Cryogenic austenitic high-manganese steel having excellent corrosion resistance, and manufacturing method therefor
The cryogenic austenitic high-manganese steel having excellent corrosion resistance, according to one aspect of the present invention, comprises 0.2-0.5 wt % of C, 23-28 wt % of Mn, 0.05-0.5 wt % of Si, 0.03 wt % or less of P, 0.005 wt % or less of S, 0.5 wt % or less of Al, and 3-4 wt % of Cr, with the remainder being Fe and other unavoidable impurities, also comprises at least 95 area % of austenite as a microstructure, and has Cr concentration sections continuously formed within an area of 50 μm in the thickness direction from the surface, wherein the Cr concentration sections comprise a high Cr concentration section having a relatively high concentration of Cr, and a low Cr concentration section having a relatively low concentration of Cr, and the high Cr concentration section may be distributed at 30 area % or less (but not 0%) relative to the whole surface area of the Cr sections.
1. A cryogenic austenitic high-manganese steel material having excellent corrosion resistance, comprising:
by weight %, 0.2-0.5% of C, 23-28% of Mn, 0.05-0.5% of Si, 0.03% or less of P, 0.005% or less of S, 0.5% or less of Al, 3-4% of Cr, and a balance of Fe and inevitable impurities;
95 area % or more of austenite as a microstructure; and
a Cr concentration section continuously formed in an area within 50 μm from a surface in a thickness direction,
wherein the Cr concentration section includes a high Cr concentration section in which Cr is concentrated in a relatively high concentration and a low Cr concentration section in which Cr is concentrated in a relatively low concentration, and
wherein the high Cr concentration section is distributed in a fraction of 30 area % or less (excluding 0%) relative to an entire surface area of the Cr concentration section.
2. The steel material of claim 1 , further comprising:
by weight %, one or more elements selected from among 1% or less of Cu (excluding 0%) and 0.0005-0.01% of B.
3. The steel material of claim 1 ,
wherein the high Cr concentration section refers to an area including Cr by more than 1.5 times the Cr content of the steel material, and
wherein the low Cr concentration section refers to an area including Cr by more than 1 time and 1.5 times or less the Cr content of the steel material.
4. The steel material of claim 1 , wherein the high Cr concentration section is distributed in a fraction of 10 area % or less relative to an entire surface area of the Cr concentration section.
5. The steel material of claim 1 , wherein a grain size of austenite is 5-150 μm.
6. The steel material of claim 1 ,
wherein yield strength of the steel material is 400 MPa or more,
wherein tensile strength of the steel material is 800 MPa or more, and
wherein elongation of the steel material is 40% or more.
7. The steel material of claim 1 , wherein the steel material has a Charpy impact toughness of 90J or more (based on a 10 mm sample thickness) at −196° C., and corrosion loss of 80 mg/cm 2 or less in a corrosion resistance test according to ISO9223.
8. The steel material of claim 1 , comprising by weight %, 3-3.8% of Cr.
9. The steel material of claim 1 , comprising by weight %, 0.001-0.01% of B.
10. The steel material of claim 1 , comprising by weight %, 0.002-0.01% of B.
11. A method of manufacturing a cryogenic austenitic high-manganese steel material having excellent corrosion resistance, the method comprising:
reheating a slab including, by weight %, 0.2-0.5% of C, 23-28% of Mn, 0.05-0.5% of Si, 0.03% or less of P, 0.005% or less of S, 0.5% or less of Al, 3-4% of Cr, and a balance of Fe and inevitable impurities, in a temperature range of 1050-1300° C.;
hot-rolling the reheated slab at a finishing rolling temperature of 900-950° C., thereby providing an intermediate material; and
cooling the intermediate material to a temperature range of 600° C. or less at a cooling rate of 1-100° C./s, thereby providing a final material.
12. The method of claim 11 , wherein the slab further includes, by weight %, one or more elements selected from among 1% or less of Cu (excluding 0%) and 0.0005-0.01% of B.
13. The steel material of claim 1 , comprising by weight %, 0.002-0.008% of B.