Steel plate having excellent heat affected zone toughness and method for manufacturing thereof
The present invention relates to a steel plate which can appropriately be used as a structural material and the like. Provided are a steel plate, exhibiting excellent strength and toughness on a heat affected zone even when high heat input welding is performed, and a method for manufacturing thereof.
1. A steel material, comprising, by weight:
0.02 to 0.08% of carbon (C),
0.15 to 0.5% of silicon (Si),
1.2 to 1.8% of manganese (Mn),
0.008% or less, excluding 0%, of phosphorus (P),
0.003% or less, excluding 0%, of sulfur(S),
0.005 to 0.1% of aluminum (Al),
0.01 to 0.5% of nickel (Ni),
0.01 to 0.1% of molybdenum (Mo),
0.005 to 0.05% of niobium (Nb),
0.005 to 0.02% of titanium (Ti),
20 to 100 ppm of nitrogen (N), and
a balance of Fe and other unavoidable impurities,
wherein the steel material satisfies the following Relation Formula 1,
wherein a microstructure of a base metal includes 20 to 60% of an acicular ferrite phase and 40 to 80% of a bainite phase by area fraction,
wherein a microstructure of a fusion line in a heat affected zone after welding includes a ferrite phase in 5 to 20% by area and a bainite phase as a remainder, and
wherein the steel material has a thickness of 10 to 40 mm:
0.42>C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15 [Relation Formula 1]
wherein each element means a weight content.
2. The steel material of claim 1 , further comprising: 0.01 to 0.1% by weight of vanadium (V).
3. The steel material of claim 1 , wherein
the base metal and the fusion line in the heat affected zone include a carbonitride, and
the carbonitride is in a form of MC or M(C,N), in which M is 20% by weight or more of Mo and a balance of Ti.
4. The steel material of claim 1 , wherein the heat affected zone has an austenite average crystal grain size of 500 μm or less.
5. The steel material of claim 1 , wherein the base metal includes a martensite phase or a tempered martensite phase at 10% or less, including 0%, by area fraction.
6. The steel material of claim 1 , wherein the steel material has a tensile strength of 450 MPa or more and Charpy impact absorption energy at −50° C. of 200 J or more after post weld heat treatment (PWHT).
7. The steel material of claim 1 , wherein the heat affected zone has a tensile strength of 450 MPa or more and Charpy impact absorption energy at −50° C. of 100 J or more after post weld heat treatment (PWHT).
8. The steel material of claim 1 , wherein the welding is electrogas welding (EGW) and is a high heat input welding method of a heat input capacity of 100 to 200 kJ/cm.
9. The steel material of claim 1 , comprising, by weight, 0.055 to 0.08% of carbon (C).
10. The steel material of claim 1 , wherein the microstructure of the fusion line further includes a martensite austenite (MA) phase.
11. A method for manufacturing the steel material of claim 1 , the method comprising:
reheating a steel slab at 1050 to 1250° C., the steel slab including, by weight: 0.02 to 0.08% of carbon (C), 0.15 to 0.5% of silicon (Si), 1.2 to 1.8% of manganese (Mn), 0.008% or less, excluding 0%, of phosphorus (P), 0.003% or less, excluding 0% of sulfur(S), 0.005 to 0.1% of aluminum (Al), 0.01 to 0.5% of nickel (Ni), 0.01 to 0.1% of molybdenum (Mo), 0.005 to 0.05% of niobium (Nb), 0.005 to 0.02% of titanium (Ti), and 20 to 100 ppm of nitrogen (N), with a balance of Fe and other unavoidable impurities, and satisfying the following Relation Formula 1;
roughly rolling the reheated steel slab in a temperature range of 1200 to Ar3+30° C.;
after the rough rolling, finish-rolling the steel slab at a temperature of Ar3 or higher to manufacture a hot rolled steel plate; and
cooling the hot rolled steel plate down to room temperature to 200° C. at a cooling rate of 5° C./s or more:
0.42>C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15 [Relation Formula 1]
wherein each element means a weight content.
12. The method of claim 11 , wherein the steel slab further includes 0.01 to 0.1% of vanadium (V).
13. The method of claim 11 , further comprising: subjecting the cooled hot rolled steel plate to an electrogas welding (EGW) process at a heat input capacity of 100 to 200 kJ/cm.
14. The method of claim 13 , wherein a microstructure of a fusion line in the heat affected zone formed after the electrogas welding (EGW) includes 5 to 20% by area of ferrite phase and a bainite phase as a reminder.
15. The method of claim 13 , further comprising: after the electrogas welding (EGW) process, performing a post weld heat treatment (PWHT) in a temperature range of 590 to 620° C.