SiCoPC blend containing phosphazene and silicone/acrylate impact modifier
View Patent ↗The invention relates to a composition for production of a thermoplastic moulding compound, wherein the composition comprises or consists of the following constituents: A) 42% to 80% by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate, B) 2% to 38% by weight of at least one polysiloxane-polycarbonate block co-condensate, C) 1% to 15% by weight of at least one rubber-modified graft polymer comprising C.1) 5% to 95% by weight based on the graft polymer C of a shell composed of at least one vinyl monomer and C.2) 95% to 5% by weight based on the graft polymer C of a graft substrate composed of silicone-acrylate composite rubber, D) 2% to 10% by weight of at least one phosphazene, E) 0% to 10% by weight of at least one additive, to the moulding compound itself, to the use of the composition or moulding compound for production of moulded articles and to the moulded articles themselves.
1. Composition for producing a thermoplastic moulding compound, wherein the composition contains:
A) 42% to 80% by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate,
B) 2% to 38% by weight of at least one polysiloxane-polycarbonate block co-condensate characterized in that component B contains siloxane blocks derived from one of the following structures:
wherein R1 represents hydrogen, Cl, Br, C1-C4-alkyl,
R2 independently represents aryl or alkyl,
X represents a single bond, C1 to C5-alkylene, C2 to C5-alkylidene, C5 to C12-cycloalkylidene, —O—, —SO— —CO—, —S—, or —SO2—,
n is a number between 10 and 150 determined by 1H-NMR spectroscopy,
m is a number from 1.5 to 5 determined by 1H-NMR spectroscopy,
C) 1% to 15% by weight of at least one rubber-modified graft polymer comprising
C.1) 5% to 95% by weight based on the graft polymer C of a shell composed of at least one vinyl monomer and
C.2) 95% to 5% by weight based on the graft polymer C of a graft substrate composed of silicone-acrylate composite rubber,
D) 2% to 10% by weight of at least one phosphazene,
E) 0% to 10% by weight of at least one additive.
2. Composition according to claim 1 , characterized in that the graft substrate C.2 contains 20% to 80% by weight of silicone rubber and 80% to 20% by weight of polyalkyl (meth)acrylate rubber.
3. Composition according to claim 1 , characterized in that the component B contains a proportion of 2% to 20% by weight of siloxane blocks.
4. Composition according to claim 1 , characterized in that component C.1 is methyl methacrylate.
5. Composition according to claim 1 , characterized in that component E contains talc.
6. Composition according to claim 1 containing:
50% to 70% by weight of component A,
15% to 35% by weight of component B,
5% to 11% by weight of component C,
4% to 8% by weight of component D,
0.2% to 5% by weight of component E.
7. Composition according to claim 1 consisting of components A, B, C, D and E.
8. Moulded article obtained from the composition according to claim 1 .