Two-part curable adhesive composition
A two-part curable adhesive composition includes a main agent (A) containing a urethane prepolymer (a1) and a remaining polyisocyanate (a2), and a curing agent (B) containing a non-crystalline polyol compound (b1) and a polyamine compound (b2). An equivalent ratio of an isocyanate group in a raw polyisocyanate to a hydroxyl group in a crystalline polyol compound constituting the urethane prepolymer (a1) is from 2.05 to 12. An NCO group/total active hydrogen group ratio is from 0.5 to 4. An isocyanate group/hydroxyl group ratio is from 2 to 12.
1. A two-part curable adhesive composition comprising:
a main agent (A) containing a urethane prepolymer (a1); and
a curing agent (B) containing a non-crystalline polyol compound (b1) and a polyamine compound (b2),
the urethane prepolymer (a1) being obtained by reacting a raw polyisocyanate and a crystalline polyol compound having a number average molecular weight of 500 or greater and having at least one hydroxyl group per molecule in such a manner that an equivalent ratio of an isocyanate group in the raw polyisocyanate to the hydroxyl group in the crystalline polyol compound is from 2.05 to 12 and all of the crystalline polyol compounds are monomer units of the urethane prepolymer (a1),
the crystalline polyol compound being at least one selected from polyester polyol, polytetramethylene ether glycol, polycarbonate polyol, and polycaprolactone polyol,
the main agent (A) further containing, in addition to the urethane prepolymer (a1), a remaining polyisocyanate (a2) that is a remainder of the raw polyisocyanate that has not been reacted with the crystalline polyol compound,
the non-crystalline polyol compound (b1) being a compound having a number average molecular weight of 1000 or more and having at least two hydroxyl groups per molecule, and being at least one selected from polyoxypropylene glycol, polybutadiene polyol, polyisoprene polyol, and acrylic polyol,
the equivalent ratio of the isocyanate group in the main agent (A) to total active hydrogen groups in the curing agent (B) being from 0.5 to 4,
the equivalent ratio of the isocyanate group in the main agent (A) to the hydroxyl group in the non-crystalline polyol compound (b1) being from 2 to 12, and
a ratio of a mass of the crystalline polyol compound to a mass of the non-crystalline polyol compound (b1) being 1 or less.
2. The two-part curable adhesive composition according to claim 1 , wherein the equivalent ratio of the amino group in the polyamine compound (b2) to the hydroxyl group of the non-crystalline polyol compound (b1) is from 1.5 to 6.
3. The two-part curable adhesive composition according to claim 1 , wherein a terminal end of the non-crystalline polyol compound (b1) comprises at least one selected from a primary hydroxyl group, and a secondary hydroxyl group.
4. A two-part curable adhesive composition comprising:
a main agent (A) containing a urethane prepolymer (a1); and
a curing agent (B) containing a non-crystalline polyol compound (b1) and a polyamine compound (b2),
the urethane prepolymer (a1) being obtained by reacting a raw polyisocyanate and a crystalline polyol compound having a number average molecular weight of 500 or greater and having at least one hydroxyl group per molecule in such a manner that an equivalent ratio of an isocyanate group in the raw polyisocyanate to the hydroxyl group in the crystalline polyol compound is from 2.05 to 12 and all of the crystalline polyol compounds are monomer units of the urethane prepolymer (a1),
the crystalline polyol compound being at least one selected from polyester polyol, polytetramethylene ether glycol, polycarbonate polyol, and polycaprolactone polyol,
the main agent (A) further containing, in addition to the urethane prepolymer (a1), a remaining polyisocyanate (a2) that is a remainder of the raw polyisocyanate that has not been reacted with the crystalline polyol compound,
the non-crystalline polyol compound (b1) being a compound having a number average molecular weight of 1000 or more and having at least two hydroxyl groups per molecule, and being at least one selected from polyoxypropylene glycol, polybutadiene polyol, polyisoprene polyol, and acrylic polyol,
the equivalent ratio of the isocyanate group in the main agent (A) to total active hydrogen groups in the curing agent (B) being from 0.5 to 4,
the equivalent ratio of the isocyanate group in the main agent (A) to the hydroxyl group in the non-crystalline polyol compound (b1) being from 2 to 12, and the curing agent (B) further contains a hydroxyl group-containing compound (b3) having a number average molecular weight of 200 or less in an amount of 5% by mass or more of the curing agent (B).
5. The two-part curable adhesive composition according to claim 1 , wherein the remaining polyisocyanate (a2) is at least one selected from diphenylmethane diisocyanate, polymeric methane diisocyanate, and isocyanate compound having an isocyanurate group.
6. The two-part curable adhesive composition according to claim 1 , wherein the polyamine compound (b2) has a number average molecular weight of less than 500 and has at least two amino groups and at least one aromatic group per molecule.
7. The two-part curable adhesive composition according to claim 1 , wherein the cured product obtained by curing the two-part curable adhesive composition has a tensile strength in accordance with JIS K6251 of 15 MPa or more and an elongation at break of 120% or greater.
8. The two-part curable adhesive composition according to claim 1 , wherein the cured product obtained by curing the two-part curable adhesive composition has a tensile modulus of 50 MPa or greater.
9. The two-part curable adhesive composition according to claim 1 , wherein a usable time is from 30 seconds to 10 minutes.