Methods for improving nanocellulose dispersion in elastomeric compounds, and compositions containing dispersed nanocellulose in elastomer compounds

Inventors: Charles R. Herd (Woodstock, GA); Zachary A. Combs (Smyrna, GA); Lewis B. Tunnicliffe (Woodstock, GA); Kimberly Nelson (Atlanta, GA); Shaobo Pan (Atlanta, GA)

Assignee: GranBio Intellectual Property Holdings, LLC

C08L9/06 B60C1/0016 C08K3/04 C08K5/01 C08K7/02 C08K9/04 C08L1/02 C08L7/00 C08L91/06 B60C1/00 C08K2201/006 C08K2201/011 C08L2201/50 C08L2201/52 C08L2205/035 C08L2205/16 C08L2205/22 C08L2207/322

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Quick Facts

Patent No.: US 12,134,698
App. No.: 17/286,544
Granted: Nov 5, 2024
Kind: B2

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Abstract

Nanocellulose dispersion compositions containing a partitioning agent and a nanocellulose, and methods of making the nanocellulose dispersion compositions, are disclosed. These compositions can promote improved dispersibility of the nanocellulose fibrils and nanocellulose crystals in polymer matrices, such as in elastomer formulations for use in tire production.

Claims (25)

1. A nanocellulose dispersion composition (NDC) comprising:

(i) a partitioning agent comprising an elastomer latex, a wax, or a combination thereof; and

(ii) a hydrophobic nanocellulose;

wherein the nanocellulose dispersion composition (NDC) does not comprise a carbon black material.

2. The composition of claim 1 , wherein the partitioning agent is compatible with a polymer and reduces nanocellulose agglomeration.

3. The composition of claim 1 , wherein the nanocellulose dispersion composition has greater nanocellulose dispersibility in a polymer formulation than that of the nanocellulose without the partitioning agent.

4. The composition of claim 1 , wherein the hydrophobic nanocellulose comprises nanocellulose crystals (NC), nanocellulose fibrils (NF), or a combination thereof.

5. The composition of claim 1 , wherein the hydrophobic nanocellulose comprises lignin-coated nanocellulose crystals (LCNC), lignin-coated nanocellulose fibrils (LCNF), or a combination thereof.

6. The composition of claim 1 , wherein the nanocellulose dispersion composition (NDC) further comprises a hydrocarbon oil.

7. The composition of claim 6 , wherein the hydrocarbon oil comprises an aliphatic hydrocarbon, an aromatic hydrocarbon, or a combination thereof.

8. The composition of claim 6 , wherein the hydrocarbon oil comprises a treated distillate aromatic extract (TDAE) oil.

9. The composition of claim 1 , wherein the elastomer latex comprises a natural rubber (NR), an isoprene rubber (IR), an emulsion styrene-butadiene rubber (ESBR), or any combination thereof.

10. The composition of claim 1 , wherein the wax comprises a non-branched alkane paraffin wax; a natural mineral, petroleum refined, or lignin refined branched paraffin wax or ceresine wax; a polyethylene wax; a functionalized polyethylene wax; or any combination thereof.

11. The composition of claim 1 , wherein the partitioning agent comprises the elastomer latex and the wax.

12. The composition of claim 1 , wherein a weight ratio of the partitioning agent to the hydrophobic nanocellulose is in a range from about 0.5:1 to about 25:1.

13. The composition of claim 1 , wherein a weight ratio of the partitioning agent to the hydrophobic nanocellulose is in a range from about 1:1 to about 10:1.

14. A polymer composition comprising:

(I) a polymer; and

(II) the nanocellulose dispersion composition (NDC) of claim 1 ,

wherein the polymer composition does not comprise a carbon black material.

15. The polymer composition of claim 14 , wherein a weight ratio of the polymer to the nanocellulose dispersion composition (polymer:NDC) is in a range from about 100:1 to about 1:1.

16. The polymer composition of claim 14 , wherein a weight ratio of the polymer to the nanocellulose dispersion composition (polymer:NDC) is in a range from about 50:1 to about 2:1.

17. The polymer composition of claim 14 , wherein the polymer comprises a thermoplastic.

18. The polymer composition of claim 14 , wherein the polymer comprises an elastomer.

19. The polymer composition of claim 14 , wherein the polymer comprises a natural rubber (NR), an epoxidized natural rubber (ENR), a synthetic cis-polyisoprene (IR), an emulsion styrene butadiene rubber (eSBR), a solution styrene butadiene rubber (sSBR), a polybutadiene rubber (BR), a butyl rubber (IIR/CIIR/BIIR), a chloroprene rubber (CR), a nitrile elastomer (NBR), a hydrogenated nitrile elastomer (HNBR), a carboxylated nitrile elastomer (XNBR), an ethylene propylene rubber (EPM/EPDM), a fluoroelastomer (FPM/FKM), a polyurethane rubber (AU/EU/PU), or any combination thereof.