Catalyst and preparation thereof
The present invention relates to a process for producing solid Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50 vol ) of 5 to 500 μm the process comprising steps I. providing a solution of a mixture of Group 2 metal compounds of i) a solution of a Group 2 metal dihalide and ii) at least one Group 2 metal alkoxide of the Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005) II. contacting the solution of the mixture of Group 2 metal compounds of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinide, preferably a transition metal of Group 4 to 6 of Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005), and III. recovering the solid catalyst component, wherein the solution of a Group 2 metal dihalide i) is obtained by dissolving a solid Group 2 metal dihalide in an alcohol comprising at least a monohydric alcohol of formula ROH, where R is selected from hydrocarbyl of 3 to 16 C atoms, and wherein the amount of Group 2 metal originating from Group 2 metal dihalide in the solution of the mixture of Group 2 metal compounds is in the range of 5 to 90 mol-%. The invention further relates to a catalyst comprising the catalyst component and use thereof in olefin polymerisation process.
1. A process for producing solid Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50 vol ) of 5 to 500 μm, the process comprising steps:
I. providing a solution of a mixture of Group 2 metal compounds of:
i) a solution of a Group 2 metal dihalide and
ii) at least one Group 2 metal alkoxide of the Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005),
II. contacting the solution of the mixture of Group 2 metal compounds of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinide of Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005), and
III. recovering the solid catalyst component,
wherein the solution of a Group 2 metal dihalide i) is obtained by dissolving a solid Group 2 metal dihalide in an alcohol comprising at least a monohydric alcohol of formula ROH, where R is selected from hydrocarbyl of 3 to 16 C atoms, and
wherein the amount of Group 2 metal originating from Group 2 metal dihalide in the solution of the mixture of Group 2 metal compounds is in the range of 5 to 90 mol %.
2. The process according to claim 1 , wherein an internal donor selected from esters of carboxylic acids or di-acids, ethers, di-ethers and oxygen or nitrogen containing silicon compounds is added to the process before the recovery step III.
3. The process according to claim 1 , wherein the Group 2 metal dihalide is MgCl 2 and the Group 2 metal alkoxide is Mg alkoxide.
4. The process according to claim 1 , wherein the transition metal compound of Group 4 to 10, or of a lanthanide or actinide is a Group 4 to 6 transition metal compound.
5. The process according to claim 1 , wherein the amount of Group 2 metal originating from Group 2 metal dihalide is in the range of 10 to 85 mol %.
6. The process according to claim 1 , wherein the Group 2 metal dihalide is dissolved in a mixture of alcohols comprising the monohydric alcohol of formula ROH (A1), where R is selected from a hydrocarbyl of 3 to 16 C atoms, and an alcohol (A2) comprising in addition to the hydroxyl group another oxygen containing functional group not being a hydroxyl group.
7. The process according to claim 1 , wherein the Group 2 metal dihalide is dissolved in a mixture of alcohols comprising the monohydric alcohol of formula ROH (A1), where R is selected from a hydrocarbyl of 3 to 16 C atoms, and an alcohol (A2) comprising in addition to the hydroxyl group another oxygen containing functional group not being a hydroxyl group; and
wherein in the alcohol (A2) another oxygen containing functional group not being a hydroxyl group is an ether group, wherein the ether moiety comprises from 2 to 18 carbon atoms.
8. The process according to claim 1 , wherein the mol ratio of the monohydric alcohol (A1): alcohol (A2) is in the range of 10:0 to 1:9.
9. A process for producing polymers of α-olefins of 2 to 10 C atoms or copolymers thereof with C 2 to C 12 α-olefin comonomers in the presence of the Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50 vol ) of 5 to 500 μm obtained, by a process comprising steps:
I. providing a solution of a mixture of Group 2 metal compounds of
i) a solution of a Group 2 metal dihalide and
ii) at least one Group 2 metal alkoxide of the Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005)
II. contacting the solution of the mixture of Group 2 metal compounds of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinidee of Periodic Table (IUPAC, Nomenclature of Inorganic Chemistry, 2005), and
III. recovering the solid catalyst component,
wherein the solution of a Group 2 metal dihalide i) is obtained by dissolving a solid Group 2 metal dihalide in an alcohol comprising at least a monohydric alcohol of formula ROH, where R is selected from hydrocarbyl of 3 to 16 C atoms, and
wherein the amount of Group 2 metal originating from Group 2 metal dihalide in the solution of the mixture of Group 2 metal compounds is in the range of 5 to 90 mol %.