IP Library Granted Patent US 12,017,421
Granted Patent B2
US 12,017,421 · App. 17/299,866 · Granted Jun 25, 2024

Method of producing composites

Inventors: Mahdi Ghazizadeh (The Woodlands, TX); Eitan Zeira (Merrimack, NH); Derek Kincaid (The Woodlands, TX); David Hatrick (The Woodlands, TX)
B29C70/54B29C35/12B29C70/30B29K2713/00B29K2995/0005B29L2009/00
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Quick Facts
Patent No.
US 12,017,421
App. No.
17/299,866
Granted
Jun 25, 2024
Kind
B2
Abstract

A method of producing composites that are capable of being used in various industries, including the aerospace and automotive industries. In particular, the present disclosure relates to methods of curing one or more prepregs and/or a liquid curable composition using one or more self-supporting, nonwoven carbon nanotube sheets comprising substantially non-aligned carbon nanotubes.

Claims (28)

1. A method of producing a composite laminate, comprising:

(i) providing a curable system comprising:

a stack of two or more prepregs, and

one or more carbon nanotube sheets, wherein at least one of the carbon nanotube sheets is placed in-between the two or more prepregs and wherein the carbon nanotube sheet is a self-supporting, nonwoven sheet of substantially non-aligned carbon nanotubes; and

(ii) at least partially curing the curable system by running an electric current through the one or more carbon nanotube sheets and subjecting the curable system to alternating electromagnetic fields such that at least a portion of the prepregs are cured.

2. The method of claim 1 , wherein each prepreg comprises a mixture of a fibrous reinforcement and a curable resin.

3. The method of claim 2 , wherein the fibrous reinforcement is comprised of fibers selected from conductive fibers, nonconductive fibers, and a combination thereof.

4. The method of claim 3 , wherein the fibrous reinforcement comprises conductive fibers.

5. The method of claim 4 , wherein a nonconductive sheet is placed between each of the one or more carbon nanotube sheets and the prepregs.

6. The method of claim 1 , wherein the carbon nanotube sheet further comprises a curable resin incorporated therein.

7. The method of claim 1 , wherein the stack of two or more prepregs has a thickness in a range of from 0.1 mm to 160 mm.

8. The method of claim 1 , wherein the stack of two or more prepregs has a thickness in a range of from 50 mm to about 80 mm.

9. The method of claim 1 , wherein the carbon nanotube sheets can be separately placed in different locations between prepregs.

10. The method of claim 1 , wherein one or more carbon nanotube sheets are placed in the middle of the stack of two or more prepregs such that the thickness of the prepregs is substantially the same on both sides of the one or more carbon nanotube sheets.

11. The method of claim 1 , wherein the step of at least partially curing the curable system comprises running the electric current through the one or more carbon nanotube sheets such that at least a portion of the prepregs is cured.

12. The method of claim 1 , wherein the step of at least partially curing the curable system comprises subjecting the curable system to alternating electromagnetic fields such that at least a portion of the prepregs is cured.

13. The method of claim 11 , wherein the curable system is substantially uniformly cured.

14. A method of producing a composite laminate, comprising:

(i) providing a curable system comprising:

a stack of two or more prepregs, and

one or more carbon nanotube sheets having a density from about 0.1 mg/cm 2 to about 5 mg/cm 2 , wherein at least one of the carbon nanotube sheets is placed in-between the two or more prepregs and wherein the carbon nanotube sheet is a self-supporting, nonwoven sheet of substantially non-aligned carbon nanotubes, and

one or more additives selected from catalysts, curing agents, antioxidants, toughening agents, UV stabilizers, and fire retardants; and

(ii) at least partially curing the curable system by running an electric current through the one or more carbon nanotube sheets and subjecting the curable system to alternating electromagnetic fields such that at least a portion of the prepregs are cured.

15. The method of claim 14 , wherein each prepreg comprises a mixture of a fibrous reinforcement and a curable resin.

16. The method of claim 14 , wherein the carbon nanotube sheet further comprises a curable resin incorporated therein.

17. The method of claim 14 , wherein the stack of two or more prepregs has a thickness in a range of from 0.1 mm to 160 mm.

18. The method of claim 14 , wherein the carbon nanotube sheets can be separately placed in different locations between prepregs.

19. The method of claim 14 , wherein the one or more carbon nanotube sheets are placed in a middle position of the stack of two or more prepregs such that a thickness of the prepregs is substantially same on both sides of the one or more carbon nanotube sheets.

Assignments (3)
SECURITY INTEREST Recorded May 4, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCOMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK N.A.
Reel/Frame 075498/0663 →
PATENT SECURITY AGREEMENT Recorded Mar 10, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCAMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK, N.A.
Reel/Frame 075106/0238 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2023
From: GHAZIZADEH, MAHDI; KINCAID, DEREK; ZEIRA, EITAN; HATRICK, DAVID
To: NANOCOMP TECHNOLOGIES INC.
Reel/Frame 065580/0930 →
Continuity (2)
Provisional Application 62778737 · Dec 12, 2018
Related Publication 20220080681A1 · Mar 17, 2022