Polyester film, preparation method thereof and method for reproducing polyethyleneterephthalate container using same
The embodiments relate to a polyester film, to a process for preparing the same, and to a process for regenerating a polyethylene terephthalate (PET) container using the same. The polyester film has excellent seaming characteristics and recyclability by virtue of controlled crystallinity, whereby clumping rarely occurs even if it is thermally treated for a long period of time in the regeneration process.
1. A polyester film comprising:
a copolymerized polyester resin in which a diol and a dicarboxylic acid are copolymerized; and
a homopolyethylene terephthalate (HOMO-PET) resin,
wherein the diol comprises ethylene glycol, neopentyl glycol and 1% by mole to 8% by mole of diethylene glycol,
wherein the dicarboxylic acid comprises terephthalic acid,
wherein the polyester film comprises the HOMO-PET resin in an amount of 0.5% by weight to 25% by weight based on a total weight of the copolymerized polyester resin and the HOMO-PET resin,
wherein a melting point (Tm) is 190° C. to 230° C. as measured by differential scanning calorimetry, a clumping ratio is 10% or less, and a peel strength is 150 gf/3 cm or more.
2. The polyester film of claim 1 , which has a heat shrinkage rate of 45% to 85% in a first direction upon thermal treatment at a temperature of 100° C. for 10 seconds.
3. The polyester film of claim 1 , which has a heat shrinkage rate of 7% or less in a second direction perpendicular to a first direction upon thermal treatment at a temperature of 100° C. for 10 seconds.
4. The polyester film of claim 1 , wherein the diol comprises ethylene glycol and at least one comonomer selected from the group consisting of neopentyl glycol and diethylene glycol in an amount of 10% by mole or more.
5. The polyester film of claim 1 , wherein the neopentyl glycol is in an amount of 5% by mole to 35% by mole of the total diol.
6. A process for preparing a polyester film, which comprises:
preparing a copolymerized polyester resin in which a diol and a dicarboxylic acid are copolymerized;
adding a homopolyethylene terephthalate (HOMO-PET) resin to the copolymerized polyester resin and then melt-extruding the resins at a temperature of 250° C. to 300° C. to prepare an unstretched sheet; and
stretching the unstretched sheet and then heat-setting the stretched sheet at a temperature of 70° C. to 100° C. to prepare a polyester film,
wherein the diol comprises ethylene glycol, neopentyl glycol and 1% by mole to 8% by mole of diethylene glycol,
wherein the dicarboxylic acid comprises terephthalic acid,
wherein the polyester film comprises the HOMO-PET resin in an amount of 0.5% by weight to 25% by weight of based on a total weight of the copolymerized polyester resin and the HOMO-PET resin,
wherein the polyester film has a melting point (Tm) of 190° C. to 230° C. as measured by differential scanning calorimetry, a clumping ratio of 10% or less, and a peel strength of 150 gf/3 cm or more.
7. A process for regenerating a polyethylene terephthalate container, which comprises:
providing a polyethylene terephthalate container provided with the polyester film of claim 1 ;
crushing the polyethylene terephthalate container provided with the polyester film to obtain flakes; and
thermally treating the flakes to produce regenerated polyester chips,
wherein a clumping ratio of the flakes is 10% or less, and the flakes comprise first flakes obtained by crushing the polyethylene terephthalate (PET) container and second flakes obtained by crushing the polyester film.