INCREASING TRANSPARENCY OF NANOFIBER SHEETS
Methods for increasing transparency of a nanofiber sheet to many wavelengths of radiation, including those wavelengths within the visible spectrum, are described. These techniques include straining a nanofiber sheet so as to increase its width.
1 . A method comprising:
drawing a first nanofiber sheet from a nanofiber forest, the first nanofiber sheet having a fixed end integral with the nanofiber forest and a free end opposite the fixed end, wherein a plurality of nanofibers of the first nanofiber sheet are aligned with a drawing direction of the first nanofiber sheet; attaching a strain element to the free end;
applying strain to the free end by elongating the strain element in a direction not parallel to the alignment of the nanofibers;
attaching the strained free end of the nanofiber sheet to a support, the support maintaining the applied strain in the first nanofiber sheet;
removing the first nanofiber sheet from the nanofiber forest; and
stacking a second nanofiber sheet on the first nanofiber sheet.
2 . The method of claim 1 , further comprising:
drawing the second nanofiber sheet from the nanofiber forest, the second nanofiber sheet having a second fixed end integral with the nanofiber forest and a second free end opposite the second fixed end, wherein a plurality of nanofibers of the second nanofiber sheet are aligned with the drawing direction of the second nanofiber sheet;
attaching the strain element to the second free end;
applying strain to the second free end by elongating the strain element in a second direction not parallel to the orientation of the nanofibers;
attaching the second strained, free end of the second nanofiber sheet to a second support, the second support maintaining the applied strain in the second nanofiber sheet; and
removing the second nanofiber sheet from the nanofiber forest.
3 . The method of claim 1 , further comprising forming a plurality of gaps in one or both of the first nanofiber sheet and the second nanofiber sheet in response to applying the strain.
4 . The method of claim 3 ,
wherein an average gap size of the gaps is from 8 microns on a side to 45 microns on a side, and
wherein:
applying the strain to the first nanofiber sheet and the second nanofiber sheet comprises straining each sheet by a factor of 3; and
a transparency of the stacked first nanofiber sheet and the second nanofiber sheet to radiation in the visible spectrum is 90%.
5 . (canceled)
6 . The method of claim 2 , wherein a transparency of the stack of the first nanofiber sheet and the second nanofiber sheet to radiation having a wavelength of 550 nm is from 72% to 88%.
7 . The method of claim 2 , wherein the first nanofiber sheet and the second nanofiber sheet are stacked relative to have their corresponding nanofiber alignment directions not parallel to one another.
8 . The method of claim 1 , wherein an angle between nanofiber alignment directions of the first nanofiber sheet and the second nanofiber sheet are from 45° to 135°, excluding 0°.
9 . The method of claim 1 ,
wherein the second nanofiber sheet is in an as-drawn state, and
wherein the method further comprises densifying the second nanofiber sheet by exposing the second nanofiber sheet to a solvent and removing the solvent before the stacking.
10 . (canceled)
11 . A method comprising:
drawing a nanofiber sheet from a nanofiber forest, the nanofiber sheet having a fixed end integral with the nanofiber forest and a free end opposite the fixed end, wherein a plurality of nanofibers of the nanofiber sheet are aligned in a direction parallel to a drawing direction of the nanofiber sheet;
attaching a strain element to the free end;
applying strain to the free end by elongating the strain element in a direction not parallel to the alignment of the nanofibers; and
attaching the strained, free end of the nanofiber sheet to a support, the support maintaining the applied strain in the nanofiber sheet.
12 . The method of claim 11 , further comprising removing the strain element from the strained free end.
13 . The method of claim 11 , further comprising applying the method of claim 11 to the fixed end of the nanofiber sheet.
14 . The method of claim 13 , further comprising severing the fixed end from the nanofiber forest after applying the strain to the fixed end.
15 . The method of claim 11 , wherein the strain is applied in a direction from 45° to 135° relative to the direction of alignment of the nanofibers within the nanofiber sheet.
16 . The method of claim 11 , wherein the nanofiber sheet has a first width prior to straining and a second width after straining, the second width greater than the first width.
17 . The method of claim 16 , wherein the second width is from 2.5 times to 3 times the first width.
18 . The method of claim 16 , wherein a transparency to radiation having a wavelength of 550 nm is at least 80%.
19 . A transparent nanofiber sheet produced by a method comprising:
drawing a nanofiber sheet from a nanofiber forest in a drawing direction, the nanofiber sheet having a fixed end integral with the nanofiber forest and a free end opposite of the fixed end, wherein a plurality of nanofibers of the nanofiber sheet is aligned in an alignment direction that is parallel with the drawing direction;
attaching a strain element to the free end;
elongating the strain element in a direction different from the alignment direction, such that a width of the free end is increased to be larger than a width of the fixed end;
attaching the elongated free end to an inelastic support; and
removing the nanofiber sheet from the nanofiber forest.
20 . The transparent nanofiber sheet produced by the method of claim 19 , wherein the width of the free end is 2.5 times to 3 times wider than the width of the fixed end.
21 . The transparent nanofiber sheet produced by the method of claim 19 , wherein the width of the free end is 1.5 times to 2 times wider than the width of the fixed end.
22 . The transparent nanofiber sheet produced by the method of claim 19 , wherein the width of the free end is 1.1 times to 2.5 times wider than the width of the fixed end.
23 . The transparent nanofiber sheet produced by the method of claim 19 , wherein a transparency in a visible radiation spectrum of the free end of the nanofiber sheet is 10% to 15% greater than the fixed end of the nanofiber sheet.
24 . The transparent nanofiber sheet produced by the method of claim 19 , wherein the plurality of nanofibers includes multi-walled nanofibers.
25 . The transparent nanofiber sheet produced by the method of claim 19 ,
wherein the produced transparent nanofiber sheet includes:
a first end having a first width;
a second end having a second width that is greater than the first width; and
the inelastic support attached to the second end, the inelastic support configured to maintain a strain applied to the second end, wherein the strain is applied in a strain direction different from the alignment direction of the plurality of nanofibers forming the nanofiber sheet,
wherein a transparency in a visible radiation spectrum of the second end of the nanofiber sheet is greater than the first end of the nanofiber sheet.