Granted Patent B2

US 12,399,256 · App. 17/287,716 · Granted Aug 26, 2025

Inventors: Ulrich Grosser (Kürten, DE); Alexander Meyer (Düsseldorf, DE); Thomas Pfingst (Tönisvorst, DE); Peter Capellen (Krefeld, DE); Rafael Oser (Krefeld, DE); Rainer Hagen (Leverkusen, DE); Tobias Sadler (Monheim Am Rhein, DE); Vincenzo Taravella (Curno, IT); Andrea Crotti (Curno, IT); Stefania Scotuzzi (Brembate di Sopra, IT)

Assignee: Covestro Deutschland AG

G01S7/4813C08J7/042C08J7/0427C08J7/043C08K5/0091C08K5/18C08K5/3417C08K5/3465H04N23/52C08J2369/00C08J2483/04

Abstract

Claims (42)

1. A sensor system comprising

a LiDAR unit having a transmitter for laser light having a wavelength of 800 nm to 1600 nm and a receiver for light having a wavelength of 800 nm to 1600 nm;

a camera for visible light having a wavelength of 380 nm to 780 nm and

a cover arranged such that IR light transmitted by the LiDAR unit and received thereby and visible light received by the camera passes through the cover, wherein the cover comprises a layer containing dyes,

wherein

the cover has a light transmission Ty in the range from 380 to 780 nm of >3% to <25% determined according to DIN ISO 13468-2:2006 (D65, 10°),

the cover has a transmission for light in the range of 380 nm to 1100 nm of >40% determined according to DIN ISO 13468-2:2006 (D65, 10°),

the cover attenuates the LiDAR signal only to the extent that the signal intensity of the IR light transmitted by the LiDAR unit and re-received thereby (determined by reflection from a smooth surface painted with TiO 2 -containing white paint at a distance of 3.2 m) is >65% of a reference intensity determined without the cover and in that

the layer containing dyes comprises a thermoplastic composition comprising the following components:

i) at least 70 wt % based on the total weight of the composition of a transparent thermoplastic polymer;

ii) at least one green and/or blue colourant;

iii) at least one red and/or violet colourant;

wherein the product of the sum of the weight percent fractions (based on the total weight of the composition) of the colourants ii) and iii) and the thickness of the layer containing dyes is >0.041 wt % mm to <0.12 wt % mm

and wherein the composition contains 0 to <0.0005 wt % based on the total weight of the composition of infrared absorbers.

2. The system as claimed in claim 1 , wherein the component ii) is selected from the group consisting of the formulae (1), (2a-c), (3), (4a), (4b), (5a), (5b), (6), (7), (8), and mixtures thereof and the component iii) is selected from the group consisting of the formulae (9), (10), (11), (12), (13), (14a), (14b), (15), and mixtures thereof:

wherein

Rc and Rd independently of one another represent a linear or branched alkyl radical or halogen, n independently of the respective Rc, Rd, Ra and Rb represents a natural number between 0 and 3

where the radicals R(5-20) independently of one another are selected from the group consisting of hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, thexyl, fluoro, chloro, bromo, sulfone, CN, and M is selected from the group consisting of aluminum, nickel, cobalt, iron, zinc, copper, and manganese,

wherein

R1 and R2 independently of one another represent a linear or branched alkyl radical or halogen,

n is a natural number between 0 and 4,

wherein R is selected from the group consisting of H and p-methylphenylamine radical,

wherein

Ra and Rb independently of one another represent a linear or branched alkyl radical or halogen, n independently of the respective Ra and Rb represents a natural number between 0 and 3,

3. The system as claimed in claim 2 , wherein the thermoplastic composition of the layer containing dyes comprises the following components:

at least 99 wt % based on the total weight of the composition of aromatic polycarbonate having a melt volume rate MVR of 15 to 20 cm 3 /(10 min) determined according to ISO 1133-1:2012-03 (300° C., 1.2 kg);

colourants of formula (2a), (2b) and/or (2c);

colourants of formula (5b) where M=Cu and R(5-20)=H;

colourants of formula (10);

wherein the sum of the colourants employed in total is ≥0.017 wt % to ≤0.057 wt % based on the total weight of the composition.

4. The system as claimed in claim 1 , wherein the thermoplastic composition of the layer containing dyes comprises a yellow and/or orange-coloured dye of formulae (16), (17), (18), (19), (20) or a mixture of at least two thereof:

5. The system as claimed in claim 1 , wherein the cover further comprises a layer of an aromatic polycarbonate which does not contain green, blue, red and/or violet colourants.

6. A vehicle comprising a system as claimed in claim 1 .

7. The system as claimed in claim 6 , wherein the topcoat layer contains an organomodified silane or a reaction product thereof.

8. The system as claimed in claim 6 , wherein an adhesion promoter layer is present between the topcoat layer and the layer containing dyes.

9. The system as claimed in claim 6 , wherein the topcoat used in the topcoat layer is a UV-curable topcoat.

10. The system as claimed in claim 6 , wherein a further layer is present on the side of the layer containing dyes that is opposite the topcoat layer.

11. The system as claimed in claim 10 , wherein the further layer is an antireflection layer, an anti-condensation layer, an anti-dust layer, a media resistance layer or a scratch resistance layer or a combination thereof.

12. The system as claimed in claim 1 , wherein in the cover the layer containing dyes has a thickness of >0.15 mm to <5 mm.

13. The system as claimed in claim 1 , wherein the cover comprises a plurality of layers containing dyes which may be identical or different.

14. The system as claimed in claim 1 , wherein the cover further comprises a layer of an aromatic polycarbonate which does not contain green, blue, red and/or violet colourants.

15. A vehicle comprising a system as claimed in claim 1 .

Assignments (2)

Priority Claims (1)

Continuity (1)

References Cited (16)