High speed cross-linking of grafted plastomers
The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-α-olefin plastomer having—a density of from 850 kg/m 3 to 900 kg/m 3 ; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-α-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt. % with respect to the grafted ethylene-α-olefin plastomer; (c) contacting said grafted ethylene-α-olefin plastomer with 2 to 8 wt. % of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.
1. A process for providing a cross-linked composition, the process comprising the steps of
(a) providing an ethylene-α-olefin plastomer which is a copolymer of ethylene and 1-octene and providing no other polymer, the ethylene-α-olefin plastomer having
a density of from 850 kg/m 3 to 900 kg/m 3 ; and
a melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min;
(b) grafting the ethylene-α-olefin plastomer from step (a) with a silane crosslinker such that the content of the silane crosslinker is in the range of 0.1 to 10.0 wt. % with respect to the resulting grafted ethylene-α-olefin plastomer; and
(c) contacting said grafted ethylene-α-olefin plastomer from step (b) with 2 to 8 wt. % of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-free silane crosslinking catalyst to form an intermediate composition, which in turn forms a cross-linked composition having a gel content of at least 60% when subjected to 23° C. and 50% humidity for 15 minutes, and wherein said tin-free catalyst comprises a sulfonic acid;
wherein step c) is carried out:
in an extruder; and/or
at a temperature 120 to 210° C.
2. The process according to claim 1 , wherein the ethylene-α-olefin plastomer has
a density of from 865 to 895 kg/m 3 ; and
a melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.40 to 2 g/10min.
3. The process according to claim 1 , wherein the ethylene content of the ethylene-a-olefin plastomer is from 60.0 to 95.0 wt %.
4. The process according to claim 1 , wherein the 1-octane content of the ethylene-α-olefin plastomer is up to 40.0 wt %.
5. The process according to claim 1 , wherein a gel content of said cross-linked composition after 15 min of contacting is at least 70%.
6. The process according to claim 1 , wherein step b) takes place
in an extruder; and/or
at a temperature 120 to 210° C.
7. The process according to claim 1 , wherein step b) is initiated by a free radical forming agent.
8. The process according to claim 1 , wherein the grafted ethylene-α-olefin plastomer is formed into pellets.