IP Library Granted Patent US 11,879,166
Granted Patent B2
US 11,879,166 · App. 17/292,901 · Granted Jan 23, 2024

7XXX-series aluminium alloy product

Inventors: Achim Bürger (Höhr-Grenzhausen, DE); Philippe Meyer (Koblenz, DE); Sunil Khosla (Bramcote, GB); Sabine Maria Spangel (Koblenz, DE); Christian Gerhard Krechel (Koblenz, DE)
Assignee: Novelis Koblenz GmbH
C22C21/10C22F1/053
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Quick Facts
Patent No.
US 11,879,166
App. No.
17/292,901
Granted
Jan 23, 2024
Kind
B2
Abstract

The invention relates to a wrought 7xxx-series aluminium alloy product having a composition comprising, in wt. %., Zn 6.20 to 7.50, Mg 2.15 to 2.75, Cu 1.20 to 2.00, and wherein Cu+Mg<4.50, and wherein Mg<2.5+5/3(Cu-1.2), Fe up to 0.25, Si up to 0.25, and optionally one or more elements selected from the group consisting of: (Zrup to 0.3,Crup to 0.3,Mnup to 0.45,Tiup to 0.25, Scup to 0.5, Agup to 0.5), the balance being aluminium and impurities.

Claims (37)

1. A wrought 7xxx-series aluminium alloy product having a composition comprising, in wt. %,

Zn 6.40 to 6.60,

Mg 2.25 to 2.60,

Cu 1.50 to 1.80,

and wherein Cu+Mg<4.50, and wherein Mg<2.5+5/3(Cu−1.2),

Fe up to 0.05,

Si up to 0.05, and

optionally one or more elements selected from the group consisting of:

Zr up to 0.3,

Cr up to 0.3,

Ti up to 0.05,

Sc up to 0.05,

Ag up to 0.05,

a balance being aluminium and impurities, wherein the composition is free from Mn, wherein said wrought 7xxx-series aluminium alloy product is aged to achieve:

a minimum life without failure due to stress corrosion cracking (SCC) measured in accordance with ASTM G47-98 of at least 30 days, at a short transverse (ST) stress level of 170 MPa; and

a minimum life without failure due to environmental assisted cracking (EAC) in a sodium chloride free humid atmosphere and measured with constant load testing configurations in accordance with ASTM G47-98 on round ST tension specimens of at least 50 days at a short transverse (ST) constant load stress level of 85% Yield Strength (YS), and with a continuous exposure to a temperature of 70° C., and at a humidity of 85% (RH).

2. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the Mg-content is at least 2.30 wt. %.

3. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the Zn-content is at least 6.50 wt. %.

4. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein

in wt. %, Cu+Mg<4.45, and wherein, in wt. %, Mg<2.55+2(Cu−1.25).

5. The wrought 7xxx-series aluminium alloy product according to claim 1 , further comprising up to 0.3 wt. % of one or more of V, Ni, Co, Nb, Mo, Ge, Er, Hf, Ce, Y, Dy, Sr.

6. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product has a Zr-content in a range of 0.03 wt. % to 0.25 wt. %.

7. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product has a Cr-content in a range of 0.04 wt. % to 0.3 wt. %.

8. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product has a Cr-content of up to 0.05 wt. %.

9. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product has a thickness of at least 12.7 mm.

10. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is an aerospace product.

11. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is in a T7 condition.

12. The wrought 7xxx-series aluminium alloy product according to claim 11 , wherein said wrought 7xxx-series aluminium alloy product is in the T7 condition selected from the group consisting of T73, T74, T76, T77, and T79.

13. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product has a thickness of at least 25.4 mm.

14. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is in the form of a rolled, extruded or forged product.

15. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is aged to achieve:

a conventional tensile yield strength (in MPa) measured in the L-direction measured at quarter thickness of more than 470-0.12*(t-100)MPa (t being a thickness of said wrought 7xxx-series aluminium alloy product in mm).

16. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is aged to achieve:

a conventional tensile yield strength (in MPa) measured in the L-direction measured at quarter thickness of more than 485-0.12*(t-100)MPa (t being a thickness of said wrought 7xxx-series aluminium alloy product in mm);

a minimum life without failure due to stress corrosion cracking (SCC) measured in accordance with ASTM G47-98 of at least 30 days, at a short transverse (ST) stress level of 205 MPa; and

the minimum life without failure due to environmental assisted cracking (EAC) in the sodium chloride free humid atmosphere and measured with constant load testing configurations in accordance with ASTM G47-98 on round ST tension specimens of at least 140 days at the short transverse (ST) constant load stress level of 85% Yield Strength (YS), and with the continuous exposure to the temperature of 70° C., and at the humidity of 85% (RH).

17. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said wrought 7xxx-series aluminium alloy product is an aircraft structural part.

Assignments (6)
RELEASE OF SECURITY INTEREST AT REEL/FRAME 58711/0922 Recorded Mar 13, 2025
From: STANDARD CHARTERED BANK
To: NOVELIS INC.; NOVELIS KOBLENZ GMBH
Reel/Frame 070502/0231 →
SECURITY INTEREST Recorded Mar 11, 2025
From: NOVELIS DEUTSCHLAND GMBH; NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: CITIBANK, N.A.
Reel/Frame 070481/0417 →
CHANGE OF NAME Recorded Aug 10, 2022
From: ALERIS ROLLED PRODUCTS GERMANY GMBH
To: NOVELIS KOBLENZ GMBH
Reel/Frame 061419/0936 →
SECURITY INTEREST Recorded Jan 20, 2022
From: NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: STANDARD CHARTERED BANK
Reel/Frame 058711/0922 →
SECURITY INTEREST Recorded Jan 20, 2022
From: NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 058711/0952 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 22, 2021
From: BÜRGER, ACHIM; MEYER, PHILIPPE; KHOSLA, SUNIL; SPANGEL, SABINE MARIA; KRECHEL, CHRISTIAN GERHARD
To: ALERIS ROLLED PRODUCTS GERMANY GMBH
Reel/Frame 056616/0029 →