Water-based binder solutions for use in additive manufacturing processes
In various embodiments, a water-based binder solution for use in additive manufacturing, includes a thermoplastic binder. The thermoplastic binder includes a first polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 5,000 g/mol to less than or equal to 15,000 g/mol, a second polymer strand having a weight average molecular weight of from greater than or equal to 10,000 g/mol to less than or equal to 50,000 g/mol, and a third polymer strand having a weight average molecular weight of from greater than or equal to 1,000 g/mol to less than or equal to 5,000 g/mol. The binder solution further comprises from greater than or equal to 0.1 wt % to less than or equal to 5 wt % of a non-aqueous solvent having a boiling point of greater than 100° C.
1. A method of additive manufacturing comprising:
depositing a layer of powder on a working surface;
selectively depositing a water-based binder solution comprising from greater than or equal to 0.1 wt % to less than or equal to 5 wt % of a non-aqueous solvent having a boiling point of greater than 100° C. and below 175° C. and a thermoplastic binder into the layer of powder in a pattern representative of a structure of a part, wherein:
the thermoplastic binder comprises:
a first polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 5,000 g/mol to less than or equal to 15,000 g/mol; and
at least one of a second polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 10,000 g/mol to less than or equal to 50,000 g/mol and a third polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 1,000 g/mol to less than or equal to 5,000 g/mol;
the first polymer strand differs from each of the second polymer strand and the third polymer strand;
the second polymer strand differs from the third polymer strand; and
coupling the first polymer strand with the at least one of the second polymer strand and the third polymer strand to form a green body part.
2. The method according to claim 1 , wherein the non-aqueous solvent is present in the water-based binder solution in an amount of from greater than or equal to 1 wt % to less than 4 wt %.
3. The method according to claim 1 , wherein the non-aqueous solvent comprises 2-methoxy ethanol, butanol, 2-butanol, tent-butanol, 1-methoxy-2-propanol, 2-butoxy ethanol, isoamyl alcohol, isobutyl alcohol, ethylene glycol butyl ether, or combinations thereof.
4. The method according to claim 1 , wherein the first polymer strand comprises polyvinyl pyrrolidone (PVP), polyvinyl alcohol (PVA), or combinations thereof.
5. The method according to claim 4 , wherein the first polymer strand is present in an amount of from greater than or equal to 5 wt % to less than or equal to 20 wt % based on a total weight of the water-based binder solution.
6. The method according to claim 1 , wherein the thermoplastic binder comprises the second polymer strand in an amount of from greater than or equal to 0.5 wt % to less than or equal to 7 wt % based on a total weight of the water-based binder solution.
7. The method according to claim 6 , wherein the thermoplastic binder comprises the third polymer strand in an amount of from greater than or equal to 0.1 wt % to less than or equal to 5 wt % based on a total weight of the water-based binder solution.
8. The method according to claim 1 , wherein the second polymer strand is selected from the group consisting of polyvinyl alcohol (PVA), polyacryl amide (PAAm), derivatives thereof and combinations thereof.
9. The method according to claim 1 , wherein the third polymer strand is selected from the group consisting of polyacrylic acid (PAA), polymethyl methacrylate (PMMA), polyvinyl methyl ether-maleic anhydride (PVME-MA), derivatives thereof, and combinations thereof.
10. The method according to claim 1 , wherein the water-based binder solution further comprises from greater than or equal to 0.1 wt % to less than or equal to 2 wt % of a surfactant.
11. The method according to claim 1 , wherein a total weight of polymers present in the water-based binder solution is from greater than or equal to 5 wt % to less than or equal to 20 wt % based on a total weight of the water-based binder solution.
12. The method according to claim 1 , wherein:
the first polymer strand comprises polyvinyl pyrrolidone (PVP);
the second polymer strand is selected from the group consisting of polyvinyl alcohol (PVA), polyacryl amide (PAAm), derivatives thereof and combinations thereof; and
the third polymer strand is selected from the group consisting of polyacrylic acid (PAA), polymethyl methacrylate (PMMA), polyvinyl methyl ether-maleic anhydride (PVME-MA), derivatives thereof, and combinations thereof.
13. A water-based binder solution for use in additive manufacturing, comprising:
a thermoplastic binder comprising:
a first polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 5,000 g/mol to less than or equal to 15,000 g/mol; and
at least one of a second polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 10,000 g/mol to less than or equal to 50,000 g/mol and a third polymer strand having a weight average molecular weight (Mw) of from greater than or equal to 1,000 g/mol to less than or equal to 5,000 g/mol;
wherein the first polymer strand differs from each of the second polymer strand and the third polymer strand and the second polymer strand differs from the third polymer strand;
from greater than or equal to 0.1 wt % to less than or equal to 5 wt % of a non-aqueous solvent having a boiling point of greater than 100° C.; and
water.
14. The water-based binder solution according to claim 13 , further comprising from greater than or equal to 0.1 wt % to less than or equal to 2 wt % of a surfactant.
15. The water-based binder solution according to claim 13 , wherein:
the first polymer strand comprises polyvinyl pyrrolidone (PVP);
the second polymer strand is selected from the group consisting of polyvinyl alcohol (PVA), polyacryl amide (PAAm), derivatives thereof and combinations thereof; and
the third polymer strand is selected from the group consisting of polyacrylic acid (PAA), polymethyl methacrylate (PMMA), polyvinyl methyl ether-maleic anhydride (PVME-MA), derivatives thereof, and combinations thereof.