Polyester film and method for reproducing polyester container using same
Embodiments relate to a polyester-based film and a process for regenerating a polyester-based container using the same, which not only solve the environmental problems by enhancing the recyclability of polyester-based containers but also are capable of enhancing the quality, yield, and productivity. When the polyester-based film is cut into a size of 1 cm in width and 1 cm in length, immersed in an aqueous solution of sodium hydroxide (NaOH) having a concentration of 1% by weight, and stirred for 15 minutes at 85° C. at a speed of 240 m/minute, the average particle size of the component of the printing layer separated from the base layer satisfies 15 μm or more. Thus, it is possible to enhance the quality of the regenerated polyester-based chips produced from the polyester-based container provided with the polyester-based film.
1. A polyester-based film, which comprises a base layer comprising a polyester-based resin; and a printing layer disposed on one side of the base layer,
wherein when the film is cut into a size of 1 cm in width and 1 cm in length, immersed in an aqueous solution of sodium hydroxide (NaOH) having a concentration of 1%, and stirred for 15 minutes at 85° C. at a speed of 240 m/minute, the average particle size of the component of the printing layer separated from the base layer is 15 μm or more,
when the flakes obtained by crushing a polyethylene terephthalate (PET) container provided with the polyester-based film are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping ratio is 5% or less.
2. The polyester-based film of claim 1 , wherein the printing layer is formed from a composition for a printing layer that comprises a first solvent, a first binder, and a first pigment, and the weight ratio of the first solvent and the first binder is 1:0.5 to 2.5.
3. The polyester-based film of claim 2 , wherein the first solvent comprises one or more selected from the group consisting of methanol, ethanol, propanol, isopropyl alcohol, butyl alcohol, 2-methyl-2-propanol, octanol, allyl alcohol, benzyl alcohol, ethylene glycol, diethylene glycol, triethylene glycol, tetramethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, hexylene glycol, and neopentyl glycol.
4. The polyester-based film of claim 2 , wherein the composition for a printing layer comprises the first solvent in an amount of 1% by weight to 35% by weight, the first binder in an amount of 25% by weight to 60% by weight, and the first pigment in an amount of 5% by weight to 50% by weight, based on the total weight of the composition for a printing layer.
5. The polyester-based film of claim/6, wherein the polyester-based resin comprises a diol component and a dicarboxylic acid component,
the diol component comprises at least one selected from the group consisting of ethylene glycol, diethylene glycol, and neopentyl glycol, and
the polyester-based resin comprises neopentyl glycol in an amount of 1% by mole to 35% by mole based on the total number of moles of the diol component.
6. The polyester-based film of claim 5 , wherein the polyester-based resin comprises ethylene glycol in an amount of 55% by mole to 90% by mole and diethylene glycol in an amount of 1% by mole to 15% by mole, based on the total number of moles of the diol component, and the molar ratio of ethylene glycol and diethylene glycol is 7.8 to 26:1.
7. The polyester-based film of claim 1 , wherein the thickness of the base layer is 10 μm to 100 μm, and the thickness of the printing layer is 0.1 μm to 100 μm.
8. The polyester-based film of claim 1 , which has a light transmittance of 90% or more at a wavelength of 550 nm,
a change in light transmittance of 0.7% or less before and after the immersion, and
a change (ΔL) in Col-L of 0.7 or less, a change (Δa) in Col-a of 0.5 or less, and a change (Δb) in Col-b of 0.5 or less, before and after the immersion.
9. A process for regenerating a polyester-based container, which comprises:
providing a polyester-based container at least a portion of which is surrounded by the polyester-based film according to claim 1 ;
crushing the polyester-based container provided with the film to obtain flakes;
immersing the crushed flakes in an aqueous solution of sodium hydroxide (NaOH) having a concentration of 1% at 85° C.; and
thermally treating the immersed flakes to produce regenerated polyester-based chips,
wherein when the flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping fraction is 5% or less.
10. Regenerated polyester chips prepared according to the regeneration process of claim 9 .