Polyester film, preparation method thereof and method for reproducing polyethyleneterephthalate container using same
Embodiments relate to a polyester film, preparation method thereof and method for reproducing polyethyleneterephthalate (PET) container using same, the crystallization temperature (Tc) of the polyester film is not measured or is 70° C. to 130° C., as measured by differential scanning calorimetry, whereby it is possible to easily control the crystallinity. Accordingly, the polyester film has excellent shrinkage characteristics and recyclability, and clumping rarely occurs even if it is dried at high temperatures for a long period of time in the regeneration process.
1. A polyester film, which comprises a copolymerized polyester resin in which a diol and a dicarboxylic acid are copolymerized,
wherein the crystallization temperature (Tc) of the film is not measured or is 70° C. to 130° C. by differential scanning calorimetry,
when the flakes obtained by crushing a polyethylene terephthalate (PET) container provided with the polyester film are thermally treated at a temperature of 210° C. for 90 minutes, the clumping ratio is 10% or less, and
the diol comprises neopentyl glycol in an amount of 5% by mole to 35% by mole based on the total number of moles of the diol.
2. The polyester film of claim 1 , wherein the crystallization temperature (Tc) is 96° C. to 120° C. and the melting point (Tm) is 170° C. or higher as measured by differential scanning calorimetry.
3. The polyester film of claim 1 , wherein the clumping ratio is 5% or less.
4. The polyester film of claim 1 , wherein the heat of crystallization at the crystallization temperature (Tc) is 0.01 J/g to 50 J/g.
5. The polyester film of claim 1 , which has a heat shrinkage rate of 30% or more in a first direction upon thermal treatment at a temperature of 80° C. for 10 seconds.
6. The polyester film of claim 1 , wherein the diol comprises ethylene glycol and at least one comonomer selected from the group consisting of neopentyl glycol and diethylene glycol in an amount of 15% by mole or more.
7. The polyester film of claim 6 , wherein the diol further comprises diethylene glycol in an amount of 1% by mole to 10% by mole.