymers (P) contain polymerized monomeric units of hydroxyethyl (meth)acrylate as monomeric unit (m1).

6. The method according to claim 1 , characterized in that the one or more linear polymers (P) are comprised in the acidic aqueous composition (A) in a concentration in a range of 100 to 4000 ppm.

7. The method according to claim 1 , characterized in that the one or more linear polymers (P) have a number average molecular weight in a range of 10,000 to 42,000 g/mol.

8. The method according to claim 1 , characterized in that the acidic aqueous composition (A) comprises free fluoride in a range of 1 to 250 ppm.

9. The method according to claim 1 , characterized in that the method comprises an additional coating step of applying at least one coating composition to the surface of the substrate obtained after the contacting step (1) to form a coating layer upon the surface, wherein optionally after step (1) a rinsing step (2) is carried out prior to said coating step.

10. An acidic aqueous composition (A) comprising

(a) one or more metal compounds (M) selected from the group consisting of complex fluorides of titanium, zirconium, hafnium, and mixtures thereof, and

(b) one or more linear polymers (P) prepared by controlled radical polymerization containing

(m1) hydroxyethyl- and/or hydroxypropyl-(meth)acrylate,

(m2) vinylphosphonic acid, and

(m3) (meth)acrylic acid

in a form of their polymerized monomeric units,

said one or more linear polymers (P) being comprised in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm, based on a total weight of the acidic aqueous composition (A).

11. The method according to claim 1 , wherein the one or more linear polymers (P) contain hydroxyethyl- and/or hydroxypropyl-(meth)acrylate monomeric units (m1) in an amount of 20 to 65 mol-%, vinyl phosphonic acid monomeric units (m2) in an amount of 3 to 35 mol-%, and (meth)acrylic acid monomeric units (m3) in an amount of 25 to 70 mol-%, based on the total amount of all monomeric units of the one or more linear polymers (P), wherein the sum of all monomeric units present in the one or more linear polymers (P) adds up to 100 mol-%.

12. The method according to claim 1 , wherein the one or more linear polymers (P) have a number average molecular weight Mn in a range of 5,000 to 60,000 g/mol.

13. The method according to claim 1 , wherein the acidic aqueous composition (A) contains at least 60 wt.-% of water, based on its total content of organic and inorganic solvents including water.

14. A master batch for producing the acidic aqueous composition (A) according to claim 10 , wherein the acidic aqueous composition (A) is produced by diluting the master batch with water and optionally by adjusting a pH value, and wherein the master batch comprises, besides water:

(a) one or more metal compounds (M) selected from the group consisting of complex fluorides of titanium, zirconium, hafnium, and mixtures thereof, and

(b) one or more linear polymers (P) prepared by controlled radical polymerization containing

(m1) hydroxyethyl- and/or hydroxypropyl-(meth)acrylate,

(m2) vinylphosphonic acid, and

(m3) (meth)acrylic acid

in a form of their polymerized monomeric units,

and wherein the master batch comprises ingredients (a) and (b) in a higher concentration than the acidic aqueous composition (A).

15. The method according to claim 1 , wherein the method provides corrosion protection to the surface and/or provides an increased adhesion of further coatings applied onto the treated surface.

16. A substrate comprising at least one surface, wherein said surface is at least partially made of aluminum and/or an aluminum alloy, wherein said at least one surface has been treated by the acidic composition (A) according to claim 10 .

Assignments (3)

Priority Claims (1)

Continuity (1)

References Cited (16)