IP Library Granted Patent US 11,505,735
Granted Patent B2
US 11,505,735 · App. 17/275,929 · Granted Nov 22, 2022

Friction reducing additives including nanoparticles

Inventors: Liang X. Xu (The Woodlands, TX); James W. Ogle (Livingston, TX)
Assignee: Halliburton Energy Services. Inc.
C09K8/68C09K8/602C09K8/665B82Y30/00B82Y40/00C09K2208/10C09K2208/28
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Quick Facts
Patent No.
US 11,505,735
App. No.
17/275,929
Granted
Nov 22, 2022
Kind
B2
Abstract

Compositions and methods for use in fracturing treatments using friction reducing additives that include nanoparticles are provided. In some embodiments, the methods include: providing a treatment fluid that includes an aqueous base fluid and a friction reducing additive, the friction reducing additive including at least one polymer and a plurality of nanoparticles; and introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

Claims (34)

1. A method comprising:

providing a treatment fluid that comprises an aqueous base fluid and a friction reducing additive, the friction reducing additive comprising at least one polymer and a plurality of nanoparticles,

wherein the polymer comprises at least one multifunctional polymer that comprises one or more functional groups selected from the group consisting of: a choline group, a diallyldimethylammonium chloride group, and any combination thereof, and

wherein the polymer is present in an amount in a range of from less than about 2 gallons per thousand gallons of the treatment fluid to greater than 0 gallons per thousand gallons of the treatment fluid and the plurality of nanoparticles are present in an amount of from about 0.01% to about 5% by volume of the treatment fluid; and

introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

2. The method of claim 1 wherein the polymer comprises an anionic polymer.

3. The method of claim 1 wherein the polymer comprises a cationic polymer.

4. The method of claim 1 wherein the polymer comprises an amphoteric polymer.

5. The method of claim 1 wherein the polymer comprises a cationic acrylamide-based polymer.

6. The method of claim 1 wherein the polymer comprises at least one multifunctional polymer that comprises one or more choline groups.

7. The method of claim 1 wherein the aqueous base fluid comprises a brine.

8. The method of claim 1 wherein the aqueous base fluid comprises produced water.

9. The method of claim 1 wherein the plurality of nanoparticles comprise at least one material selected from the group consisting of: silica, graphene, a metal, an alkaline earth metal, a metal oxide, boron, laponite, a hydroxide, a polymer, carbon, a clay, a composite material, and any combination thereof.

10. The method of claim 1 wherein the plurality of nanoparticles comprises a plurality of functionalized nanoparticles.

11. The method of claim 1 wherein the treatment fluid further comprises at least one surfactant.

12. The method of claim 1 wherein the treatment fluid has an initial viscosity of from about 4 cP to about 50 cP.

13. A method comprising:

providing a treatment fluid that comprises an aqueous base fluid and a friction reducing additive, wherein

the friction reducing additive comprises at least one polymer, a surfactant, and a plurality of nanoparticles,

the polymer comprises at least one multifunctional polymer that comprises one or more functional groups selected from the group consisting of: a choline group, a diallyldimethylammonium chloride group, and any combination thereof,

the polymer is present in an amount in a range of less than about 2 gallons per thousand gallons of the treatment fluid to greater than 0 gallons per thousand gallons of the treatment fluid,

the plurality of nanoparticles are present in an amount of from about 0.01% to about 5% by volume of the treatment fluid, and

the treatment fluid has a viscosity of from about 4 cP to about 50 cP; and

introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

14. The method of claim 13 wherein the plurality of nanoparticles comprises clay nanoparticles.

15. The method of claim 13 wherein the polymer comprises at least one multifunctional polymer that comprises one or more choline groups.

16. A method comprising:

providing a treatment fluid that comprises an aqueous base fluid and a friction reducing additive, wherein the friction reducing additive comprises

at least one acrylamide-based polymer, wherein the acrylamide-based polymer comprises at least one multifunctional polymer that comprises one or more functional groups selected from the group consisting of: a choline group, a diallyldimethylammonium chloride group, and any combination thereof and is present in an amount in a range of from less than about 2 gallons per thousand gallons of the treatment fluid to greater than 0 gallons per thousand gallons of the treatment fluid,

a surfactant, and

a plurality of clay nanoparticles, wherein the plurality of clay nanoparticles are present in an amount of from about 0.01% to about 5% by volume of the treatment fluid; and

introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

17. The method of claim 16 wherein the acrylamide-based polymer comprises at least one multifunctional acrylamide-based polymer that comprises one or more a choline groups.

18. The method of claim 16 wherein the treatment fluid has an initial viscosity in a range of from about 4 cP to about 50 cP.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2021
From: XU, LIANG X.; OGLE, JAMES W.
To: MULTI-CHEM GROUP, LLC.
Reel/Frame 055624/0889 →
Continuity (1)
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