Particulate laundry additive
A composition including a plurality of particles. The plurality of particles include: about 25% to about 99% by weight water soluble carrier; and about 0.01% to 50% by weight antioxidant. The antioxidant is dispersed in a matrix of the water soluble carrier.
1. A composition comprising a plurality of particles, said plurality of particles comprising:
about 25% to about 99% by weight water soluble carrier, wherein said water soluble carrier comprises polyethylene glycol having a weight average molecular weight from 2000 to 15000; and
about 0.01% to 2% by weight antioxidant, wherein said antioxidant comprises alkylated phenol and said alkylated phenol is selected from a C 1 -C 8 linear or C 3 -C 8 branched alkyl ester of 3,5-bis(1,1-dimethylethyl)-4-hydroxy-benzenepropanoic acid, a mono- or bis-ester of 3-(1,1-dimethylethyl)-4-hydroxy-5-methyl benzenepropanoic acid; a 2,2′-methylenebis-phenol;
and mixtures thereof; and
wherein said antioxidant is dispersed in a matrix of said water soluble carrier.
2. The composition according to claim 1 , wherein said plurality of particles further comprise about 0.2% to about 20% by weight perfume.
3. The composition according to claim 2 , wherein said perfume and said antioxidant are dispersed together in said matrix of said water soluble carrier.
4. The composition according to claim 1 , wherein said plurality of particles are free from perfume.
5. The composition according to claim 1 , wherein said water soluble carrier further comprises a water soluble polymer selected from:
polyalkylene polymer of formula H—(C 2 H 4 O) x —(CH(CH 3 )CH 2 O) y —(C 2 H 4 O) z —OH wherein x is from 50 to 300, y is from 20 to 100, and z is from 10 to 200;
polyethylene glycol fatty acid ester of formula (C 2 H 4 O) q —C(O)O—(CH 2 ) r —CH 3 wherein q is from 20 to 200 and r is from 10 to 30;
polyethylene glycol fatty alcohol ether of formula HO—(C 2 H 4 O) s —(CH 2 ) t )—CH 3 wherein s is from 30 to 250 and t is from 10 to 30;
C 8 -C 22 alkyl polyalkoxylate comprising more than 40 alkoxylate units;
EO/PO/EO block copolymer;
PO/EO/PO block copolymer;
EO/PO block copolymer;
PO/EO block copolymer;
polypropylene glycol;
ethoxylated nonionic surfactant having a degree of ethoxylation greater than 30;
polyvinyl alcohol;
and mixtures thereof.
6. The composition according to claim 1 , wherein said water soluble carrier is polyethylene glycol having a weight average molecular weight from about 2000 to about 15000.
7. The composition according to claim 1 , wherein said antioxidant comprises mono- or bis-ester of 3-(1,1-dimethylethyl)-4-hydroxy-5-methyl benzenepropanoic acid.
8. The composition according to claim 1 , wherein said alkylated phenol is selected from 3,5-bis(1,1-dimethylethyl)-4-hydroxy-benzenepropanoic acid, methyl ester; 3-(1,1-dimethylethyl)-4-hydroxy-5-methyl benzenepropanoic acid, 1,1′-[1,2-ethanediylbis(oxy-2,1-ethanediyl)]ester; 2,2′-methylenebis[6-(1,1-dimethylethyl)-4-methylphenol]; and mixtures thereof.
9. The composition according to claim 1 , wherein said plurality of particles comprise less than about 20% by weight anionic surfactant.
10. The composition according to claim 1 , wherein said water soluble carrier, wherein said water soluble carrier comprises polyethylene glycol having a weight average molecular weight from 2000 to 1500 sodium acetate, sodium bicarbonate, sodium chloride, sodium silicate, polypropylene glycol polyoxoalkylene, polyethylene glycol fatty acid ester, polyethylene glycol ether, sodium sulfate, starch, or mixtures thereof.
11. The composition according to claim 1 , wherein said plurality of particles further comprise a material selected from: α-, β-, γ-, and δ-tocopherol; α-, β-, γ-, and δ-tocotrienol; 2,2,4-trimethyl-1,2-dihydroquinoline; tert-butyl hydroxyanisole; 6-hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid; and mixtures thereof.
12. The composition according to claim 1 , wherein said plurality of particles comprise individual particles, wherein said individual particles each have a mass from about 5 mg to about 200 mg.
13. A process for forming the plurality of particles of claim 1 comprising the steps of:
providing a melt composition comprising said water soluble carrier and said antioxidant;
passing said melt composition through one or more apertures of a distributor; and
depositing said melt composition on a movable conveyor beneath said one or more apertures.
14. A process for treating laundry comprising the steps of:
providing an article of laundry in a washing machine;
dispensing said plurality of particles according to claim 1 into said washing machine; and
contacting said article of laundry during a wash sub-cycle of said washing machine with said plurality of particles.
15. The process according to claim 14 further comprising a step of dispensing into said washing machine a laundry detergent comprising from about 3 % to about 60 % by weight anionic or nonionic surfactant.
16. The process according to claim 14 , wherein about 5 g to about 50 g of said plurality of particles is dispensed into said washing machine.
17. The process according to claim 16 , wherein said plurality of particles is dissolved into a wash liquor within said washing machine and said antioxidant is at a level of from about 0.1 ppm to about 20 ppm.