Polypropylene random copolymer composition for cold and hot water pipe applications
Polypropylene polymer compositions are disclosed that can be used to produce different types of molded articles, such as extruded piping structures. The polypropylene polymer composition contains a polypropylene random copolymer in combination with a property enhancing agent. The property enhancing agent is incorporated into the polymer composition so that the composition has relatively high impact resistance properties in combination with a relatively high flexural modulus.
1. A polypropylene polymer composition comprising:
(a) a polypropylene random copolymer comprising;
propylene from about 99 wt % to about 95 wt % based on the total weight of the polypropylene random copolymer;
an ethylene content (ET) of from about 1 wt % to about 5 wt % based on the total weight of the polypropylene random copolymer; and
a melt flow rate of greater than about 0.01 g/10 min to about 2 g/10 min; and
(b) a property enhancing agent, the property enhancing agent being present in the composition in an amount sufficient to increase an impact resistance or a flexural modulus of the composition and wherein the composition has an IZOD notched impact strength resistance at 23° C. of from about 400 J/m to about 900 J/m and has a flexural modulus of from about 650 MPa to about 1200 MPa; and
wherein the propylene random copolymer is monomodal; and
wherein the composition has a xylene soluble fraction (XS) of from about 2% to about 14% based on the total weight of the polypropylene polymer composition.
2. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent comprises a phosphate ester salt, sodium benzoate, a dibenzyl sorbitol, a metal salt of a carboxylic acid or mixtures thereof.
3. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent comprises sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl) phosphate, a dibenzylidene sorbitol, 4-cyclohexone-1,2-dicarboxylic acid or mixtures thereof.
4. The polypropylene polymer composition of claim 2 , wherein the polymer composition has a melt flow rate of from about 0.01 g/10 min to less than about 0.5 g/10 min, an ethylene content of from about 3.3% to about 4.5% by weight, and an IZOD notched impact strength resistance at 23° C. of greater than about 500 J/m to about 900 J/m.
5. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent comprises N,N′-dicyclohexylnaphthalene-2,6-dicarboxamide, a metal salt of 6-quinaziran sulfonic acid, a disodium salt of o-phthalic acid, an isophthalic acid, a terephthalic acid, or a combination of an organic dibasic acid and an oxide, a hydroxide, or an acid of a Group II metal.
6. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent comprises a combination of pimelic acid and calcium stearate.
7. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent comprises N,N′-dicyclohexylnaphthalene-2,6-dicarboxamide.
8. The polypropylene polymer composition of claim 5 , wherein the polymer composition has a melt flow rate of from about 0.15 g/10 min to about 2 g/10 min, has an ethylene content of from about 1% to about 3.5% by weight, has a flexural modulus of greater than about 800 MPa to about 1200 MPa, and has an IZOD impact strength resistance at 23° C. of greater than about 600 J/m to about 900 J/m.
9. The polypropylene polymer composition of claim 1 , wherein the property enhancing agent is present in the polymer composition in an amount from about 100 ppm to about 5000 ppm.
10. The polypropylene polymer composition of claim 1 , wherein the polypropylene random copolymer is present in the polymer composition in an amount greater than about 70% by weight.
11. The polypropylene polymer composition of claim 1 , wherein the polypropylene random copolymer has been Ziegler-Natta catalyzed.
12. The polypropylene polymer composition of claim 11 , wherein the polypropylene random copolymer has been catalyzed in the presence of an internal electron donor comprising a non-phthalate, substituted phenylene aromatic diester.
13. The polypropylene polymer composition of claim 1 , wherein the composition includes a second property enhancing agent, the second property enhancing agent comprising a metal stearate, a hydrotalcite, or talc.
14. A piping structure having a length and defining a first opening at one end and a second opening at an opposite end, the piping structure defining a hollow passageway therebetween, the piping structure being formed from the polypropylene polymer composition of claim 1 .
