Electrode plate and electrochemical device
The electrode plate according to the present application includes a current collector and an electrode active material layer disposed on at least one surface of the current collector, wherein the current collector includes a support layer and a conductive layer disposed on at least one surface of the support layer, the conductive layer has a single-sided thickness D2 satisfying: 30 nm D2 3 μm; and a conductive primer layer containing a first conductive material and a binder is provided between the current collector and the electrode active material layer, and the first conductive material in the conductive primer layer comprises at least one of a one-dimensional conductive material and a two-dimensional conductive material. The electrode plate of the present application has good workability, and the electrochemical device including the electrode plate has high energy density, good electrical performance and long-term reliability.
1. An electrode plate comprising a current collector ( 10 , 20 ) and an electrode active material layer ( 12 , 22 ) disposed on at least one surface of the current collector ( 10 , 20 ),
wherein the current collector ( 10 , 20 ) comprises a support layer ( 101 , 201 ) and a conductive layer ( 102 , 202 ) disposed on at least one surface of the support layer ( 101 , 201 ), the conductive layer ( 102 , 202 ) has a single-sided thickness D2 that satisfies: 30 nm≤D2≤3 μm, the conductive layer ( 102 , 202 ) is a metal conductive layer, and the metal conductive layer comprises a material that is selected from at least one of aluminum, copper, titanium, silver, and aluminum-zirconium alloy or from a combination of nickel or nickel copper alloy with at least one of aluminum, copper, titanium, silver, and aluminum-zirconium alloy;
wherein a conductive primer layer ( 11 , 21 ) containing a first conductive material and a binder is provided between the current collector ( 10 , 20 ) and the electrode active material layer ( 12 , 22 ), and the first conductive material in the conductive primer layer ( 11 , 21 ) comprises at least one of a one-dimensional conductive material and a two-dimensional conductive material;
wherein the first conductive material is present in a weight percentage of 10% to 99%, and the binder is present in a weight percentage of 1% to 90% based on the total weight of the conductive primer layer ( 11 , 21 );
wherein based on the total weight of the first conductive material, the first conductive material comprises 5 wt % to 50 wt % of at least one of the one-dimensional conductive material and the two-dimensional conductive material, and 50 wt % to 95 wt % of other conductive materials; and
wherein the conductive layer ( 102 , 202 ) is further provided with a protective layer ( 103 , 203 ) on its surface, the protective layer ( 103 , 203 ) is a metal protective layer or a metal oxide protective layer, in which the metal protective layer comprises a material that is selected from at least one of nickel, chromium, nickel alloy and chromium alloy, the protective layer ( 103 , 203 ) being provided on one surface of the conductive layer ( 102 , 202 ) of the current collector ( 10 , 20 ) facing the support layer ( 101 , 201 ) or on both surfaces of the conductive layers ( 102 , 202 ) of the current collector ( 10 , 20 ); and
wherein the conductive primer layer ( 11 , 21 ) has a single-side thickness H of 0.1 to 5 μm and H/D2 is 0.5:1 to 5:1.
2. The electrode plate according to claim 1 , wherein the support layer ( 101 , 201 ) comprises at least one material selected from insulating polymer materials, insulating polymer composite materials, conductive polymer materials, and conductive polymer composite materials.
3. The electrode plate according to claim 2 , wherein the support layer ( 101 , 201 ) has a normal temperature Young's modulus that satisfies: 20 GPa≥E≥4 GPa.
4. The electrode plate according to claim 1 , wherein the support layer ( 101 , 201 ) has a thickness D1 that satisfies: 1 μm≤D1≤30 μm.
5. The electrode plate according to claim 1 , wherein there are cracks in the conductive layer ( 102 , 202 ).
6. The electrode plate according to claim 1 , wherein the conductive layer ( 102 , 202 ) has a single-sided thickness D2 that satisfies: 300 nm≤D2≤2 μm.
7. The electrode plate according to claim 1 , wherein the protective layer ( 103 , 203 ) has a thickness that satisfies: D3≤ 1/10D2 and 1 nm≤D3≤200 nm.
8. The electrode plate according to claim 1 , wherein the first conductive material is present in a weight percentage of 20% to 80%; and/or,
the binder is present in a weight percentage of 20% to 80% based on the total weight of the conductive primer layer ( 11 , 21 ).
9. The electrode plate according to claim 1 , wherein
the binder is at least one selected from styrene butadiene rubber, oil-dispersible polyvinylidene fluoride (PVDF), polyvinylidene fluoride copolymer, sodium carboxymethyl cellulose, polystyrene, polyacrylic acid, polytetrafluoroethylene, polyacrylonitrile, polyimide, water-dispersible PVDF, polyurethane, polyvinyl alcohol, polyacrylates, polyacrylic acid-polyacrylonitrile copolymer, and polyacrylate-polyacrylonitrile copolymers.
10. The electrode plate according to claim 1 , wherein
the one-dimensional conductive material is one-dimensional conductive carbon; the two-dimensional conductive material is two-dimensional conductive carbon.
11. The electrode plate according to claim 1 , wherein the other conductive material is at least one of a conductive carbon material and a metal material in which the conductive carbon material is at least one selected from a zero-dimensional conductive carbon, an one-dimensional conductive carbon, a two-dimensional conductive carbon, and a three-dimensional conductive carbon; the metal material is at least one selected from aluminum powder, iron powder and silver powder.
12. The electrode plate according to claim 1 , wherein the electrode active material layer ( 12 , 22 ) comprises an electrode active material, an electrode binder and an electrode conductive agent.
13. An electrochemical device comprising a positive electrode plate, a negative electrode plate, a separator and electrolyte wherein the positive electrode plate and/or the negative electrode plate is the electrode plate according to claim 1 .
14. An apparatus characterized by comprising the electrochemical device as claimed in claim 13 , wherein the electrochemical device is used as a power source of the apparatus.
15. The electrode plate according to claim 1 , wherein the support layer ( 101 , 201 ) has a thickness D1 that satisfies: 1 μm≤D1≤15 μm.
16. The electrode plate according to claim 1 , wherein the conductive layer ( 102 , 202 ) has a single-sided thickness D2 that satisfies: 500 nm≤D2≤1.5 μm.
17. The electrode plate according to claim 1 , wherein the protective layer ( 103 , 203 ) has a thickness that satisfies: D3≤ 1/10D2 and 10 nm≤D3≤50 nm.
18. The electrode plate according to claim 1 , wherein the first conductive material is present in a weight percentage of 50% to 80%; and/or,
the binder is present in a weight percentage of 20% to 50% based on the total weight of the conductive primer layer ( 11 , 21 ).