Non-oriented electrical steel sheet and manufacturing method therefor
The present invention relates to a non-grain-oriented electrical steel sheet which is excellent in high-frequency iron loss, and a manufacturing method thereof. A non-grain-oriented electrical steel sheet according to an exemplary embodiment of the present invention includes 2.5 to 3.8 wt % of Si, 0.5 to 2.5 wt % of Al, 0.2 to 4.5 wt % of Mn, 0.0005 to 0.02 wt % of As, 0.0005 to 0.01 wt % of Bi, the balance Fe, and inevitable impurities, and satisfies the following [Equation 1]. 0.3≤[surface fine crystal grain diameter]×[fine grain formation thickness]×([As]/[Bi])≤5.0 [Equation 1] In Equation 1, [surface fine crystal grain diameter] means an average particle diameter (μm) of fine crystal grains in an electrode surface layer of an electrical steel sheet, [fine grain formation thickness] means a thickness (mm) of an electrode surface layer in which fine crystal grains are formed, and [As] and [Bi] mean a composition (wt %) of As and a composition (wt %) of Bi, respectively.
1. A non-grain-oriented electrical steel sheet comprising 2.5 to 3.8 wt % of Si, 0.5 to 2.5 wt % of Al, 0.2 to 4.5 wt % of Mn, 0.0005 to 0.02 wt % of As, 0.0005 to 0.01 wt % of Bi, the balance Fe, and inevitable impurities, and satisfying the following [Equation 1]
0.3≤[surface fine crystal grain diameter]×[fine grain formation thickness]×([As]/[Bi])≤5.0 [Equation 1]
(in Equation 1, [surface fine crystal grain diameter] means an average particle diameter (μm) of fine crystal grains in an outermost surface layer of the non-grain-oriented electrical steel sheet, [fine grain formation thickness] means a thickness (mm) of the outermost surface layer in which fine crystal grains are formed, and [As] and [Bi] mean a composition (wt %) of As and a composition (wt %) of Bi, respectively,
wherein the fine crystal grain is a grain having diameter less than 25% of the average crystal grain diameter, and the outermost surface layer is part from the surface to less than 10% of the thickness of the electrical steel sheet.
2. The non-grain-oriented electrical steel sheet of claim 1 , wherein:
a sum of As and Bi is 0.0005 to 0.025%.
3. The non-grain-oriented electrical steel sheet of claim 1 , wherein:
the non-grain-oriented electrical steel sheet satisfies the following [Equation 2]
1≤[As]/[Bi]≤10 [Equation 2]
(in Equation 2, [As] and [Bi] mean a composition (wt %) of As and a composition (wt %) of Bi in a slab, respectively.
4. The non-grain-oriented electrical steel sheet of claim 1 , wherein:
the non-grain-oriented electrical steel sheet further comprises one or more of 0.0040 wt % or less (excluding 0 wt %) of N, 0.0040 wt % or less (excluding 0 wt %) of C, 0.0040 wt % or less (excluding 0 wt %) of S, 0.0040 wt % or less (excluding 0 wt %) of Ti, 0.0040 wt % or less (excluding 0 wt %) of Nb, and 0.0040 wt % or less (excluding 0 wt %) of V.
5. The non-grain-oriented electrical steel sheet of claim 1 , wherein:
the non-grain-oriented electrical steel sheet has a specific resistance of 45 μΩ·cm or more.
6. The non-grain-oriented electrical steel sheet of claim 1 , wherein:
the non-grain-oriented electrical steel sheet may have an iron loss (W0.5/10000) of 10 W/kg or less.
7. The non-grain-oriented electrical steel sheet of claim 1 , comprising 0.001 to 0.02 wt % of As.
8. The non-grain-oriented electrical steel sheet of claim 1 , comprising 0.005 to 0.02 wt % of As.
9. A method for manufacturing a non-grain-oriented electrical steel sheet, the method comprising:
a step for preparing a slab comprising 2.5 to 3.8 wt % of Si, 0.5 to 2.5 wt % of Al, 0.2 to 4.5 wt % of Mn, 0.0005 to 0.02 wt % of As, 0.0005 to 0.01 wt % of Bi, the balance Fe, and inevitable impurities;
a step for heating the slab;
a step for hot-rolling the heated slab to produce a hot-rolled sheet;
a step for cold-rolling the hot-rolled sheet to produce a cold-rolled sheet; and
a step for subjecting the cold-rolled sheet to final annealing to manufacture an electrical steel sheet,
wherein in the step for subjecting the cold-rolled sheet to final annealing, a heating rate up to 700° C. is set at 10° C./s or more,
wherein the electrical steel sheet satisfies [Equation 1]
0.3≤[surface fine crystal grain diameter]×[fine grain formation thickness]×([As]/[Bi])≤5.0 [Equation 1]
in Equation 1, [surface fine crystal grain diameter] means an average particle diameter (μm) of fine crystal grains in an outermost surface layer of the non-grain-oriented electrical steel sheet, [fine grain formation thickness] means a thickness (mm) of the outermost surface layer in which fine crystal grains are formed, and [As] and [Bi] mean a composition (wt %) of As and a composition (wt %) of Bi, respectively,
wherein the fine crystal grain is a grain having diameter less than 25% of the average crystal grain diameter, and the outermost surface layer is part from the surface to less than 10% of the thickness of the electrical steel sheet.
10. The method of claim 9 , wherein:
a sum of As and Bi of the slab is 0.0005 to 0.025%.
11. The method of claim 9 , wherein:
the slab satisfies [Equation 2]
1≤[As]/[Bi]≤10 [Equation 2]
(in Equation 2, [As] and [Bi] mean a composition (wt %) of As and a composition (wt %) of Bi in a slab, respectively.
12. The method of claim 9 , wherein:
the slab further comprises one or more of 0.0040 wt % or less (excluding 0 wt %) of N, 0.0040 wt % or less (excluding 0 wt %) of C, 0.0040 wt % or less (excluding 0 wt %) of S, 0.0040 wt % or less (excluding 0 wt %) of Ti, 0.0040 wt % or less (excluding 0 wt %) of Nb, and 0.0040 wt % or less (excluding 0 wt %) of V.
13. The method of claim 9 ,
after the step for manufacturing a hot-rolled sheet,
further comprising a step for subjecting the hot-rolled sheet to hot-rolled sheet annealing.