15. The piping structure of claim 13 , wherein the piping structure has been formed through extrusion.
16. A piping structure comprising;
a tubular member having a length and defining a hollow interior passageway, the tubular member including a wall defining the interior passageway, the wall being made from a polypropylene polymer composition comprising;
(a) a polypropylene random copolymer comprising;
propylene from about 99 wt % to about 95 wt % based on the total weight of the polypropylene random copolymer;
an ethylene content (ET) of from about 1 wt % to about 5 wt % based on the total weight of the polypropylene random copolymer; and a melt flow rate of greater than about 0.01 g/10 min to about 2 g/10 min; and
(b) a property enhancing agent, the property enhancing agent being present in the composition in an amount sufficient to increase an impact resistance or a flexural modulus of the composition and wherein the composition has an IZOD notched impact strength resistance at 230 C of from about 400 J/m to about 900 J/m and has a flexural modulus of from about 650 MPa to about 1200 MPa;
wherein the propylene random copolymer is monomodal; and
wherein the composition has a xylene soluble fraction (XS) of from about 2% to about 14% based on the total weight of the polypropylene polymer composition.
17. The piping structure of claim 16 , wherein the property enhancing agent comprises a phosphate ester salt, sodium benzoate, a dibenzyl sorbitol, or mixtures thereof and wherein the polymer composition has a melt flow rate of from about 0.01 g/10 min to less than about 0.5 g/10 min, an ethylene content of from about 3.3% to about 5% by weight, and an IZOD notched impact strength resistance at 23° C. of greater than about 500 J/m to about 900 J/m.
18. The piping structure of claim 16 , wherein the property enhancing agent comprises N,N′-dicyclohexylnaphthalene-2,6-dicarboxamide, a metal salt of 6-quinaziran sulfonic acid, a disodium salt of o-phthalic acid, an isophthalic acid, a terephthalic acid, or a combination of an organic dibasic acid and an oxide, a hydroxide, a metal salt of a 4-cyclohexene-1,2-dicarboxylic acid, or an acid of a Group II metal, and wherein the polymer composition has a melt flow rate of from about 0.15 g/10 min to about 2 g/10 min, has an ethylene content of from about 1% to about 3% by weight, has a flexural modulus of greater than about 800 MPa to about 1200 MPa, and has an IZOD impact strength resistance at 23° C. of greater than about 600 J/m to about 900 J/m.
19. A polypropylene polymer composition comprising:
(a) a polypropylene random copolymer comprising;
propylene from about 99 wt % to about 95 wt % based on the total weight of the polypropylene random copolymer;
an ethylene content (ET) of from about 1 wt % to about 5 wt % based on the total weight of the polypropylene random copolymer; and
a melt flow rate of greater than about 0.01 g/10 min to about 2 g/10 min; and
(b) a property enhancing agent comprising sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl) phosphate, a dibenzylidene sorbitol, 4-cyclohexone-1,2-dicarboxylic acid or mixtures thereof, the property enhancing agent being present in the composition in an amount sufficient to increase an impact resistance or a flexural modulus of the composition and wherein the composition has an IZOD notched impact strength resistance at 23º C of from about 400 J/m to about 900 J/m and has a flexural modulus of from about 650 MPa to about 1200 MPa; and
wherein the propylene random copolymer is monomodal.
20. A polypropylene polymer composition comprising:
(a) a polypropylene random copolymer comprising;
propylene from about 99 wt % to about 95 wt % based on the total weight of the polypropylene random copolymer;
an ethylene content (ET) of from about 1 wt % to about 5 wt % based on the total weight of the polypropylene random copolymer; and
a melt flow rate of greater than about 0.01 g/10 min to about 2 g/10 min; and
(b) a property enhancing agent comprising a combination of pimelic acid and calcium stearate, the property enhancing agent being present in the composition in an amount sufficient to increase an impact resistance or a flexural modulus of the composition and wherein the composition has an IZOD notched impact strength resistance at 23° C. of from about 400 J/m to about 900 J/m and has a flexural modulus of from about 650 MPa to about 1200 MPa; and
wherein the propylene random copolymer is monomodal.