Hot rolled and unannealed ferritic stainless steel sheet having excellent impact toughness, and manufacturing method therefor
A non-annealed hot-rolled ferritic stainless steel sheet with excellent impact toughness includes, in percent (%) by weight of the entire composition, C: more than 0 and 0.03% or less, Si: 0.1 to 0.5%, Mn: 1.5% or less, P: 0.04% or less, Cr: 10.5 to 14%, Ni: more than 0 and 1.5% or less, Ti: 0.01 to 0.5%, Cu: more than 0 and 1.0% or less, N: more than 0 and 0.015% or less, Al: 0.1% or less, the remainder of iron (Fe) and other inevitable impurities, and satisfies the following equation (1), and the average grain size of the cross-sectional microstructure in the direction perpendicular to the rolling direction is 60 μm or less. (1500≤(1001.5*C+950.6*Mn+1350.5*Ni+395.6*Cu−0.7*Si−1.0*Ti−0.1*Cr−1.0*P−1.0*Al+1020.5*N)≤2200). (1).
1. A non-annealed hot-rolled ferritic stainless steel sheet, the ferritic stainless steel comprising, in percent by weight of the entire composition, C: more than 0 and 0.03% or less, Si: 0.1 to 0.5%, Mn: 1.5% or less, P: 0.04% or less, Cr: 10.5 to 14%, Ni: more than 0 and 1.5% or less, Ti: 0.01 to 0.5%, Cu: more than 0 and 1.0% or less, N: more than 0 and 0.015% or less, Al: 0.1% or less, the remainder of iron and other inevitable impurities, and
satisfying the following equation (1), and an average grain size of a cross-sectional microstructure in a direction perpendicular to a rolling direction is 60 μm or less:
1500≤(1001.5*C+950.6*Mn+1350.5*Ni+395.6*Cu−0.7*Si−1.0*Ti−0.1*Cr−1.0*P−1.0*Al+1020.5*N)≤2200 (1)
wherein C, Mn, Ni, Cu, Si, Ti, Cr, P, Al and N mean the content of each element in percent by weight,
wherein the non-annealed hot-rolled ferritic stainless steel sheet has a thickness of 6.0 to 25.0 mm,
wherein a fraction of grain boundary having a misorientation between grains of the microstructure of 15 to 180° is 55% or more, and
wherein an austenite phase fraction is 30% or more at a reheating temperature for hot rolling.
2. The ferritic stainless steel sheet according to claim 1 , wherein a −20° C. Charpy impact energy is 150 J/cm 2 or more.
3. The ferritic stainless steel sheet according to claim 1 , wherein an average size of grains having the misorientation between the grains of the microstructure of 15 to 180° is 60 μm or less.
4. The ferritic stainless steel sheet according to claim 1 , wherein an average size of grains having a misorientation between grains of the microstructure of 5 to 180° is 30 μm or less.
5. The ferritic stainless steel sheet according to claim 4 , wherein the austenite phase fraction is 40% or more at the reheating temperature for the hot rolling.
6. The ferritic stainless steel sheet according to claim 4 , wherein the reheating temperature for the hot rolling is 1,200° C. to 1,220° C.
7. The ferritic stainless steel sheet according to claim 4 , wherein the ferritic stainless steel sheet is non-annealed.
8. The ferritic stainless steel sheet according to claim 1 , wherein an average size of grains having a misorientation between grains of the microstructure of 2 to 180° is 20 μm or less.
9. The ferritic stainless steel sheet according to claim 1 , wherein a fraction of grain boundary having a misorientation between grains of the microstructure of 5 to 15° is 25% or less.
10. The ferritic stainless steel sheet according to claim 1 , wherein a fraction of grain boundary having a misorientation between grains of the microstructure of 2 to 5° is 16% or less.
11. The ferritic stainless steel sheet according to claim 1 , wherein a −20° C. Charpy impact energy is 150 J/cm 2 or more, an average size of grains having the misorientation between the grains of the microstructure of 15 to 180° is 60 μm or less, an average size of grains having a misorientation between grains of the microstructure of 5 to 180° is 30 μm or less, an average size of grains having a misorientation between grains of the microstructure of 2 to 180° is 20 μm or less, a fraction of grain boundary having a misorientation between grains of the microstructure of 5 to 15° is 25% or less, and a fraction of grain boundary having a misorientation between grains of the microstructure of 2 to 5° is 16% or less.
12. A manufacturing method of a non-annealed hot-rolled ferritic stainless steel sheet with excellent impact toughness, the method comprising:
heating the slab containing in percent (%) by weight of the entire composition, C: more than 0 and 0.03% or less, Si: 0.1 to 0.5%, Mn: 1.5% or less, P: 0.04% or less, Cr: 10.5 to 14%, Ni: more than 0 and 1.5% or less, Ti: 0.01 to 0.5%, Cu: more than 0 and 1.0% or less, N: more than 0 and 0.015% or less, Al: 0.1% or less, the remainder of iron (Fe) and other inevitable impurities, at 1,220° C. or less;
rough rolling the heated slab;
finishing rolling the rough rolled bar; and
winding up a hot-rolled steel sheet, and
the reduction ratio in the last rolling mill of the rough rolling is 27% or more,
the coiling temperature is Acl to 800° C.
13. The manufacturing method according to claim 12 , wherein the slab satisfies the following equation (1),
1500≤(1001.5*C+950.6*Mn+1350.5*Ni+395.6*Cu−0.7*Si−1.0*Ti−0.1*Cr−1.0*P−1.0*Al+1020.5*N)≤2200 (1)
(Here, C, Mn, Ni, Cu, Si, Ti, Cr, P, Al and N mean the content (% by weight) of each element).
14. The manufacturing method according to claim 12 , wherein the temperature of the rough rolled bar is 1,020 to 970° C.,
wherein the finishing rolling end temperature is 920° C. or less.
15. The manufacturing method according to claim 12 , wherein the thickness of the hot rolled steel sheet is 6.0 to 25.0 mm.
16. The manufacturing method according to claim 12 , wherein the microstructure of the cross-section in the direction perpendicular to the rolling direction of the wound hot-rolled steel sheet has an average size of grains having a misorientation between grains of 15 to 180° of 60 μm or less.
17. The manufacturing method according to claim 12 , wherein the microstructure of the cross-section in the direction perpendicular to the rolling direction of the wound hot-rolled steel sheet has a fraction of grain boundary having a misorientation between grains of the microstructure of 15 to 180° of 55% or more.