Polyolefin composition with improved balance of properties
The present invention is directed to a polyolefin composition comprising a blend of a heterophasic polypropylene composition and 5.0 to 30.0 wt % of an ethylene homo- or copolymer, the ethylene homo- or copolymer having a density of at least 941 kg/m 3 and a melt flow rate MFR 21 of 1 to 10 g/10 min. The heterophasic polypropylene composition comprises a propylene homopolymer or a propylene ethylene random copolymer and an elastomeric ethylene propylene rubber, and is characterized by 75.0 to 95.0 wt % of a crystalline fraction having an ethylene content of up to 4.0 wt % and an MFR 2 of 0.1 to 100 g/10 min, and 5.0 to 25.0 wt % of a soluble fraction having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/kg, wherein the crystalline fraction and the soluble fraction are determined in 1,2,4-trichlorobenzene at 40° C.
1. A polyolefin composition comprising a blend of:
(A) a heterophasic polypropylene composition comprising:
a propylene homopolymer or a propylene ethylene random copolymer and
an elastomeric ethylene propylene rubber, and
(B) 5.0 to 30.0 wt % of an ethylene homo- or copolymer, based on a weight of the polyolefin composition;
wherein the heterophasic polypropylene composition is comprises:
(a1) 75.0 to 95.0 wt % of a crystalline fraction (CF) having an ethylene content of up to 4.0 wt % and a MFR 2 of 0.1 to 100 g/10 min, wherein MFR 2 is determined according to ISO 1133 at 230° C. under a load of 2.16 kg and,
(a2) 5.0 to 25.0 wt % of a soluble fraction (SF) having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/g,
wherein the crystalline fraction (CF) and the soluble fraction (SF) are determined in 1,2,4-trichlorobenzene at 40° C., and
wherein the ethylene homo- or copolymer has a density of at least 941 kg/m 3 and a melt flow rate MFR 21 of 1.0 to 7.5 g/10 min, wherein MFR 21 is determined according to ISO 1133 at 190° C. under a load of 21.6 kg.
2. The polyolefin composition according to claim 1 , wherein the ethylene homo- or copolymer has a density of at least 950 kg/m 3 .
3. The polyolefin composition according to claim 1 , wherein the ethylene homo- or copolymer is an ethylene copolymer and comprises a copolymer of ethylene and a C 4 to C 12 α-olefin.
4. The polyolefin composition according to claim 3 , wherein the ethylene copolymer comprises a copolymer of ethylene and a comonomer selected from the group consisting of 1-butene, 1-hexene, 1-octene, and mixtures thereof.
5. The polyolefin composition according to claim 3 , wherein the ethylene copolymer comprises one homopolymer fraction and one copolymer fraction that comprises 1-hexene as comonomer.
6. The polyolefin composition according to claim 1 , wherein the ethylene homo- or copolymer has a weight average molecular weight M W of at least 250,000 g/mol.
7. The polyolefin composition according to claim 1 , wherein the ethylene homo- or copolymer has a complex viscosity at a frequency of 0.05 rad/s eta 0.05 of 750 kPa·s to 1900 kPa·s.
8. The polyolefin composition according to claim 1 , wherein the propylene homopolymer or propylene ethylene random copolymer and the elastomeric ethylene propylene rubber have been produced in the presence of a single-site catalyst (SSC).
9. The polyolefin composition according to claim 1 , wherein the heterophasic polypropylene composition comprises 5.0 to 15.0 wt % of the soluble fraction (SF).
10. The polyolefin composition according to claim 1 , wherein the soluble fraction (SF) has an ethylene content of 10.0 to 30.0 wt %.
11. The polyolefin composition according to claim 1 , wherein the soluble fraction (SF) has an intrinsic viscosity of 2.0 to 4.0 dl/g.
12. The polyolefin composition according to claim 1 , wherein the heterophasic polypropylene composition comprises:
(a3) 75.0 to 95.0 wt % of a xylene cold insoluble fraction (XCI) having an ethylene content of up to 4.0 wt % and an MFR2 of 0.1 to 100 g/10 min and,
(a4) 5.0 to 25.0 wt % of a xylene cold soluble fraction (XCS) having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/g.
13. The polyolefin composition according to claim 12 , wherein the xylene cold soluble fraction (XCS) has an intrinsic viscosity of 2.0 to 4.0 dl/g.
14. A molded article comprising the polyolefin composition according to claim 1 .
15. The molded article according to claim 14 , which is an injection molded article.