Batch mixtures containing pre-reacted inorganic particles and methods of manufacture of ceramic bodies therefrom
A batch mixture comprising pre-reacted pseudobrookite particles consisting essentially of aluminum titanate and magnesium dititanate, a reactive alumina source, a reactive titania source, and a reactive silica source. Other batch mixtures and methods of manufacturing honeycomb extrudates and porous honeycomb bodies using the batch mixture are disclosed.
1. A method of making a ceramic body, the method comprising:
mixing together a batch mixture comprising a total amount of inorganic particles comprised of a first quantity of particles and a second quantity of particles, wherein the first quantity of particles comprises constituents capable of producing aluminum titanate via reactive sintering at one or more reactive sintering temperatures, wherein the first quantity of particles comprises a reactive alumina source, a reactive titania source, and a reactive silica source, and wherein the second quantity of particles comprises pre-reacted crystalline particles comprising aluminum titanate in an amount from 70 wt % to 99 wt % and magnesium dititanate in an amount from 1 wt % to 30 wt % relative to the total amount of inorganic particles, wherein the pre-reacted crystalline particles have a pseudobrookite type crystal structure and are stable with respect to the first quantity of particles at the one or more reactive sintering temperatures;
shaping the batch mixture into a green ceramic body comprising the total amount of inorganic particles; and
heating the green ceramic body at the one or more reactive sintering temperatures and for one or more times sufficient to cause the reactive alumina source, the reactive titania source, and the reactive silica source to reactively sinter and form the ceramic body with a predominant solid state phase comprising crystalline aluminum titanate having the pseudobrookite type crystal structure,
wherein the pre-reacted crystalline particles present in the green ceramic body constitute less than or equal to 33 wt. % of the total amount of inorganic particles.
2. The method of claim 1 wherein the ceramic body further comprises at least one crystalline phase that does not have the pseudobrookite type crystal structure.
3. The method of claim 1 wherein the ceramic body further comprises at least one amorphous phase.
4. The method of claim 1 wherein the crystalline aluminum titanate in the ceramic body is formed by the reactive sintering of the reactive alumina source, the reactive titania source, and the reactive silica source.
5. The method of claim 1 wherein the pre-reacted crystalline particles constitute 0.01 to 33 wt. % of the total amount of inorganic particles.
6. The method of claim 1 wherein the pre-reacted crystalline particles constitute 0.01 to 5.0 wt. % of the total amount of inorganic particles.
7. The method of claim 1 wherein the pre-reacted crystalline particles constitute 0.1 to 2.0 wt. % of the total amount of inorganic particles.
8. The method of claim 1 wherein a median particle diameter of the pre-reacted crystalline particles is less than or equal to 20 μm.
9. The method of claim 1 wherein a median particle diameter of the pre-reacted crystalline particles is less than or equal to 5 μm.
10. The method of claim 1 wherein a median particle diameter of the pre-reacted crystalline particles is less than or equal to 1.0 μm.
11. The method of claim 1 wherein the reactive titania source comprises titanium dioxide.
12. The method of claim 1 wherein the reactive titania source constitutes 10 wt. % to 40 wt. % of the total amount of inorganic particles.
13. The method of claim 1 wherein the reactive titania source constitutes 20 wt. % to 34 wt. % of the total amount of inorganic particles.
14. The method of claim 1 wherein the reactive alumina source comprises calcined alumina, hydrated alumina, or both.
15. The method of claim 1 wherein the reactive alumina source constitutes 20 wt. % to 55 wt. % of the total amount of inorganic particles.
16. The method of claim 1 wherein the reactive silica source constitutes 6 wt. % to 15 wt. % of the total amount of inorganic particles.
17. The method of claim 1 wherein the pre-reacted crystalline particles comprise 75 wt. % to 82 wt. % aluminum titanate and 18 wt. % to 25 wt. % magnesium dititanate.
18. The method of claim 1 wherein a CTE of the ceramic body is less than or equal to 5.0×10 −7 /° C. over a temperature range from 25° C. to 800° C.
19. The method of claim 1 wherein a CTE of the ceramic body is less than or equal to 3.0×10 −7 /° C. over a temperature range from 25° C. to 800° C.
20. The method of claim 1 wherein a CTE of the ceramic body is less than or equal to 0.0×10 −7 /° C. over a temperature range from 25° C. to 800° C.
21. The method of claim 2 wherein the at least one crystalline phase that does not have the pseudobrookite type crystal structure comprises strontium.
22. The method of claim 2 wherein the at least one crystalline phase that does not have the pseudobrookite type crystal structure comprises cordierite.
23. A method of making a ceramic body, the method comprising:
mixing together a batch mixture comprising a total amount of inorganic particles comprised of a first quantity of particles and a second quantity of particles, wherein the first quantity of particles comprises constituents capable of producing aluminum titanate via reactive sintering at one or more reactive sintering temperatures, wherein the first quantity of particles comprises a reactive alumina source, a reactive titania source, and a reactive silica source, and wherein the second quantity of particles comprises pre-reacted crystalline particles comprising aluminum titanate in an amount from 70 wt % to 99 wt % relative to the total amount of inorganic particles in the batch mixture, wherein the pre-reacted crystalline particles have a pseudobrookite type crystal structure and are stable with respect to the first quantity of particles at the one or more reactive sintering temperatures;
shaping the batch mixture into a green ceramic body, the pre-reacted crystalline particles present in the green ceramic body in an amount from equal to or greater than 0.01 wt. % to equal to or less than 5.0 wt. % of the total amount of inorganic particles in the green ceramic body;
heating the green ceramic body at the one or more reactive sintering temperatures and for one or more times sufficient to cause the reactive alumina source, the reactive titania source, and the reactive silica source to reactively sinter and form the ceramic body with a solid state phase comprising crystalline aluminum titanate having the pseudobrookite type crystal structure and in an amount from 63 wt % to 84 wt %; and
wherein a CTE of the ceramic body is less than or equal to 5.0×10 −7 /° C. over a temperature range from 25° C. to 800° C.
24. The method of claim 23 wherein the pre-reacted crystalline particles comprise from 1 wt % to 30 wt. % magnesium dititanate.
25. The method of claim 23 wherein the pre-reacted crystalline particles comprise from 0.1 wt. % to 2.0 wt. % of the total amount of inorganic particles in the green ceramic body.
26. The method of claim 23 , wherein the pre-reacted crystalline particles comprise from 0.1 wt. % to 0.2 wt. % of the total amount of inorganic particles in the green ceramic body.